skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Tuning Bifunctional Oxygen Electrocatalysts by Changing the A-Site Rare-Earth Element in Perovskite Nickelates

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [4];  [5];  [6];  [7];  [8];  [2];  [9];  [3];  [5];  [10];  [10];  [5];  [7];  [3];  [2];  [2]
  1. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA, School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 Singapore
  2. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
  3. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 Singapore
  4. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 China, University of Chinese Academy of Sciences, Beijing 100049 China
  5. Department of Material Science & Engineering, National University of Singapore, Singapore 117575 Singapore
  6. NUS Graduate School for Integrative Sciences and Engineering, National University of Singapore, Singapore 117456 Singapore
  7. Department of Physics, Faculty of Science, National University of Singapore, Singapore 117542 Singapore
  8. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99352 USA
  9. School of Physical Engineering, Zhengzhou University, Zhengzhou Henan 450001 China
  10. Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 China
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1463195
Grant/Contract Number:  
68278
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 28 Journal Issue: 39; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Wang, Le, Stoerzinger, Kelsey A., Chang, Lei, Zhao, Jiali, Li, Yangyang, Tang, Chi Sin, Yin, Xinmao, Bowden, Mark E., Yang, Zhenzhong, Guo, Haizhong, You, Lu, Guo, Rui, Wang, Jiaou, Ibrahim, Kurash, Chen, Jingsheng, Rusydi, Andrivo, Wang, Junling, Chambers, Scott A., and Du, Yingge. Tuning Bifunctional Oxygen Electrocatalysts by Changing the A-Site Rare-Earth Element in Perovskite Nickelates. Germany: N. p., 2018. Web. doi:10.1002/adfm.201803712.
Wang, Le, Stoerzinger, Kelsey A., Chang, Lei, Zhao, Jiali, Li, Yangyang, Tang, Chi Sin, Yin, Xinmao, Bowden, Mark E., Yang, Zhenzhong, Guo, Haizhong, You, Lu, Guo, Rui, Wang, Jiaou, Ibrahim, Kurash, Chen, Jingsheng, Rusydi, Andrivo, Wang, Junling, Chambers, Scott A., & Du, Yingge. Tuning Bifunctional Oxygen Electrocatalysts by Changing the A-Site Rare-Earth Element in Perovskite Nickelates. Germany. doi:10.1002/adfm.201803712.
Wang, Le, Stoerzinger, Kelsey A., Chang, Lei, Zhao, Jiali, Li, Yangyang, Tang, Chi Sin, Yin, Xinmao, Bowden, Mark E., Yang, Zhenzhong, Guo, Haizhong, You, Lu, Guo, Rui, Wang, Jiaou, Ibrahim, Kurash, Chen, Jingsheng, Rusydi, Andrivo, Wang, Junling, Chambers, Scott A., and Du, Yingge. Mon . "Tuning Bifunctional Oxygen Electrocatalysts by Changing the A-Site Rare-Earth Element in Perovskite Nickelates". Germany. doi:10.1002/adfm.201803712.
@article{osti_1463195,
title = {Tuning Bifunctional Oxygen Electrocatalysts by Changing the A-Site Rare-Earth Element in Perovskite Nickelates},
author = {Wang, Le and Stoerzinger, Kelsey A. and Chang, Lei and Zhao, Jiali and Li, Yangyang and Tang, Chi Sin and Yin, Xinmao and Bowden, Mark E. and Yang, Zhenzhong and Guo, Haizhong and You, Lu and Guo, Rui and Wang, Jiaou and Ibrahim, Kurash and Chen, Jingsheng and Rusydi, Andrivo and Wang, Junling and Chambers, Scott A. and Du, Yingge},
abstractNote = {},
doi = {10.1002/adfm.201803712},
journal = {Advanced Functional Materials},
number = 39,
volume = 28,
place = {Germany},
year = {2018},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adfm.201803712

Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Oxygen reduction reaction at La x Ca 1−x MnO 3 nanostructures: interplay between A-site segregation and B-site valency
journal, January 2016

  • Celorrio, Verónica; Calvillo, Laura; Dann, Ellie
  • Catalysis Science & Technology, Vol. 6, Issue 19
  • DOI: 10.1039/C6CY01105E

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices
journal, March 2015

  • McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/ja510442p

Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energy
journal, January 2012

  • Vesborg, Peter C. K.; Jaramillo, Thomas F.
  • RSC Advances, Vol. 2, Issue 21
  • DOI: 10.1039/c2ra20839c

Oxygen Reduction at Carbon-Supported Lanthanides: The Role of the B-Site
journal, December 2015

  • Celorrio, Verónica; Dann, Ellie; Calvillo, Laura
  • ChemElectroChem, Vol. 3, Issue 2
  • DOI: 10.1002/celc.201500440

Ca 2 Mn 2 O 5 as Oxygen-Deficient Perovskite Electrocatalyst for Oxygen Evolution Reaction
journal, October 2014

  • Kim, Jaemin; Yin, Xi; Tsao, Kai-Chieh
  • Journal of the American Chemical Society, Vol. 136, Issue 42
  • DOI: 10.1021/ja506254g

Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Toward sustainable fuel cells
journal, December 2016

  • Stephens, Ifan Erfyl Lester; Rossmeisl, Jan; Chorkendorff, Ib
  • Science, Vol. 354, Issue 6318
  • DOI: 10.1126/science.aal3303

Strongly correlated perovskite fuel cells
journal, May 2016


Orbital Order and Possible Superconductivity in LaNiO 3 / LaMO 3 Superlattices
journal, January 2008


Highly Active Epitaxial La (1– x ) Sr x MnO 3 Surfaces for the Oxygen Reduction Reaction: Role of Charge Transfer
journal, April 2015

  • Stoerzinger, Kelsey A.; Lü, Weiming; Li, Changjian
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 8
  • DOI: 10.1021/acs.jpclett.5b00439

Oxygen Vacancy Induced Room-Temperature Metal–Insulator Transition in Nickelate Films and Its Potential Application in Photovoltaics
journal, April 2016

  • Wang, Le; Dash, Sibashisa; Chang, Lei
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 15
  • DOI: 10.1021/acsami.6b00650

Investigation of the metal–insulator transition in NdNiO 3 films by site-selective X-ray absorption spectroscopy
journal, January 2017

  • Palina, Natalia; Wang, Le; Dash, Sibashisa
  • Nanoscale, Vol. 9, Issue 18
  • DOI: 10.1039/C7NR00742F

Design of Efficient Bifunctional Oxygen Reduction/Evolution Electrocatalyst: Recent Advances and Perspectives
journal, July 2017

  • Huang, Zhen-Feng; Wang, Jiong; Peng, Yuecheng
  • Advanced Energy Materials, Vol. 7, Issue 23
  • DOI: 10.1002/aenm.201700544

Elastic properties of rhombohedral, cubic, and monoclinic phases of LaNiO 3 by first principles calculations
journal, October 2015


Strain dependent stabilization of metallic paramagnetic state in epitaxial NdNiO 3 thin films
journal, September 2012

  • Kumar, Yogesh; Choudhary, R. J.; Sharma, S. K.
  • Applied Physics Letters, Vol. 101, Issue 13
  • DOI: 10.1063/1.4754593

Orientation-Dependent Oxygen Evolution Activities of Rutile IrO 2 and RuO 2
journal, April 2014

  • Stoerzinger, Kelsey A.; Qiao, Liang; Biegalski, Michael D.
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 10
  • DOI: 10.1021/jz500610u

Energy and fuels from electrochemical interfaces
journal, December 2016

  • Stamenkovic, Vojislav R.; Strmcnik, Dusan; Lopes, Pietro P.
  • Nature Materials, Vol. 16, Issue 1
  • DOI: 10.1038/nmat4738

Oxygen Reduction Reaction Activity of La-Based Perovskite Oxides in Alkaline Medium: A Thin-Film Rotating Ring-Disk Electrode Study
journal, February 2012

  • Sunarso, Jaka; Torriero, Angel A. J.; Zhou, Wei
  • The Journal of Physical Chemistry C, Vol. 116, Issue 9
  • DOI: 10.1021/jp211946n

Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
journal, November 2010

  • Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y.
  • Chemical Reviews, Vol. 110, Issue 11
  • DOI: 10.1021/cr100246c

Hybridization-controlled charge transfer and induced magnetism at correlated oxide interfaces
journal, January 2016

  • Grisolia, M. N.; Varignon, J.; Sanchez-Santolino, G.
  • Nature Physics, Vol. 12, Issue 5
  • DOI: 10.1038/nphys3627

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
journal, October 2011


Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution
journal, January 2017

  • Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong
  • Nature Chemistry, Vol. 9, Issue 5
  • DOI: 10.1038/nchem.2695

Spatially resolved ultrafast magnetic dynamics initiated at a complex oxide heterointerface
journal, July 2015

  • Först, M.; Caviglia, A. D.; Scherwitzl, R.
  • Nature Materials, Vol. 14, Issue 9
  • DOI: 10.1038/nmat4341

Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
journal, January 2014

  • Wang, Zhong-Li; Xu, Dan; Xu, Ji-Jing
  • Chem. Soc. Rev., Vol. 43, Issue 22
  • DOI: 10.1039/C3CS60248F

Competition between strain and dimensionality effects on the electronic phase transitions in NdNiO3 films
journal, December 2015

  • Wang, Le; Ju, Sheng; You, Lu
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep18707

Oxide enthalpy of formation and band gap energy as accurate descriptors of oxygen vacancy formation energetics
journal, January 2014

  • Deml, Ann M.; Stevanović, Vladan; Muhich, Christopher L.
  • Energy & Environmental Science, Vol. 7, Issue 6
  • DOI: 10.1039/c3ee43874k

Oxygen-deficient BaTiO3− perovskite as an efficient bifunctional oxygen electrocatalyst
journal, April 2015


Low-cost Oxygen Electrode Material
journal, May 1970


Influence of the nature of the conduction band of transition metal oxides on catalytic activity for oxygen reduction
journal, October 1977

