Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface
Abstract
Here, we have developed a proof of concept electrode design to covalently graft poly(methyl methacrylate) brushes directly to silicon thin film electrodes via surface-initiated atom transfer radical polymerization. This polymer layer acts as a stable artificial solid electrolyte interface that enables surface passivation despite large volume changes during cycling. Thin polymer layers (75 nm) improve average first cycle coulombic efficiency from 62.4% in bare silicon electrodes to 76.3%. Average first cycle reversible capacity was improved from 3157 to 3935 mAh g-1, and average irreversible capacity was reduced from 2011 to 1020 mAh g-1. Electrochemical impedance spectroscopy performed on silicon electrodes showed that resistance from solid electrolyte interface formation increased from 79 to 1508 Ω in untreated silicon thin films over 26 cycles, while resistance growth was lower – from 98 to 498 Ω – in silicon films functionalized with PMMA brushes. The lower increase suggests enhanced surface passivation and lower electrolyte degradation. This work provides a pathway to develop artificial solid electrolyte interfaces synthesized under controlled reaction conditions.
- Authors:
-
[2];
- Univ. of Rochester, NY (United States). Dept. of Chemical Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1462871
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 8; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Shen, Brian H., Veith, Gabriel M., and Tenhaeff, Wyatt E.. Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface. United States: N. p., 2018.
Web. doi:10.1038/s41598-018-30000-z.
Shen, Brian H., Veith, Gabriel M., & Tenhaeff, Wyatt E.. Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface. United States. https://doi.org/10.1038/s41598-018-30000-z
Shen, Brian H., Veith, Gabriel M., and Tenhaeff, Wyatt E.. Wed .
"Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface". United States. https://doi.org/10.1038/s41598-018-30000-z. https://www.osti.gov/servlets/purl/1462871.
@article{osti_1462871,
title = {Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface},
author = {Shen, Brian H. and Veith, Gabriel M. and Tenhaeff, Wyatt E.},
abstractNote = {Here, we have developed a proof of concept electrode design to covalently graft poly(methyl methacrylate) brushes directly to silicon thin film electrodes via surface-initiated atom transfer radical polymerization. This polymer layer acts as a stable artificial solid electrolyte interface that enables surface passivation despite large volume changes during cycling. Thin polymer layers (75 nm) improve average first cycle coulombic efficiency from 62.4% in bare silicon electrodes to 76.3%. Average first cycle reversible capacity was improved from 3157 to 3935 mAh g-1, and average irreversible capacity was reduced from 2011 to 1020 mAh g-1. Electrochemical impedance spectroscopy performed on silicon electrodes showed that resistance from solid electrolyte interface formation increased from 79 to 1508 Ω in untreated silicon thin films over 26 cycles, while resistance growth was lower – from 98 to 498 Ω – in silicon films functionalized with PMMA brushes. The lower increase suggests enhanced surface passivation and lower electrolyte degradation. This work provides a pathway to develop artificial solid electrolyte interfaces synthesized under controlled reaction conditions.},
doi = {10.1038/s41598-018-30000-z},
journal = {Scientific Reports},
number = ,
volume = 8,
place = {United States},
year = {2018},
month = {8}
}
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Works referenced in this record:
Low temperature bonding of PMMA and COC microfluidic substrates using UV/ozone surface treatment
journal, January 2007
- Tsao, C. W.; Hromada, L.; Liu, J.
- Lab on a Chip, Vol. 7, Issue 4
The Chemistry of Electrolyte Reduction on Silicon Electrodes Revealed by in Situ ATR-FTIR Spectroscopy
journal, June 2017
- Shi, Feifei; Ross, Philip N.; Somorjai, Gabor A.
- The Journal of Physical Chemistry C, Vol. 121, Issue 27
XPS and AFM surface studies of solvent-cast PS/PMMA blends
journal, February 2001
- Ton-That, C.; Shard, A. G.; Teare, D. O. H.
- Polymer, Vol. 42, Issue 3
A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes
journal, February 2016
- Higgins, Thomas M.; Park, Sang-Hoon; King, Paul J.
- ACS Nano, Vol. 10, Issue 3
Lithium insertion into amorphous silicon thin-film electrodes
journal, February 2007
- Kulova, T. L.; Skundin, A. M.; Pleskov, Yu. V.
