Predicting Calendar Aging in Lithium Metal Secondary Batteries: The Impacts of Solid Electrolyte Interphase Composition and Stability
Abstract
Abstract Calendar aging of lithium metal batteries, in which cells' components degrade internally due to chemical reactions while no current is being applied, is a relatively unstudied field. In this work, a model to predict calendar aging of lithium metal cells is developed using two sets of readily obtainable data: solid electrolyte interphase (SEI) layer composition (measured via X‐ray photoelectron spectroscopy) and SEI stability (measured as a degradation rate using a simple constant current–constant voltage charging protocol). Electrolyte properties such as volume and salt concentration are varied in order to determine their effect on SEI stability and composition, with subsequent impacts to calendar aging. Lower salt concentrations produce a solvent‐based, more soluble SEI, while the highest concentration produces a salt‐based, less soluble SEI. Higher electrolyte volumes promote dissolution of the SEI and thus decrease its stability. The model predicts that lithium metal would be the limiting factor in calendar aging, depleting long before the electrolyte does. Additionally, the relative composition of the electrolyte during aging is modeled and found to eventually converge to the same value independent of initial salt concentration.
- Authors:
-
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Univ. of California San Diego, La Jolla, CA (United States)
- Publication Date:
- Research Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1473703
- Alternate Identifier(s):
- OSTI ID: 1463193
- Report Number(s):
- INL/JOU-18-45118-Rev001
Journal ID: ISSN 1614-6832
- Grant/Contract Number:
- AC07-05ID14517
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 26; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; rechargeable lithium batteries; solid electrolyte interphase (SEI) layer stability; electrolyte salt concentration; electrolyte volume; lithium metal calendar life
Citation Formats
Wood, Sean M., Fang, Chengcheng, Dufek, Eric J., Nagpure, Shrikant C., Sazhin, Sergiy V., Liaw, Boryann, and Meng, Y. Shirley. Predicting Calendar Aging in Lithium Metal Secondary Batteries: The Impacts of Solid Electrolyte Interphase Composition and Stability. United States: N. p., 2018.
Web. doi:10.1002/aenm.201801427.
Wood, Sean M., Fang, Chengcheng, Dufek, Eric J., Nagpure, Shrikant C., Sazhin, Sergiy V., Liaw, Boryann, & Meng, Y. Shirley. Predicting Calendar Aging in Lithium Metal Secondary Batteries: The Impacts of Solid Electrolyte Interphase Composition and Stability. United States. https://doi.org/10.1002/aenm.201801427
Wood, Sean M., Fang, Chengcheng, Dufek, Eric J., Nagpure, Shrikant C., Sazhin, Sergiy V., Liaw, Boryann, and Meng, Y. Shirley. Mon .
"Predicting Calendar Aging in Lithium Metal Secondary Batteries: The Impacts of Solid Electrolyte Interphase Composition and Stability". United States. https://doi.org/10.1002/aenm.201801427. https://www.osti.gov/servlets/purl/1473703.
@article{osti_1473703,
title = {Predicting Calendar Aging in Lithium Metal Secondary Batteries: The Impacts of Solid Electrolyte Interphase Composition and Stability},
author = {Wood, Sean M. and Fang, Chengcheng and Dufek, Eric J. and Nagpure, Shrikant C. and Sazhin, Sergiy V. and Liaw, Boryann and Meng, Y. Shirley},
abstractNote = {Abstract Calendar aging of lithium metal batteries, in which cells' components degrade internally due to chemical reactions while no current is being applied, is a relatively unstudied field. In this work, a model to predict calendar aging of lithium metal cells is developed using two sets of readily obtainable data: solid electrolyte interphase (SEI) layer composition (measured via X‐ray photoelectron spectroscopy) and SEI stability (measured as a degradation rate using a simple constant current–constant voltage charging protocol). Electrolyte properties such as volume and salt concentration are varied in order to determine their effect on SEI stability and composition, with subsequent impacts to calendar aging. Lower salt concentrations produce a solvent‐based, more soluble SEI, while the highest concentration produces a salt‐based, less soluble SEI. Higher electrolyte volumes promote dissolution of the SEI and thus decrease its stability. The model predicts that lithium metal would be the limiting factor in calendar aging, depleting long before the electrolyte does. Additionally, the relative composition of the electrolyte during aging is modeled and found to eventually converge to the same value independent of initial salt concentration.},
doi = {10.1002/aenm.201801427},
journal = {Advanced Energy Materials},
number = 26,
volume = 8,
place = {United States},
year = {Mon Aug 06 00:00:00 EDT 2018},
month = {Mon Aug 06 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Problem, Status, and Possible Solutions for Lithium Metal Anode of Rechargeable Batteries
journal, February 2018
- Zhang, Sheng S.