  • Matsumoto, Y.; Yoneyama, H.; Tamura, H.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 83, Issue 2
  • DOI: 10.1016/S0022-0728(77)80169-1

Self-powered sensitive and stable UV-visible photodetector based on GdNiO 3 /Nb-doped SrTiO 3 heterojunctions
journal, January 2017

  • Wang, Le; Chang, Lei; Yin, Xinmao
  • Applied Physics Letters, Vol. 110, Issue 4
  • DOI: 10.1063/1.4974144

Phase diagram of compressively strained nickelate thin films
journal, September 2013

  • Disa, A. S.; Kumah, D. P.; Ngai, J. H.
  • APL Materials, Vol. 1, Issue 3
  • DOI: 10.1063/1.4820431

Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
journal, March 2011

  • Man, Isabela C.; Su, Hai‐Yan; Calle‐Vallejo, Federico
  • ChemCatChem, Vol. 3, Issue 7
  • DOI: 10.1002/cctc.201000397

Chemical Structures and Performance of Perovskite Oxides
journal, July 2001

  • Pena, M.; Fierro, J.
  • Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018
  • DOI: 10.1021/cr980129f

Polarity compensation in ultra-thin films of complex oxides: The case of a perovskite nickelate
journal, October 2014

  • Middey, S.; Rivero, P.; Meyers, D.
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06819

SmxNd1−xNiO3 thin-film solid solutions with tunable metal–insulator transition synthesized by alternate-target pulsed-laser deposition
journal, February 2003

  • Ambrosini, Andrea; Hamet, Jean-François
  • Applied Physics Letters, Vol. 82, Issue 5
  • DOI: 10.1063/1.1541116

Polar metals by geometric design
journal, April 2016


Brownmillerite-type Ca 2 FeCoO 5 as a Practicable Oxygen Evolution Reaction Catalyst
journal, July 2017

  • Tsuji, Etsushi; Motohashi, Teruki; Noda, Hiroyuki
  • ChemSusChem, Vol. 10, Issue 14
  • DOI: 10.1002/cssc.201701192

Progress in perovskite nickelate research
journal, July 2008


Role of Strain and Conductivity in Oxygen Electrocatalysis on LaCoO 3 Thin Films
journal, January 2015

  • Stoerzinger, Kelsey A.; Choi, Woo Seok; Jeen, Hyoungjeen
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 3
  • DOI: 10.1021/jz502692a

Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides
journal, January 2017

  • Hong, Wesley T.; Stoerzinger, Kelsey A.; Lee, Yueh-Lin
  • Energy & Environmental Science, Vol. 10, Issue 10
  • DOI: 10.1039/C7EE02052J

Strain coupling of oxygen non-stoichiometry in perovskite thin films
journal, December 2017

  • Herklotz, Andreas; Lee, Dongkyu; Guo, Er-Jia
  • Journal of Physics: Condensed Matter, Vol. 29, Issue 49
  • DOI: 10.1088/1361-648X/aa949b

Understanding the electrocatalysis of oxygen reduction on platinum and its alloys
journal, January 2012

  • Stephens, Ifan E. L.; Bondarenko, Alexander S.; Grønbjerg, Ulrik
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee03590a

Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency
journal, June 2016

  • Petrie, Jonathan R.; Jeen, Hyoungjeen; Barron, Sara C.
  • Journal of the American Chemical Society, Vol. 138, Issue 23
  • DOI: 10.1021/jacs.6b03520

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
journal, October 2013

  • McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 135, Issue 45
  • DOI: 10.1021/ja407115p

Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO 3 Perovskites
journal, February 2016

  • Petrie, Jonathan R.; Cooper, Valentino R.; Freeland, John W.
  • Journal of the American Chemical Society, Vol. 138, Issue 8
  • DOI: 10.1021/jacs.5b11713

Oxygen Diode Formed in Nickelate Heterostructures by Chemical Potential Mismatch
journal, March 2018


Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004

  • Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 46
  • DOI: 10.1021/jp047349j

Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries
journal, June 2011

  • Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki
  • Nature Chemistry, Vol. 3, Issue 7, p. 546-550
  • DOI: 10.1038/nchem.1069

Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
journal, January 2015

  • Hong, Wesley T.; Risch, Marcel; Stoerzinger, Kelsey A.
  • Energy & Environmental Science, Vol. 8, Issue 5
  • DOI: 10.1039/C4EE03869J

Reversible nano-structuring of SrCrO3-δ through oxidation and reduction at low temperature
journal, August 2014

  • Zhang, K. H. L.; Sushko, P. V.; Colby, R.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5669

Colossal resistance switching and band gap modulation in a perovskite nickelate by electron doping
journal, September 2014

  • Shi, Jian; Zhou, You; Ramanathan, Shriram
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5860

Electrochemically Driven Giant Resistive Switching in Perovskite Nickelates Heterostructures
journal, August 2017

  • Wang, Le; Zhang, Qinghua; Chang, Lei
  • Advanced Electronic Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aelm.201700321