- Journal of Electroanalytical Chemistry, Vol. 600, Issue 1
A review of the electrochemical performance of alloy anodes for lithium-ion batteries
journal, January 2011
- Zhang, Wei-Jun
- Journal of Power Sources, Vol. 196, Issue 1
AFM and XPS study of UV-irradiated poly(methyl methacrylate) films on glass and aluminum support
journal, April 2009
- Kaczmarek, Halina; Chaberska, Hanna
- Applied Surface Science, Vol. 255, Issue 13-14
Crack Pattern Formation in Thin Film Lithium-Ion Battery Electrodes
journal, January 2011
- Li, Juchuan; Dozier, Alan K.; Li, Yunchao
- Journal of The Electrochemical Society, Vol. 158, Issue 6
A review of polymer dissolution
journal, August 2003
- Miller-Chou, Beth A.; Koenig, Jack L.
- Progress in Polymer Science, Vol. 28, Issue 8, p. 1223-1270
Improving the Stability of Nanostructured Silicon Thin Film Lithium-Ion Battery Anodes through Their Controlled Oxidation
journal, February 2012
- Abel, Paul R.; Lin, Yong-Mao; Celio, Hugo
- ACS Nano, Vol. 6, Issue 3
Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review
journal, October 2013
- Su, Xin; Wu, Qingliu; Li, Juchuan
- Advanced Energy Materials, Vol. 4, Issue 1
Silicon Anode Design for Lithium-Ion Batteries: Progress and Perspectives
journal, December 2017
- Franco Gonzalez, Alba; Yang, Nai-Hsuan; Liu, Ru-Shi
- The Journal of Physical Chemistry C, Vol. 121, Issue 50
ARGET ATRP of methyl methacrylate in the presence of nitrogen-based ligands as reducing agents
journal, March 2009
- Kwak, Yungwan; Matyjaszewski, Krzysztof
- Polymer International, Vol. 58, Issue 3
Real-Time NMR Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries
journal, July 2009
- Key, Baris; Bhattacharyya, Rangeet; Morcrette, Mathieu
- Journal of the American Chemical Society, Vol. 131, Issue 26
Infrared Spectra of Poly(Methyl Methacrylate) Labeled with Oxygen-18
journal, November 1979
- Dirlikov, Stoil; Koenig, Jack L.
- Applied Spectroscopy, Vol. 33, Issue 6
Silane-Derived SEI Stabilization on Thin-Film Electrodes of Nanocrystalline Si for Lithium Batteries
journal, January 2009
- Song, Seung-Wan; Baek, Seung-Won
- Electrochemical and Solid-State Letters, Vol. 12, Issue 2
Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes
journal, April 2009
- Chan, Candace K.; Ruffo, Riccardo; Hong, Seung Sae
- Journal of Power Sources, Vol. 189, Issue 2, p. 1132-1140
Analysis of Three-Electrode Setups for AC-Impedance Measurements on Lithium-Ion Cells by FEM simulations
journal, January 2011
- Ender, Moses; Weber, André; Ellen, Ivers-Tiffée
- Journal of The Electrochemical Society, Vol. 159, Issue 2
Lithium intercalation into amorphous-silicon thin films: An electrochemical-impedance study
journal, July 2006
- Kulova, T. L.; Pleskov, Yu. V.; Skundin, A. M.
- Russian Journal of Electrochemistry, Vol. 42, Issue 7
Review on composite polymer electrolytes for lithium batteries
journal, July 2006
- Manuel Stephan, A.; Nahm, K. S.
- Polymer, Vol. 47, Issue 16
Shape evolution of patterned amorphous and polycrystalline silicon microarray thin film electrodes caused by lithium insertion and extraction
journal, October 2012
- He, Yu; Yu, Xiqian; Li, Geng
- Journal of Power Sources, Vol. 216
Surface-Coating Regulated Lithiation Kinetics and Degradation in Silicon Nanowires for Lithium Ion Battery
journal, April 2015
- Luo, Langli; Yang, Hui; Yan, Pengfei
- ACS Nano, Vol. 9, Issue 5
Novel conductive binder for high-performance silicon anodes in lithium ion batteries
journal, June 2017
- Liu, Dong; Zhao, Yan; Tan, Rui
- Nano Energy, Vol. 36
On the binding mechanism of CMC in Si negative electrodes for Li-ion batteries
journal, December 2007
- Lestriez, B.; Bahri, S.; Sandu, I.
- Electrochemistry Communications, Vol. 9, Issue 12
Initiated CVD of Poly(methyl methacrylate) Thin Films
journal, October 2005
- Chan, K.; Gleason, K. K.
