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Title: Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering

Abstract

Abstract High‐efficiency and low‐cost perovskite solar cells (PVKSCs) are an ideal candidate for addressing the scalability challenge of solar‐based renewable energy. The dynamically evolving research field of PVKSCs has made immense progress in solving inherent challenges and capitalizing on their unique structure–property–processing–performance traits. This review offers a unique outlook on the paths toward commercialization of PVKSCs from the interfacial engineering perspective, relevant to both specialists and nonspecialists in the field through a brief introduction of the background of the field, current state‐of‐the‐art evolution, and future research prospects. The multifaceted role of interfaces in facilitating PVKSC development is explained. Beneficial impacts of diverse charge‐transporting materials and interfacial modifications are summarized. In addition, the role of interfaces in improving efficiency and stability for all emerging areas of PVKSC design are also evaluated. The authors' integral contributions in this area are highlighted on all fronts. Finally, future research opportunities for interfacial material development and applications along with scalability–durability–sustainability considerations pivotal for facilitating laboratory to industry translation are presented.

Authors:
 [1];  [2]; ORCiD logo [3]
  1. Department of Materials Science and Engineering University of Washington Seattle WA 98195 USA
  2. Institute of Photovoltaics Nanchang University 999 Xuefu Avenue Nanchang 330031 China
  3. Department of Materials Science and Engineering University of Washington Seattle WA 98195 USA, Department of Materials Science and Engineering City University of Hong Kong Kowloon 999077 Hong Kong
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1463192
Grant/Contract Number:  
DE‐EE 0006710
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 30 Journal Issue: 32; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Rajagopal, Adharsh, Yao, Kai, and Jen, Alex K. ‐Y. Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering. Germany: N. p., 2018. Web. doi:10.1002/adma.201800455.
Rajagopal, Adharsh, Yao, Kai, & Jen, Alex K. ‐Y. Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering. Germany. https://doi.org/10.1002/adma.201800455
Rajagopal, Adharsh, Yao, Kai, and Jen, Alex K. ‐Y. Fri . "Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering". Germany. https://doi.org/10.1002/adma.201800455.
@article{osti_1463192,
title = {Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering},
author = {Rajagopal, Adharsh and Yao, Kai and Jen, Alex K. ‐Y.},
abstractNote = {Abstract High‐efficiency and low‐cost perovskite solar cells (PVKSCs) are an ideal candidate for addressing the scalability challenge of solar‐based renewable energy. The dynamically evolving research field of PVKSCs has made immense progress in solving inherent challenges and capitalizing on their unique structure–property–processing–performance traits. This review offers a unique outlook on the paths toward commercialization of PVKSCs from the interfacial engineering perspective, relevant to both specialists and nonspecialists in the field through a brief introduction of the background of the field, current state‐of‐the‐art evolution, and future research prospects. The multifaceted role of interfaces in facilitating PVKSC development is explained. Beneficial impacts of diverse charge‐transporting materials and interfacial modifications are summarized. In addition, the role of interfaces in improving efficiency and stability for all emerging areas of PVKSC design are also evaluated. The authors' integral contributions in this area are highlighted on all fronts. Finally, future research opportunities for interfacial material development and applications along with scalability–durability–sustainability considerations pivotal for facilitating laboratory to industry translation are presented.},
doi = {10.1002/adma.201800455},
journal = {Advanced Materials},
number = 32,
volume = 30,
place = {Germany},
year = {Fri Jun 08 00:00:00 EDT 2018},
month = {Fri Jun 08 00:00:00 EDT 2018}
}

Journal Article:
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https://doi.org/10.1002/adma.201800455

