Novel graphene quantum dots (GQDs)-incorporated thin film composite (TFC) membranes for forward osmosis (FO) desalination

Xu, Shengjie; Li, Feng; Su, Baowei; Hu, Michael Z.; Gao, Xueli; Gao, Congjie

doi:10.1016/j.desal.2018.04.004

Title: Novel graphene quantum dots (GQDs)-incorporated thin film composite (TFC) membranes for forward osmosis (FO) desalination

Journal Article · 05 May 2018 · Desalination

DOI: https://doi.org/10.1016/j.desal.2018.04.004 · OSTI ID:1462857

^[1]; Li, Feng ^[1];

^[1];

^[2]; Gao, Xueli ^[1]; Gao, Congjie ^[1]

Ocean Univ. of China, Qingdao (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

This paper reports a novel class of thin film composite (TFC) membranes for forward osmosis (FO) desalination. The TFC membranes were fabricated via interfacial polymerization (IP) of aqueous mixture of polyethyleneimine (PEI) and graphene quantum dots (GQDs) with organic solution of trimesoyl chloride (TMC) on modified polyacrylonitrile (PAN) ultrafiltration substrates. The chemical structures and morphologies of the synthesized GQDs and the GQDs-incorporated membranes were studied by various characterization techniques. The synthesized GQDs exhibited a narrow size distribution of 1.0–4.0 nm with an average size of 2.19 nm, and the thickness were one to three graphene layers. The results showed that GQDs nanoparticles were covalently bonded to the polyamide chains. The optimized TFC membrane with 0.050 wt% GQDs loading exhibited quite hydrophilic and neutrally charged membrane surface, along with an enhanced water flux of 12.9 L m^–2 h^–1 and a comparable reverse salt flux of 1.41 g m^–2 h^–1 when DI water and 0.5 M MgCl2 were used as the feed solution and the draw solution, respectively. Also, the optimized GQDs-incorporated TFC membrane presented an especially good anti-fouling performance. Furthermore, incorporating the novel graphene nanomaterial into polymer membranes may present its great potential application in desalination, purification and wastewater treatment.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1462857

Journal Information:: Desalination, Vol. 451, Issue C; ISSN 0011-9164

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 82 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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