- Chemical Vapor Deposition, Vol. 11, Issue 10
The Mechanism of SEI Formation on a Single Crystal Si(100) Electrode
journal, January 2015
- Vogl, Ulrike S.; Lux, Simon F.; Crumlin, Ethan J.
- Journal of The Electrochemical Society, Vol. 162, Issue 4
Role of the binder on the failure mechanism of Si nano-composite electrodes for Li-ion batteries
journal, August 2011
- Munao, D.; van Erven, J. W. M.; Valvo, M.
- Journal of Power Sources, Vol. 196, Issue 16
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010
- Verma, Pallavi; Maire, Pascal; Novák, Petr
- Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341
Mechanism of Interactions between CMC Binder and Si Single Crystal Facets
journal, August 2014
- Vogl, U. S.; Das, P. K.; Weber, A. Z.
- Langmuir, Vol. 30, Issue 34
Molecular grafting on silicon anodes: artificial Solid-Electrolyte Interphase and surface stabilization
journal, May 2016
- Dalla Corte, Daniel Alves; Gouget-Laemmel, Anne Chantal; Lahlil, Khalid
- Electrochimica Acta, Vol. 201
A Step toward High-Energy Silicon-Based Thin Film Lithium Ion Batteries
journal, April 2017
- Reyes Jiménez, Antonia; Klöpsch, Richard; Wagner, Ralf
- ACS Nano, Vol. 11, Issue 5
Silicon/Graphite Composite Electrodes for High-Capacity Anodes: Influence of Binder Chemistry on Cycling Stability
journal, January 2008
- Hochgatterer, N. S.; Schweiger, M. R.; Koller, S.
- Electrochemical and Solid-State Letters, Vol. 11, Issue 5
Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers
journal, August 1992
- Briggs, David.; Beamson, Graham.
- Analytical Chemistry, Vol. 64, Issue 15
ARGET ATRP of Methyl Acrylate with Inexpensive Ligands and ppm Concentrations of Catalyst
journal, February 2011
- Kwak, Yungwan; Magenau, Andrew J. D.; Matyjaszewski, Krzysztof
- Macromolecules, Vol. 44, Issue 4
Li-ion batteries: basics, progress, and challenges
journal, September 2015
- Deng, Da
- Energy Science & Engineering, Vol. 3, Issue 5
Ionic conductivity and FT-IR studies on plasticized PVC/PMMA blend polymer electrolytes
journal, July 2000
- Stephan, A. Manuel; Kumar, T. Prem; Renganathan, N. G.
- Journal of Power Sources, Vol. 89, Issue 1
Li + -Conductive Polymer-Embedded Nano-Si Particles as Anode Material for Advanced Li-ion Batteries
journal, February 2014
- Chen, Yao; Zeng, Shi; Qian, Jianfeng
- ACS Applied Materials & Interfaces, Vol. 6, Issue 5
Sputtered copper coating on silicon/graphite composite anode for lithium ion batteries
journal, June 2014
- Yen, Jui-Pin; Chang, Chia-Chin; Lin, Yu-Run
- Journal of Alloys and Compounds, Vol. 598
Artificial Solid Electrolyte Interphase To Address the Electrochemical Degradation of Silicon Electrodes
journal, June 2014
- Li, Juchuan; Dudney, Nancy J.; Nanda, Jagjit
- ACS Applied Materials & Interfaces, Vol. 6, Issue 13
Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films
journal, January 1980
- Ho, C.
- Journal of The Electrochemical Society, Vol. 127, Issue 2
Highly Reversible Lithium Storage in Nanostructured Silicon
journal, January 2003
- Graetz, J.; Ahn, C. C.; Yazami, R.
- Electrochemical and Solid-State Letters, Vol. 6, Issue 9
High-resolution monochromated XPS of poly(methyl methacrylate) thin films on a conducting substrate
journal, February 1991
- Beamson, G.; Bunn, A.; Briggs, D.
- Surface and Interface Analysis, Vol. 17, Issue 2
Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms
journal, January 2011
- Key, Baris; Morcrette, Mathieu; Tarascon, Jean-Marie
- Journal of the American Chemical Society, Vol. 133, Issue 3
Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
journal, April 2012
- Matyjaszewski, Krzysztof
- Macromolecules, Vol. 45, Issue 10, p. 4015-4039
FTIR Study of the Oxidation of Porous Silicon
journal, February 1997
- Mawhinney, Douglas B.; Glass, John A.; Yates, John T.
- The Journal of Physical Chemistry B, Vol. 101, Issue 7
Interfacial Properties of the a-Si∕Cu:Active–Inactive Thin-Film Anode System for Lithium-Ion Batteries
journal, January 2006
- Maranchi, J. P.; Hepp, A. F.; Evans, A. G.