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16.1% Efficient Hysteresis-Free Mesostructured Perovskite Solar Cells Based on Synergistically Improved ZnO Nanorod Arrays
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A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability
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A diketopyrrolopyrrole-containing hole transporting conjugated polymer for use in efficient stable organic–inorganic hybrid solar cells based on a perovskite
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Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers
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Anomalous Band Gap Behavior in Mixed Sn and Pb Perovskites Enables Broadening of Absorption Spectrum in Solar Cells
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Molecular Engineered Hole-Extraction Materials to Enable Dopant-Free, Efficient p-i-n Perovskite Solar Cells
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Isomer-Pure Bis-PCBM-Assisted Crystal Engineering of Perovskite Solar Cells Showing Excellent Efficiency and Stability
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All-Solid Perovskite Solar Cells with HOCO-R-NH 3 + I Anchor-Group Inserted between Porous Titania and Perovskite
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Efficient Indium-Doped TiO x Electron Transport Layers for High-Performance Perovskite Solar Cells and Perovskite-Silicon Tandems
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Triarylamine: Versatile Platform for Organic, Dye-Sensitized, and Perovskite Solar Cells
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Well-Defined Thiolated Nanographene as Hole-Transporting Material for Efficient and Stable Perovskite Solar Cells
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Performance enhancement of perovskite solar cells with Mg-doped TiO 2 compact film as the hole-blocking layer
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Bulk heterojunction perovskite hybrid solar cells with large fill factor
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Influence of Charge Transport and Defects on the Performance of Planar and Mesostructured Perovskite Solar Cells
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Pinhole-Free Hybrid Perovskite Film with Arbitrarily-Shaped Micro-Patterns for Functional Optoelectronic Devices
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In situ observation of heat-induced degradation of perovskite solar cells
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Improved Optics in Monolithic Perovskite/Silicon Tandem Solar Cells with a Nanocrystalline Silicon Recombination Junction
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A molecularly engineered hole-transporting material for efficient perovskite solar cells
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Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance
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Functionalization of perovskite thin films with moisture-tolerant molecules
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Review on up/down conversion materials for solar cell application
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Nb 2 O 5 Blocking Layer for High Open-circuit Voltage Perovskite Solar Cells
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Improving Interfacial Charge Recombination in Planar Heterojunction Perovskite Photovoltaics with Small Molecule as Electron Transport Layer
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Stable Inverted Planar Perovskite Solar Cells with Low-Temperature-Processed Hole-Transport Bilayer
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Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
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High-Efficiency Perovskite Solar Cell Based on Poly(3-Hexylthiophene): Influence of Molecular Weight and Mesoscopic Scaffold Layer
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Light-Induced Anion Phase Segregation in Mixed Halide Perovskites
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Scaffold-reinforced perovskite compound solar cells
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Effects of Surface Blocking Layer of Sb 2 S 3 on Nanocrystalline TiO 2 for CH 3 NH 3 PbI 3 Perovskite Solar Cells
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Interface passivation using ultrathin polymer–fullerene films for high-efficiency perovskite solar cells with negligible hysteresis
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Ideal Bandgap Organic-Inorganic Hybrid Perovskite Solar Cells
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Stability Comparison of Perovskite Solar Cells Based on Zinc Oxide and Titania on Polymer Substrates
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Lead-free solid-state organic–inorganic halide perovskite solar cells
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Long-Lasting Nanophosphors Applied to UV-Resistant and Energy Storage Perovskite Solar Cells
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A solution-processed bathocuproine cathode interfacial layer for high-performance bromine–iodine perovskite solar cells
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Inverted Perovskite Solar Cells: Progresses and Perspectives
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Multifunctional Fullerene Derivative for Interface Engineering in Perovskite Solar Cells
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Enhanced Electronic Properties of SnO 2 via Electron Transfer from Graphene Quantum Dots for Efficient Perovskite Solar Cells
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Mixed Cation FA x PEA 1- x PbI 3 with Enhanced Phase and Ambient Stability toward High-Performance Perovskite Solar Cells
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Dopant-Free Hole-Transporting Materials for Stable and Efficient Perovskite Solar Cells
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Low-temperature processed meso-superstructured to thin-film perovskite solar cells
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Fully Solution-Processed n-i-p-Like Perovskite Solar Cells with Planar Junction: How the Charge Extracting Layer Determines the Open-Circuit Voltage
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Perovskite Oxide SrTiO 3 as an Efficient Electron Transporter for Hybrid Perovskite Solar Cells
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Shift Happens . How Halide Ion Defects Influence Photoinduced Segregation in Mixed Halide Perovskites
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High-Performance Flexible Perovskite Solar Cells on Ultrathin Glass: Implications of the TCO
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A Victim of Halide Ion Segregation. How Light Soaking Affects Solar Cell Performance of Mixed Halide Lead Perovskites
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Interfaces in Perovskite Solar Cells
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Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability
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Relationships between Lead Halide Perovskite Thin-Film Fabrication, Morphology, and Performance in Solar Cells
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Superflexible, high-efficiency perovskite solar cells utilizing graphene electrodes: towards future foldable power sources
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Low-Temperature Processed Electron Collection Layers of Graphene/TiO2 Nanocomposites in Thin Film Perovskite Solar Cells
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Thermodynamic origin of instability in hybrid halide perovskites
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Efficiency and Stability Enhancement in Perovskite Solar Cells by Inserting Lithium-Neutralized Graphene Oxide as Electron Transporting Layer
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Nonradiative Losses in Metal Halide Perovskites
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Efficient Semitransparent Perovskite Solar Cells with Graphene Electrodes
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Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
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Light-Induced Phase Segregation in Halide-Perovskite Absorbers
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Highly Efficient and Stable Perovskite Solar Cells Enabled by All-Crosslinked Charge-Transporting Layers
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Toward Lead-Free Perovskite Solar Cells
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Progress, challenges and perspectives in flexible perovskite solar cells
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The Significance of Ion Conduction in a Hybrid Organic-Inorganic Lead-Iodide-Based Perovskite Photosensitizer
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Highly-Efficient and Long-Term Stable Perovskite Solar Cells Enabled by a Cross-Linkable n -Doped Hybrid Cathode Interfacial Layer
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Efficiency Enhancement of Perovskite Solar Cells through Fast Electron Extraction: The Role of Graphene Quantum Dots
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p-type Mesoscopic Nickel Oxide/Organometallic Perovskite Heterojunction Solar Cells
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Perovskite Solar Cells: The Birth of a New Era in Photovoltaics
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Cooperative Effect of GO and Glucose on PEDOT:PSS for High V OC and Hysteresis-Free Solution-Processed Perovskite Solar Cells
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Unraveling the Light-Induced Degradation Mechanisms of CH 3 NH 3 PbI 3 Perovskite Films
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Donor-Acceptor Type Dopant-Free, Polymeric Hole Transport Material for Planar Perovskite Solar Cells (19.8%)
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Nanocrystalline Rutile Electron Extraction Layer Enables Low-Temperature Solution Processed Perovskite Photovoltaics with 13.7% Efficiency
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Trapped charge-driven degradation of perovskite solar cells
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Perovskite–fullerene hybrid materials suppress hysteresis in planar diodes
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Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells
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Beyond the learning curve: factors influencing cost reductions in photovoltaics
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Charge-Carrier Dynamics in Organic-Inorganic Metal Halide Perovskites
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Highly Efficient Electron Transport Obtained by Doping PCBM with Graphdiyne in Planar-Heterojunction Perovskite Solar Cells
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Understanding Interface Engineering for High-Performance Fullerene/Perovskite Planar Heterojunction Solar Cells
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Roadmap and roadblocks for the band gap tunability of metal halide perovskites
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The Progress of Interface Design in Perovskite-Based Solar Cells
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Surface optimization to eliminate hysteresis for record efficiency planar perovskite solar cells
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Iodide-reduced graphene oxide with dopant-free spiro-OMeTAD for ambient stable and high-efficiency perovskite solar cells
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Dopant-free polymeric hole transport materials for highly efficient and stable perovskite solar cells
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Progress in Tandem Solar Cells Based on Hybrid Organic-Inorganic Perovskites
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Perovskite Tandem Solar Cells
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High-Performance Integrated Perovskite and Organic Solar Cells with Enhanced Fill Factors and Near-Infrared Harvesting
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Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells
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Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation
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Universal energy level tailoring of self-organized hole extraction layers in organic solar cells and organic–inorganic hybrid perovskite solar cells
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CH3NH3PbI3 Perovskite Sensitized Solar Cells Using a D-A Copolymer as Hole Transport Material
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Induced Crystallization of Perovskites by a Perylene Underlayer for High-Performance Solar Cells
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Origin of the Thermal Instability in CH 3 NH 3 PbI 3 Thin Films Deposited on ZnO
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Enhancement of the Performance of Perovskite Solar Cells, LEDs, and Optical Amplifiers by Anti-Solvent Additive Deposition
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Temperature-Dependent Charge-Carrier Dynamics in CH 3 NH 3 PbI 3 Perovskite Thin Films
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Oxygen Degradation in Mesoporous Al 2 O 3 /CH 3 NH 3 PbI 3- x Cl x Perovskite Solar Cells: Kinetics and Mechanisms
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Improving Perovskite Solar Cells: Insights From a Validated Device Model
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Metal halide perovskites for energy applications
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Gas-Induced Formation/Transformation of Organic–Inorganic Halide Perovskites
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Low-bandgap mixed tin–lead iodide perovskite absorbers with long carrier lifetimes for all-perovskite tandem solar cells
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Spiro-Phenylpyrazole-9,9′-Thioxanthene Analogues as Hole-Transporting Materials for Efficient Planar Perovskite Solar Cells
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Nonstoichiometric Adduct Approach for High-Efficiency Perovskite Solar Cells
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Interface engineering of highly efficient perovskite solar cells
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Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation
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High-Performance Hole-Extraction Layer of Sol-Gel-Processed NiO Nanocrystals for Inverted Planar Perovskite Solar Cells
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Defect Passivation of Organic–Inorganic Hybrid Perovskites by Diammonium Iodide toward High-Performance Photovoltaic Devices
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Effect of Photogenerated Dipoles in the Hole Transport Layer on Photovoltaic Performance of Organic-Inorganic Perovskite Solar Cells
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Efficient and Air-Stable Mixed-Cation Lead Mixed-Halide Perovskite Solar Cells with n-Doped Organic Electron Extraction Layers
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Achieving Large-Area Planar Perovskite Solar Cells by Introducing an Interfacial Compatibilizer
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Air-stable, hole-conductor-free high photocurrent perovskite solar cells with CH3NH3PbI3–NiO nanoparticles composite
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Efficient Semitransparent Perovskite Solar Cells for 23.0%-Efficiency Perovskite/Silicon Four-Terminal Tandem Cells
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Perovskite and Organic Solar Cells Fabricated by Inkjet Printing: Progress and Prospects
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Lead-Free Organic-Inorganic Hybrid Perovskites for Photovoltaic Applications: Recent Advances and Perspectives
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Perovskite ink with wide processing window for scalable high-efficiency solar cells
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Inverted Current-Voltage Hysteresis in Mixed Perovskite Solar Cells: Polarization, Energy Barriers, and Defect Recombination
journal, July 2016

