High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration

Li, Can; Li, Shuxuan; Lv, Li; Su, Baowei; Hu, Michael Z.

doi:10.1016/j.memsci.2018.06.048

Title: High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration

Abstract

This study reports a new class of integral polyimide (PI)-based thin film composite (TFC) membranes (with improved solvent resistance in both the skin layer and the substrate) for organic solvent nanofiltration (OSN). The OSN membrane was prepared via interfacial polymerization (IP) onto a PI ultrafiltration (UF) substrate, followed by an imidization, a chemical crosslinking, and a solvent activation process. During the IP process, m-phenylenediamine (MPD), dopamine (DA), and 1,2,4,5-benzene tetracarboxylic acyl chloride (BTAC) were respectively used as an aqueous monomer, an aqueous additive, and an organic monomer. We proved that amide bonding formed between MPD and the PI substrate during the immersion of the substrate in the aqueous MPD solution, thus providing a strong binding between the substrate and the subsequently formed skin layer of polyamide acid (PAA), which was formed due to reaction between MPD and BTAC during the IP process. DA contains amine group and could also help build a strong binding between the substrate and the skin layer during the same IP process. The subsequent imidization step converted the PAA molecules of the skin layer into PI polymers, which was quite similar to that of the substrate. The final crosslinking step crosslinked not only the inner moleculesmore »« less

Authors:

Li, Can ^[1]; Li, Shuxuan ^[1]; Lv, Li ^[1]; Su, Baowei ^[1]; Hu, Michael Z. ^[2]

Ocean Univ. of China, Qingdao (China). Key Lab. of Marine Chemistry Theory and Technology of Ministry of Education. College of Chemistry & Chemical Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division

Publication Date:: 2018-06-26

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ocean Univ. of China, Qingdao (China)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities of China; China Scholarship Council

OSTI Identifier:: 1462856

Alternate Identifier(s):: OSTI ID: 1691635

Grant/Contract Number:: AC05-00OR22725; 21476218; 201822012; 201606335018; WBS 2.5.5.507

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Membrane Science

Additional Journal Information:: Journal Volume: 564; Journal ID: ISSN 0376-7388

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; organic solvent nanofiltration (OSN); dopamine; polyimide; interfacial polymerization (IP); imidization

Citation Formats


                    Li, Can, Li, Shuxuan, Lv, Li, Su, Baowei, and Hu, Michael Z. High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration.  United States: N. p., 2018. 
Web.  doi:10.1016/j.memsci.2018.06.048.

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                    Li, Can, Li, Shuxuan, Lv, Li, Su, Baowei, & Hu, Michael Z. High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration.  United States.  https://doi.org/10.1016/j.memsci.2018.06.048

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                    Li, Can, Li, Shuxuan, Lv, Li, Su, Baowei, and Hu, Michael Z. Tue .  
"High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration".  United States.  https://doi.org/10.1016/j.memsci.2018.06.048.  https://www.osti.gov/servlets/purl/1462856.

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@article{osti_1462856,

  title        = {High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration},

  author       = {Li, Can and Li, Shuxuan and Lv, Li and Su, Baowei and Hu, Michael Z.},

  abstractNote = {This study reports a new class of integral polyimide (PI)-based thin film composite (TFC) membranes (with improved solvent resistance in both the skin layer and the substrate) for organic solvent nanofiltration (OSN). The OSN membrane was prepared via interfacial polymerization (IP) onto a PI ultrafiltration (UF) substrate, followed by an imidization, a chemical crosslinking, and a solvent activation process. During the IP process, m-phenylenediamine (MPD), dopamine (DA), and 1,2,4,5-benzene tetracarboxylic acyl chloride (BTAC) were respectively used as an aqueous monomer, an aqueous additive, and an organic monomer. We proved that amide bonding formed between MPD and the PI substrate during the immersion of the substrate in the aqueous MPD solution, thus providing a strong binding between the substrate and the subsequently formed skin layer of polyamide acid (PAA), which was formed due to reaction between MPD and BTAC during the IP process. DA contains amine group and could also help build a strong binding between the substrate and the skin layer during the same IP process. The subsequent imidization step converted the PAA molecules of the skin layer into PI polymers, which was quite similar to that of the substrate. The final crosslinking step crosslinked not only the inner molecules of the skin layer, and the inner molecules of the substrate, but also the interface molecules between the skin and substrate so as to form an integral composite membrane with improving solvent resistance. Finally, the fabricated OSN membranes under optimal preparation conditions exhibited an ethanol permeance of 2.03 L m-2 h-1 bar-1 with a rejection of 98% for Rhodamine B (479 Da) and exhibited an outstanding organic solvent resistance without compromising separation performance during the persistent immersion in DMF at 80 °C for two weeks, indicating a promising prospective in OSN applications.},