- Journal of The Electrochemical Society, Vol. 153, Issue 6
A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes
journal, February 2014
- Liu, Nian; Lu, Zhenda; Zhao, Jie
- Nature Nanotechnology, Vol. 9, Issue 3
Structural and electrochemical properties of fullerene-coated silicon thin film as anode materials for lithium secondary batteries
journal, January 2009
- Arie, Arenst Andreas; Song, Jin O.; Lee, Joong Kee
- Materials Chemistry and Physics, Vol. 113, Issue 1
Revealing lithium–silicide phase transformations in nano-structured silicon-based lithium ion batteries via in situ NMR spectroscopy
journal, February 2014
- Ogata, K.; Salager, E.; Kerr, C. J.
- Nature Communications, Vol. 5, Issue 1
Cracking mechanisms in lithiated silicon thin film electrodes
journal, November 2014
- Chew, Huck Beng; Hou, Binyue; Wang, Xueju
- International Journal of Solids and Structures, Vol. 51, Issue 23-24
In Situ Conductivity, Impedance Spectroscopy, and Ex Situ Raman Spectra of Amorphous Silicon during the Insertion/Extraction of Lithium
journal, August 2007
- Pollak, Elad; Salitra, Gregory; Baranchugov, Valentina
- The Journal of Physical Chemistry C, Vol. 111, Issue 30
Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation
journal, May 2016
- Nguyen, Cao Cuong; Yoon, Taeho; Seo, Daniel M.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 19
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
journal, May 2012
- Liu, Nian; Wu, Hui; McDowell, Matthew T.
- Nano Letters, Vol. 12, Issue 6
Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004
- Obrovac, M. N.; Christensen, Leif
- Electrochemical and Solid-State Letters, Vol. 7, Issue 5
Aqueous ARGET ATRP
journal, July 2012
- Simakova, Antonina; Averick, Saadyah E.; Konkolewicz, Dominik
- Macromolecules, Vol. 45, Issue 16
Review—SEI: Past, Present and Future
journal, January 2017
- Peled, E.; Menkin, S.
- Journal of The Electrochemical Society, Vol. 164, Issue 7
Roles of Oxygen and Interfacial Stabilization in Enhancing the Cycling Ability of Silicon Oxide Anodes for Rechargeable Lithium Batteries
journal, January 2013
- Nguyen, Cao Cuong; Choi, Hyun; Song, Seung-Wan
- Journal of The Electrochemical Society, Vol. 160, Issue 6
Highly Adhesive and Soluble Copolyimide Binder: Improving the Long-Term Cycle Life of Silicon Anodes in Lithium-Ion Batteries
journal, June 2015
- Choi, Jaecheol; Kim, Kyuman; Jeong, Jiseon
- ACS Applied Materials & Interfaces, Vol. 7, Issue 27
Evaluating the solid electrolyte interphase formed on silicon electrodes: a comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry
journal, January 2016
- Fears, T. M.; Doucet, M.; Browning, J. F.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 20
A comparison between intercalation of Li and Mg ions into the model Chevrel phase compound (MxMo6S8): Impedance spectroscopic studies
journal, August 2005
- Levi, M. D.; Aurbach, D.
- Journal of Power Sources, Vol. 146, Issue 1-2
Basic Research Needs for Electrical Energy Storage. Report of the Basic Energy Sciences Workshop on Electrical Energy Storage, April 2-4, 2007
report, April 2007
- Goodenough, J. B.; Abruna, H. D.; Buchanan, M. V.
Physical Properties of Polymers Handbook
journal, January 1997
- Geschke, D.
- Zeitschrift für Physikalische Chemie, Vol. 199, Issue Part_1
Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review
journal, October 2013
- Su, Xin; Wu, Qingliu; Li, Juchuan
- Advanced Energy Materials, Vol. 4, Issue 1
Initiated CVD of Poly(methyl methacrylate) Thin Films
journal, October 2005
- Chan, K.; Gleason, K. K.
- Chemical Vapor Deposition, Vol. 11, Issue 10
Li-ion batteries: basics, progress, and challenges
journal, September 2015
- Deng, Da
- Energy Science & Engineering, Vol. 3, Issue 5
ARGET ATRP of methyl methacrylate in the presence of nitrogen-based ligands as reducing agents
journal, March 2009
- Kwak, Yungwan; Matyjaszewski, Krzysztof
- Polymer International, Vol. 58, Issue 3
High-resolution monochromated XPS of poly(methyl methacrylate) thin films on a conducting substrate
journal, February 1991
- Beamson, G.; Bunn, A.; Briggs, D.