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Dual Interfacial Modifications Enable High Performance Semitransparent Perovskite Solar Cells with Large Open Circuit Voltage and Fill Factor
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Phenylalkylamine Passivation of Organolead Halide Perovskites Enabling High-Efficiency and Air-Stable Photovoltaic Cells
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Non-Conjugated Polymer as an Efficient Dopant-Free Hole-Transporting Material for Perovskite Solar Cells
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Liquid Water- and Heat-Resistant Hybrid Perovskite Photovoltaics via an Inverted ALD Oxide Electron Extraction Layer Design
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Low Temperature Solution-Processed Sb:SnO 2 Nanocrystals for Efficient Planar Perovskite Solar Cells
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Emergence of highly transparent photovoltaics for distributed applications
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Perovskite/Silicon Tandem Solar Cells: Marriage of Convenience or True Love Story? - An Overview
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Contact Engineering: Electrode Materials for Highly Efficient and Stable Perovskite Solar Cells
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Identifying and suppressing interfacial recombination to achieve high open-circuit voltage in perovskite solar cells
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Making and Breaking of Lead Halide Perovskites
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A–D–A-type S,N-heteropentacene-based hole transport materials for dopant-free perovskite solar cells
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Hexagonal β-NaYF 4 :Yb 3+ , Er 3+ Nanoprism-Incorporated Upconverting Layer in Perovskite Solar Cells for Near-Infrared Sunlight Harvesting
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Synthesis and use of a hyper-connecting cross-linking agent in the hole-transporting layer of perovskite solar cells
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Cross-Linkable Fullerene Derivatives for Solution-Processed n–i–p Perovskite Solar Cells
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Light and Electrically Induced Phase Segregation and Its Impact on the Stability of Quadruple Cation High Bandgap Perovskite Solar Cells
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An Hydrophilic Anode Interlayer for Solution Processed Organohalide Perovskite Solar Cells
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Nonhazardous Solvent Systems for Processing Perovskite Photovoltaics
journal, May 2016