- ACS Applied Energy Materials, Vol. 1, Issue 3
High rate and stable cycling of lithium metal anode
journal, February 2015
- Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
- Nature Communications, Vol. 6, Issue 1
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017
- Albertus, Paul; Babinec, Susan; Litzelman, Scott
- Nature Energy, Vol. 3, Issue 1
Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal
journal, January 2017
- Pei, Allen; Zheng, Guangyuan; Shi, Feifei
- Nano Letters, Vol. 17, Issue 2
Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes
journal, January 2017
- Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric
- Journal of Materials Chemistry A, Vol. 5, Issue 23
Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High-Concentration Electrolyte Layer
journal, February 2016
- Zheng, Jianming; Yan, Pengfei; Mei, Donghai
- Advanced Energy Materials, Vol. 6, Issue 8
Anode-Free Rechargeable Lithium Metal Batteries
journal, August 2016
- Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming
- Advanced Functional Materials, Vol. 26, Issue 39
Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy
journal, October 2016
- Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F.
- ACS Central Science, Vol. 2, Issue 11
Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
journal, October 2017
- Adams, Brian D.; Zheng, Jianming; Ren, Xiaodi
- Advanced Energy Materials, Vol. 8, Issue 7
Addressing Passivation in Lithium-Sulfur Battery Under Lean Electrolyte Condition
journal, February 2018
- Pan, Huilin; Han, Kee Sung; Engelhard, Mark H.
- Advanced Functional Materials, Vol. 28, Issue 38
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes
journal, September 2014
- Lu, Dongping; Shao, Yuyan; Lozano, Terence
- Advanced Energy Materials, Vol. 5, Issue 3
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013
- Suo, Liumin; Hu, Yong-Sheng; Li, Hong
- Nature Communications, Vol. 4, Issue 1
Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016
- Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro
- Nature Communications, Vol. 7, Issue 1
Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications
journal, March 2017
- Zheng, Jianming; Lochala, Joshua A.; Kwok, Alexander
- Advanced Science, Vol. 4, Issue 8
Calendar Aging of Lithium-Ion Batteries: I. Impact of the Graphite Anode on Capacity Fade
journal, January 2016
- Keil, Peter; Schuster, Simon F.; Wilhelm, Jörn
- Journal of The Electrochemical Society, Vol. 163, Issue 9
Role of Solution Structure in Solid Electrolyte Interphase Formation on Graphite with LiPF 6 in Propylene Carbonate
journal, November 2013
- Nie, Mengyun; Abraham, Daniel P.; Seo, Daniel M.
- The Journal of Physical Chemistry C, Vol. 117, Issue 48
Investigation of the Lithium Solid Electrolyte Interphase in Vinylene Carbonate Electrolytes Using Cu||LiFePO 4 Cells
journal, January 2017
- Brown, Zachary L.; Jurng, Sunhyung; Lucht, Brett L.
- Journal of The Electrochemical Society, Vol. 164, Issue 9
Effect of Vinylene Carbonate and Fluoroethylene Carbonate on SEI Formation on Graphitic Anodes in Li-Ion Batteries
journal, January 2015
- Nie, Mengyun; Demeaux, Julien; Young, Benjamin T.
- Journal of The Electrochemical Society, Vol. 162, Issue 13
Electrochemical and Infrared Studies of the Reduction of Organic Carbonates
journal, January 2001
- Zhang, Xuerong; Kostecki, Robert; Richardson, Thomas J.
- Journal of The Electrochemical Society, Vol. 148, Issue 12
K + Reduces Lithium Dendrite Growth by Forming a Thin, Less-Resistive Solid Electrolyte Interphase
journal, July 2016
- Wood, Sean M.; Pham, Codey H.; Rodriguez, Rodrigo
- ACS Energy Letters, Vol. 1, Issue 2
The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries
journal, January 2009
- El Ouatani, L.; Dedryvère, R.; Siret, C.