- Surface and Interface Analysis, Vol. 17, Issue 2
AFM and XPS study of UV-irradiated poly(methyl methacrylate) films on glass and aluminum support
journal, April 2009
- Kaczmarek, Halina; Chaberska, Hanna
- Applied Surface Science, Vol. 255, Issue 13-14
Molecular grafting on silicon anodes: artificial Solid-Electrolyte Interphase and surface stabilization
journal, May 2016
- Dalla Corte, Daniel Alves; Gouget-Laemmel, Anne Chantal; Lahlil, Khalid
- Electrochimica Acta, Vol. 201
Sputtered copper coating on silicon/graphite composite anode for lithium ion batteries
journal, June 2014
- Yen, Jui-Pin; Chang, Chia-Chin; Lin, Yu-Run
- Journal of Alloys and Compounds, Vol. 598
A comparison between intercalation of Li and Mg ions into the model Chevrel phase compound (MxMo6S8): Impedance spectroscopic studies
journal, August 2005
- Levi, M. D.; Aurbach, D.
- Journal of Power Sources, Vol. 146, Issue 1-2
Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes
journal, April 2009
- Chan, Candace K.; Ruffo, Riccardo; Hong, Seung Sae
- Journal of Power Sources, Vol. 189, Issue 2, p. 1132-1140
A review of the electrochemical performance of alloy anodes for lithium-ion batteries
journal, January 2011
- Zhang, Wei-Jun
- Journal of Power Sources, Vol. 196, Issue 1
Role of the binder on the failure mechanism of Si nano-composite electrodes for Li-ion batteries
journal, August 2011
- Munao, D.; van Erven, J. W. M.; Valvo, M.
- Journal of Power Sources, Vol. 196, Issue 16
Shape evolution of patterned amorphous and polycrystalline silicon microarray thin film electrodes caused by lithium insertion and extraction
journal, October 2012
- He, Yu; Yu, Xiqian; Li, Geng
- Journal of Power Sources, Vol. 216
Structural and electrochemical properties of fullerene-coated silicon thin film as anode materials for lithium secondary batteries
journal, January 2009
- Arie, Arenst Andreas; Song, Jin O.; Lee, Joong Kee
- Materials Chemistry and Physics, Vol. 113, Issue 1
Novel conductive binder for high-performance silicon anodes in lithium ion batteries
journal, June 2017
- Liu, Dong; Zhao, Yan; Tan, Rui
- Nano Energy, Vol. 36
Review on composite polymer electrolytes for lithium batteries
journal, July 2006
- Manuel Stephan, A.; Nahm, K. S.
- Polymer, Vol. 47, Issue 16
Experimental limitations in impedance spectroscopy: Part III. Effect of reference electrode geometry/position
journal, April 1997
- Hsieh, G.; Mason, T. O.; Garboczi, E. J.
- Solid State Ionics, Vol. 96, Issue 3-4
Primary and secondary oxygen-induced C1s binding energy shifts in x-ray photoelectron spectroscopy of polymers
journal, August 1992
- Briggs, David.; Beamson, Graham.
- Analytical Chemistry, Vol. 64, Issue 15
The Chemistry of Electrolyte Reduction on Silicon Electrodes Revealed by in Situ ATR-FTIR Spectroscopy
journal, June 2017
- Shi, Feifei; Ross, Philip N.; Somorjai, Gabor A.
- The Journal of Physical Chemistry C, Vol. 121, Issue 27
Silicon Anode Design for Lithium-Ion Batteries: Progress and Perspectives
journal, December 2017
- Franco Gonzalez, Alba; Yang, Nai-Hsuan; Liu, Ru-Shi
- The Journal of Physical Chemistry C, Vol. 121, Issue 50
Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation
journal, May 2016
- Nguyen, Cao Cuong; Yoon, Taeho; Seo, Daniel M.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 19
Surface-Coating Regulated Lithiation Kinetics and Degradation in Silicon Nanowires for Lithium Ion Battery
journal, April 2015
- Luo, Langli; Yang, Hui; Yan, Pengfei
- ACS Nano, Vol. 9, Issue 5
FTIR Study of the Oxidation of Porous Silicon
journal, February 1997
- Mawhinney, Douglas B.; Glass, John A.; Yates, John T.
