Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps
Abstract
Here, applications of cryogenic ion traps for forming reaction intermediates and solvated clusters from precursor ions generated by electrospray ionization are presented and discussed. These studies are motivated by the aim of spectroscopically probing isolated complexes that exhibit higher levels of complexity in chemical compositions and intermolecular interactions, which make them more closely resemble the systems existing in real-world environments. Illustrative examples are provided to highlight the current capabilities, showcase the detailed information available in the spectroscopic results, and outline general future directions.
- Authors:
-
- Department of Chemistry, University of Wisconsin—Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States
- Publication Date:
- Research Org.:
- Univ. of Wisconsin, Madison, WI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1463034
- Alternate Identifier(s):
- OSTI ID: 1469205; OSTI ID: 1508602
- Grant/Contract Number:
- SC0010326; CHE-1454086
- Resource Type:
- Published Article
- Journal Name:
- Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
- Additional Journal Information:
- Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Volume: 122 Journal Issue: 32; Journal ID: ISSN 1089-5639
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Garand, Etienne. Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps. United States: N. p., 2018.
Web. doi:10.1021/acs.jpca.8b05712.
Garand, Etienne. Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps. United States. doi:10.1021/acs.jpca.8b05712.
Garand, Etienne. Wed .
"Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps". United States. doi:10.1021/acs.jpca.8b05712.
@article{osti_1463034,
title = {Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps},
author = {Garand, Etienne},
abstractNote = {Here, applications of cryogenic ion traps for forming reaction intermediates and solvated clusters from precursor ions generated by electrospray ionization are presented and discussed. These studies are motivated by the aim of spectroscopically probing isolated complexes that exhibit higher levels of complexity in chemical compositions and intermolecular interactions, which make them more closely resemble the systems existing in real-world environments. Illustrative examples are provided to highlight the current capabilities, showcase the detailed information available in the spectroscopic results, and outline general future directions.},
doi = {10.1021/acs.jpca.8b05712},
journal = {Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory},
number = 32,
volume = 122,
place = {United States},
year = {2018},
month = {7}
}
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1021/acs.jpca.8b05712
DOI: 10.1021/acs.jpca.8b05712
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Cited by: 4 works
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Works referencing / citing this record:
Electrospray ionization photoelectron spectroscopy of cryogenic [EDTA·M( ii )] 2− complexes (M = Ca, V–Zn): electronic structures and intrinsic redox properties
journal, January 2019
- Yuan, Qinqin; Kong, Xiang-Tao; Hou, Gao-Lei
- Faraday Discussions, Vol. 217
Electrospray ionization photoelectron spectroscopy of cryogenic [EDTA·M( ii )] 2− complexes (M = Ca, V–Zn): electronic structures and intrinsic redox properties
journal, January 2019
- Yuan, Qinqin; Kong, Xiang-Tao; Hou, Gao-Lei
- Faraday Discussions, Vol. 217
Identification of Active Sites and Structural Characterization of Reactive Ionic Intermediates by Cryogenic Ion Trap Vibrational Spectroscopy
journal, January 2019
- Schwarz, Helmut; Asmis, Knut R.
- Chemistry - A European Journal, Vol. 25, Issue 9
High-resolution photoelectron imaging and resonant photoelectron spectroscopy via noncovalently bound excited states of cryogenically cooled anions
journal, January 2019
- Zhu, Guo-Zhu; Wang, Lai-Sheng
- Chemical Science, Vol. 10, Issue 41