Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO2 by Ionic Liquids

Huang, Yanjie; Cui, Guokai; Zhao, Yuling; Wang, Huiyong; Li, Zhiyong; Dai, Sheng; Wang, Jianji

doi:10.1002/anie.201706280

Title: Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO₂ by Ionic Liquids

Journal Article · 31 August 2017 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201706280 · OSTI ID:1462885

Huang, Yanjie ^[1];

^[2]; Zhao, Yuling ^[1]; Wang, Huiyong ^[1]; Li, Zhiyong ^[1];

^[3];

^[1]

Henan Normal Univ., Henan (China)
Henan Normal Univ., Henan (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Here, a novel strategy based on the concept of preorganization and cooperation has been designed for a superior capacity to capture low–concentration CO₂ by imide–based ionic liquids. By using this strategy, for the first time, an extremely high gravimetric CO₂ capacity of up to 22 wt % (1.65 mol mol^–1) and excellent reversibility (16 cycles) have been achieved from 10 vol. % of CO₂ in N₂ when using an ionic liquid having a preorganized anion. Through a combination of quantum–chemical calculations and spectroscopic investigations, it is suggested that cooperative interactions between CO₂ and multiple active sites in the preorganized anion are the driving force for the superior CO₂ capacity and excellent reversibility.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1462885

Journal Information:: Angewandte Chemie (International Edition), Vol. 56, Issue 43; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 108 works

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Development of High‐Capacity and Water‐Lean CO ₂ Absorbents by a Concise Molecular Design Strategy through Viscosity Control Liu, An‐Hua; Li, Jie‐Jie; Ren, Bai‐Hao ChemSusChem, Vol. 12, Issue 23 https://doi.org/10.1002/cssc.201902279	journal	November 2019
Choline-based ionic liquids for CO2 capture and conversion Li, Ruipeng; Zhao, Yanfei; Li, Zhiyong Science China Chemistry, Vol. 62, Issue 2 https://doi.org/10.1007/s11426-018-9358-6	journal	November 2018
Ether-functionalization of monoethanolamine (MEA) for reversible CO ₂ capture under solvent-free conditions with high-capacity and low-viscosity Liu, An-Hua; Li, Jie-Jie; Ren, Bai-Hao Sustainable Energy & Fuels, Vol. 4, Issue 3 https://doi.org/10.1039/c9se00756c	journal	January 2020
Reply to the Correspondence on “Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low‐Concentration CO ₂ by Ionic Liquids” Huang, Yanjie; Cui, Guokai; Zhao, Yuling Angewandte Chemie https://doi.org/10.1002/ange.201808486	journal	December 2018

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
anions
carbon dioxide fixation
cooperative effects
ionic liquids
preorganization

Title: Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO2 by Ionic Liquids

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Title: Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO₂ by Ionic Liquids