- The Journal of Physical Chemistry B, Vol. 101, Issue 7
Mechanism of Interactions between CMC Binder and Si Single Crystal Facets
journal, August 2014
- Vogl, U. S.; Das, P. K.; Weber, A. Z.
- Langmuir, Vol. 30, Issue 34
ARGET ATRP of Methyl Acrylate with Inexpensive Ligands and ppm Concentrations of Catalyst
journal, February 2011
- Kwak, Yungwan; Magenau, Andrew J. D.; Matyjaszewski, Krzysztof
- Macromolecules, Vol. 44, Issue 4
Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
journal, April 2012
- Matyjaszewski, Krzysztof
- Macromolecules, Vol. 45, Issue 10, p. 4015-4039
Aqueous ARGET ATRP
journal, July 2012
- Simakova, Antonina; Averick, Saadyah E.; Konkolewicz, Dominik
- Macromolecules, Vol. 45, Issue 16
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
journal, May 2012
- Liu, Nian; Wu, Hui; McDowell, Matthew T.
- Nano Letters, Vol. 12, Issue 6
Improving the Stability of Nanostructured Silicon Thin Film Lithium-Ion Battery Anodes through Their Controlled Oxidation
journal, February 2012
- Abel, Paul R.; Lin, Yong-Mao; Celio, Hugo
- ACS Nano, Vol. 6, Issue 3
Revealing lithium–silicide phase transformations in nano-structured silicon-based lithium ion batteries via in situ NMR spectroscopy
journal, February 2014
- Ogata, K.; Salager, E.; Kerr, C. J.
- Nature Communications, Vol. 5, Issue 1
Low temperature bonding of PMMA and COC microfluidic substrates using UV/ozone surface treatment
journal, January 2007
- Tsao, C. W.; Hromada, L.; Liu, J.
- Lab on a Chip, Vol. 7, Issue 4
Enhancing cycling durability of Li-ion batteries with hierarchical structured silicon–graphene hybrid anodes
journal, January 2016
- Loveridge, Melanie J.; Lain, Michael J.; Huang, Qianye
- Physical Chemistry Chemical Physics, Vol. 18, Issue 44
Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
journal, January 2004
- Obrovac, M. N.; Christensen, Leif
- Electrochemical and Solid-State Letters, Vol. 7, Issue 5
Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films
journal, January 1980
- Ho, C.
- Journal of The Electrochemical Society, Vol. 127, Issue 2
Silicon/Graphite Composite Electrodes for High-Capacity Anodes: Influence of Binder Chemistry on Cycling Stability
journal, January 2008
- Hochgatterer, N. S.; Schweiger, M. R.; Koller, S.
- Electrochemical and Solid-State Letters, Vol. 11, Issue 5
Silane-Derived SEI Stabilization on Thin-Film Electrodes of Nanocrystalline Si for Lithium Batteries
journal, January 2009
- Song, Seung-Wan; Baek, Seung-Won
- Electrochemical and Solid-State Letters, Vol. 12, Issue 2
The Mechanism of SEI Formation on a Single Crystal Si(100) Electrode
journal, January 2015
- Vogl, Ulrike S.; Lux, Simon F.; Crumlin, Ethan J.
- Journal of The Electrochemical Society, Vol. 162, Issue 4
Analysis of Three-Electrode Setups for AC-Impedance Measurements on Lithium-Ion Cells by FEM simulations
journal, January 2011
- Ender, Moses; Weber, André; Ellen, Ivers-Tiffée
- Journal of The Electrochemical Society, Vol. 159, Issue 2
Crack Pattern Formation in Thin Film Lithium-Ion Battery Electrodes
journal, March 2011
- Li, Juchuan; Dozier, Alan; Li, Yunchao
- ECS Meeting Abstracts, Vol. MA2011-01, Issue 10
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Lithium-mediated ammonia synthesis from water and nitrogen: a membrane-free approach enabled by an immiscible aqueous/organic hybrid electrolyte system
journal, January 2019
- Kim, Kwiyong; Chen, Yifu; Han, Jong-In
- Green Chemistry, Vol. 21, Issue 14
Ultrathin conformal polycyclosiloxane films to improve silicon cycling stability
journal, July 2019
- Shen, B. H.; Wang, S.; Tenhaeff, W. E.
- Science Advances, Vol. 5, Issue 7
Ultrathin conformal polycyclosiloxane films to improve silicon cycling stability
journal, July 2019
- Shen, B. H.; Wang, S.; Tenhaeff, W. E.
- Science Advances, Vol. 5, Issue 7