Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface

Shen, Brian H.; Veith, Gabriel M.; Tenhaeff, Wyatt E.

doi:10.1038/s41598-018-30000-z

Title: Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface

Journal Article · 01 August 2018 · Scientific Reports

DOI: https://doi.org/10.1038/s41598-018-30000-z · OSTI ID:1462871

Shen, Brian H. ^[1];

^[2]; Tenhaeff, Wyatt E. ^[1]

Univ. of Rochester, NY (United States). Dept. of Chemical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division

Here, we have developed a proof of concept electrode design to covalently graft poly(methyl methacrylate) brushes directly to silicon thin film electrodes via surface-initiated atom transfer radical polymerization. This polymer layer acts as a stable artificial solid electrolyte interface that enables surface passivation despite large volume changes during cycling. Thin polymer layers (75 nm) improve average first cycle coulombic efficiency from 62.4% in bare silicon electrodes to 76.3%. Average first cycle reversible capacity was improved from 3157 to 3935 mAh g^-1, and average irreversible capacity was reduced from 2011 to 1020 mAh g^-1. Electrochemical impedance spectroscopy performed on silicon electrodes showed that resistance from solid electrolyte interface formation increased from 79 to 1508 Ω in untreated silicon thin films over 26 cycles, while resistance growth was lower – from 98 to 498 Ω – in silicon films functionalized with PMMA brushes. The lower increase suggests enhanced surface passivation and lower electrolyte degradation. This work provides a pathway to develop artificial solid electrolyte interfaces synthesized under controlled reaction conditions.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1462871

Journal Information:: Scientific Reports, Vol. 8; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 22 works

