Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps
Here, applications of cryogenic ion traps for forming reaction intermediates and solvated clusters from precursor ions generated by electrospray ionization are presented and discussed. These studies are motivated by the aim of spectroscopically probing isolated complexes that exhibit higher levels of complexity in chemical compositions and intermolecular interactions, which make them more closely resemble the systems existing in real-world environments. Illustrative examples are provided to highlight the current capabilities, showcase the detailed information available in the spectroscopic results, and outline general future directions.
- Authors:
-
[1]
- Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry
- Publication Date:
- Grant/Contract Number:
- SC0010326; CHE-1454086
- Type:
- Published Article
- Journal Name:
- Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
- Additional Journal Information:
- Journal Volume: 122; Journal Issue: 32; Journal ID: ISSN 1089-5639
- Publisher:
- American Chemical Society
- Research Org:
- Univ. of Wisconsin, Madison, WI (United States)
- Sponsoring Org:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
- OSTI Identifier:
- 1463034
- Alternate Identifier(s):
- OSTI ID: 1469205
Garand, Etienne. Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps. United States: N. p.,
Web. doi:10.1021/acs.jpca.8b05712.
Garand, Etienne. Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps. United States. doi:10.1021/acs.jpca.8b05712.
Garand, Etienne. 2018.
"Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps". United States.
doi:10.1021/acs.jpca.8b05712.
@article{osti_1463034,
title = {Spectroscopy of Reactive Complexes and Solvated Clusters: A Bottom-Up Approach Using Cryogenic Ion Traps},
author = {Garand, Etienne},
abstractNote = {Here, applications of cryogenic ion traps for forming reaction intermediates and solvated clusters from precursor ions generated by electrospray ionization are presented and discussed. These studies are motivated by the aim of spectroscopically probing isolated complexes that exhibit higher levels of complexity in chemical compositions and intermolecular interactions, which make them more closely resemble the systems existing in real-world environments. Illustrative examples are provided to highlight the current capabilities, showcase the detailed information available in the spectroscopic results, and outline general future directions.},
doi = {10.1021/acs.jpca.8b05712},
journal = {Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory},
number = 32,
volume = 122,
place = {United States},
year = {2018},
month = {7}
}