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Stabilized Wide Bandgap Perovskite Solar Cells by Tin Substitution
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Optoelectronic Quality and Stability of Hybrid Perovskites from MAPbI 3 to MAPbI 2 Br Using Composition Spread Libraries
journal, January 2016

  • Braly, Ian L.; Hillhouse, Hugh W.
  • The Journal of Physical Chemistry C, Vol. 120, Issue 2
  • DOI: 10.1021/acs.jpcc.5b10728

Photoluminescence Lifetimes Exceeding 8 μs and Quantum Yields Exceeding 30% in Hybrid Perovskite Thin Films by Ligand Passivation
journal, July 2016


Noncapacitive Hysteresis in Perovskite Solar Cells at Room Temperature
journal, June 2016


Semi-transparent Perovskite Solar Cells Developed by Considering Human Luminosity Function
journal, September 2017


Templated microstructural growth of perovskite thin films via colloidal monolayer lithography
journal, January 2015

  • Hörantner, M. T.; Zhang, W.; Saliba, M.
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE01169H

CuSCN-Based Inverted Planar Perovskite Solar Cell with an Average PCE of 15.6%
journal, May 2015


Conjugated Small Molecule for Efficient Hole Transport in High-Performance p-i-n Type Perovskite Solar Cells
journal, July 2017

  • Yang, Liyan; Cai, Feilong; Yan, Yu
  • Advanced Functional Materials, Vol. 27, Issue 31
  • DOI: 10.1002/adfm.201702613