Citation information provided by
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ARGET ATRP of methyl methacrylate in the presence of nitrogen-based ligands as reducing agents Kwak, Yungwan; Matyjaszewski, Krzysztof Polymer International, Vol. 58, Issue 3 https://doi.org/10.1002/pi.2530	journal	March 2009
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Molecular grafting on silicon anodes: artificial Solid-Electrolyte Interphase and surface stabilization Dalla Corte, Daniel Alves; Gouget-Laemmel, Anne Chantal; Lahlil, Khalid Electrochimica Acta, Vol. 201 https://doi.org/10.1016/j.electacta.2016.03.105	journal	May 2016
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A review of the electrochemical performance of alloy anodes for lithium-ion batteries Zhang, Wei-Jun Journal of Power Sources, Vol. 196, Issue 1 https://doi.org/10.1016/j.jpowsour.2010.07.020	journal	January 2011
Role of the binder on the failure mechanism of Si nano-composite electrodes for Li-ion batteries Munao, D.; van Erven, J. W. M.; Valvo, M. Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.11.072	journal	August 2011
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Silicon Anode Design for Lithium-Ion Batteries: Progress and Perspectives Franco Gonzalez, Alba; Yang, Nai-Hsuan; Liu, Ru-Shi The Journal of Physical Chemistry C, Vol. 121, Issue 50 https://doi.org/10.1021/acs.jpcc.7b07793	journal	December 2017
Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation Nguyen, Cao Cuong; Yoon, Taeho; Seo, Daniel M. ACS Applied Materials & Interfaces, Vol. 8, Issue 19 https://doi.org/10.1021/acsami.6b03357	journal	May 2016
Surface-Coating Regulated Lithiation Kinetics and Degradation in Silicon Nanowires for Lithium Ion Battery Luo, Langli; Yang, Hui; Yan, Pengfei ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b01681	journal	April 2015
FTIR Study of the Oxidation of Porous Silicon Mawhinney, Douglas B.; Glass, John A.; Yates, John T. The Journal of Physical Chemistry B, Vol. 101, Issue 7 https://doi.org/10.1021/jp963322r	journal	February 1997
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ARGET ATRP of Methyl Acrylate with Inexpensive Ligands and ppm Concentrations of Catalyst Kwak, Yungwan; Magenau, Andrew J. D.; Matyjaszewski, Krzysztof Macromolecules, Vol. 44, Issue 4 https://doi.org/10.1021/ma102665c	journal	February 2011
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Aqueous ARGET ATRP Simakova, Antonina; Averick, Saadyah E.; Konkolewicz, Dominik Macromolecules, Vol. 45, Issue 16 https://doi.org/10.1021/ma301303b	journal	July 2012
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Liu, Nian; Wu, Hui; McDowell, Matthew T. Nano Letters, Vol. 12, Issue 6 https://doi.org/10.1021/nl3014814	journal	May 2012
Improving the Stability of Nanostructured Silicon Thin Film Lithium-Ion Battery Anodes through Their Controlled Oxidation Abel, Paul R.; Lin, Yong-Mao; Celio, Hugo ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn204896n	journal	February 2012
Revealing lithium–silicide phase transformations in nano-structured silicon-based lithium ion batteries via in situ NMR spectroscopy Ogata, K.; Salager, E.; Kerr, C. J. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4217	journal	February 2014
Low temperature bonding of PMMA and COC microfluidic substrates using UV/ozone surface treatment Tsao, C. W.; Hromada, L.; Liu, J. Lab on a Chip, Vol. 7, Issue 4 https://doi.org/10.1039/b618901f	journal	January 2007
Enhancing cycling durability of Li-ion batteries with hierarchical structured silicon–graphene hybrid anodes Loveridge, Melanie J.; Lain, Michael J.; Huang, Qianye Physical Chemistry Chemical Physics, Vol. 18, Issue 44 https://doi.org/10.1039/c6cp06788c	journal	January 2016
Structural Changes in Silicon Anodes during Lithium Insertion/Extraction Obrovac, M. N.; Christensen, Leif Electrochemical and Solid-State Letters, Vol. 7, Issue 5 https://doi.org/10.1149/1.1652421	journal	January 2004
Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films Ho, C. Journal of The Electrochemical Society, Vol. 127, Issue 2 https://doi.org/10.1149/1.2129668	journal	January 1980
Silicon/Graphite Composite Electrodes for High-Capacity Anodes: Influence of Binder Chemistry on Cycling Stability Hochgatterer, N. S.; Schweiger, M. R.; Koller, S. Electrochemical and Solid-State Letters, Vol. 11, Issue 5 https://doi.org/10.1149/1.2888173	journal	January 2008
Silane-Derived SEI Stabilization on Thin-Film Electrodes of Nanocrystalline Si for Lithium Batteries Song, Seung-Wan; Baek, Seung-Won Electrochemical and Solid-State Letters, Vol. 12, Issue 2 https://doi.org/10.1149/1.3028216	journal	January 2009
The Mechanism of SEI Formation on a Single Crystal Si(100) Electrode Vogl, Ulrike S.; Lux, Simon F.; Crumlin, Ethan J. Journal of The Electrochemical Society, Vol. 162, Issue 4 https://doi.org/10.1149/2.0391504jes	journal	January 2015
Analysis of Three-Electrode Setups for AC-Impedance Measurements on Lithium-Ion Cells by FEM simulations Ender, Moses; Weber, André; Ellen, Ivers-Tiffée Journal of The Electrochemical Society, Vol. 159, Issue 2 https://doi.org/10.1149/2.100202jes	journal	January 2011
Crack Pattern Formation in Thin Film Lithium-Ion Battery Electrodes Li, Juchuan; Dozier, Alan; Li, Yunchao ECS Meeting Abstracts, Vol. MA2011-01, Issue 10 https://doi.org/10.1149/ma2011-01/10/511	journal	March 2011

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Ultrathin conformal polycyclosiloxane films to improve silicon cycling stability Shen, B. H.; Wang, S.; Tenhaeff, W. E. Science Advances, Vol. 5, Issue 7 https://doi.org/10.1126/sciadv.aaw4856	journal	July 2019

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