- Journal of The Electrochemical Society, Vol. 156, Issue 2
X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade
journal, November 2004
- Herstedt, M.; Abraham, D. P.; Kerr, J. B.
- Electrochimica Acta, Vol. 49, Issue 28
A comparative XPS surface study of Li 2 FeSiO 4 /C cycled with LiTFSI- and LiPF 6 -based electrolytes
journal, January 2009
- Ensling, David; Stjerndahl, Mårten; Nytén, Anton
- J. Mater. Chem., Vol. 19, Issue 1
Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF 6 , LiBF 4 , LiDFOB, LiBOB, and LiTFSI
journal, January 2018
- Parimalam, Bharathy S.; Lucht, Brett L.
- Journal of The Electrochemical Society, Vol. 165, Issue 2
A Comparative Study of Synthetic Graphite and Li Electrodes in Electrolyte Solutions Based on Ethylene Carbonate-Dimethyl Carbonate Mixtures
journal, January 1996
- Aurbach, D.
- Journal of The Electrochemical Society, Vol. 143, Issue 12
X-ray Photoelectron Spectroscopy Studies of Lithium Surfaces Prepared in Several Important Electrolyte Solutions. A Comparison with Previous Studies by Fourier Transform Infrared Spectroscopy
journal, January 1996
- Aurbach, Doron; Weissman, Idit; Schechter, Alexander
- Langmuir, Vol. 12, Issue 16
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries
journal, August 2000
- Aurbach, Doron
- Journal of Power Sources, Vol. 89, Issue 2
Lithium Ion Solvation and Diffusion in Bulk Organic Electrolytes from First-Principles and Classical Reactive Molecular Dynamics
journal, January 2015
- Ong, Mitchell T.; Verners, Osvalds; Draeger, Erik W.
- The Journal of Physical Chemistry B, Vol. 119, Issue 4
Role of Mixed Solvation and Ion Pairing in the Solution Structure of Lithium Ion Battery Electrolytes
journal, June 2015
- Seo, Daniel M.; Reininger, Stefanie; Kutcher, Mary
- The Journal of Physical Chemistry C, Vol. 119, Issue 25
A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015
- Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi
- Advanced Science, Vol. 3, Issue 3
X-ray photoelectron spectroscopy for sulfide glass electrolytes in the systems Li<sub>2</sub>S–P<sub>2</sub>S<sub>5</sub> and Li<sub>2</sub>S–P<sub>2</sub>S<sub>5</sub>–LiBr
journal, January 2016
- Wang, Yiqun; Matsuyama, Takuya; Deguchi, Minako
- Journal of the Ceramic Society of Japan, Vol. 124, Issue 5
Excitation Energy Dependence for the Li 1s X-ray Photoelectron Spectra of LiMn2O4
journal, January 2005
- Tsuji, Junichi; Fujita, Manabu; Haruyama, Yuichi
- Analytical Sciences, Vol. 21, Issue 7
A novel and accurate analytical method based on X-ray photoelectron spectroscopy for the quantitative detection of the lithium content in LiFePO 4
journal, January 2014
- Xiong, Wei; Hu, Qinghua; Liu, Shantang
- Analytical Methods, Vol. 6, Issue 15
Highly Quantitative Electrochemical Characterization of Non-Aqueous Electrolytes and Solid Electrolyte Interphases
journal, December 2013
- Sazhin, Sergiy V.; Gering, Kevin L.; Harrup, Mason K.
- Journal of The Electrochemical Society, Vol. 161, Issue 3
Works referencing / citing this record:
Correlation between Li Plating Behavior and Surface Characteristics of Carbon Matrix toward Stable Li Metal Anodes
journal, November 2018
- Cui, Jiang; Yao, Shanshan; Ihsan-Ul-Haq, Muhammad
- Advanced Energy Materials, Vol. 9, Issue 1
Room‐Temperature Rechargeable Ca‐Ion Based Hybrid Batteries with High Rate Capability and Long‐Term Cycling Life
journal, June 2019
- Lang, Jihui; Jiang, Chunlei; Fang, Yue
- Advanced Energy Materials, Vol. 9, Issue 29
On the Reliability of Sodium Metal Anodes: The Influence of Neglected Parameters
journal, January 2019
- Rupp, Rico; Vlad, Alexandru
- Journal of The Electrochemical Society, Vol. 166, Issue 14