  doi          = {10.1016/j.memsci.2018.06.048},

  journal      = {Journal of Membrane Science},

  number       = ,

  volume       = 564,

  place        = {United States},

  year         = {2018},

  month        = {6}

}

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https://doi.org/10.1016/j.memsci.2018.06.048

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Works referenced in this record:

Molecular Separation with Organic Solvent Nanofiltration: A Critical Review
journal, October 2014

Marchetti, Patrizia; Jimenez Solomon, Maria F.; Szekely, Gyorgy
Chemical Reviews, Vol. 114, Issue 21
DOI: 10.1021/cr500006j

Solvent resistant nanofiltration: separating on a molecular level
journal, January 2008

Vandezande, Pieter; Gevers, Lieven E. M.; Vankelecom, Ivo F. J.
Chem. Soc. Rev., Vol. 37, Issue 2
DOI: 10.1039/B610848M

Recent developments in thin film (nano)composite membranes for solvent resistant nanofiltration
journal, May 2015

Hermans, Sanne; Mariën, Hanne; Van Goethem, Cedric
Current Opinion in Chemical Engineering, Vol. 8
DOI: 10.1016/j.coche.2015.01.009

Polymer nanofilms with enhanced microporosity by interfacial polymerization
journal, May 2016

Jimenez-Solomon, Maria F.; Song, Qilei; Jelfs, Kim E.
Nature Materials, Vol. 15, Issue 7
DOI: 10.1038/nmat4638

Sustainability assessment of organic solvent nanofiltration: from fabrication to application
journal, January 2014

Szekely, Gyorgy; Jimenez-Solomon, Maria F.; Marchetti, Patrizia
Green Chem., Vol. 16, Issue 10
DOI: 10.1039/C4GC00701H

The influence of membrane formation on functional performance of organic solvent nanofiltration membranes
journal, November 2006

See-Toh, Yoong Hsiang; Ferreira, Frederico Castelo; Livingston, Andrew G.
Desalination, Vol. 199, Issue 1-3
DOI: 10.1016/j.desal.2006.03.059

Polymeric membranes for nanofiltration in polar aprotic solvents
journal, September 2007

See Toh, Y. H.; Lim, F. W.; Livingston, A. G.
Journal of Membrane Science, Vol. 301, Issue 1-2
DOI: 10.1016/j.memsci.2007.06.034

A simplified diamine crosslinking method for PI nanofiltration membranes
journal, May 2010

Vanherck, Katrien; Cano-Odena, Angels; Koeckelberghs, Guy
Journal of Membrane Science, Vol. 353, Issue 1-2
DOI: 10.1016/j.memsci.2010.02.046

Synthesis and characterization of new polyimides containing ethynylene linkages
journal, April 2007

Han, Seung San; Im, Seung Soon; Won, Jong Chan
European Polymer Journal, Vol. 43, Issue 4
DOI: 10.1016/j.eurpolymj.2007.01.052

Solvent recovery from lube oil filtrates with a polyimide membrane
journal, November 2000

White, Lloyd S.; Nitsch, Albert R.
Journal of Membrane Science, Vol. 179, Issue 1-2
DOI: 10.1016/S0376-7388(00)00517-2

Pore preserving crosslinkers for polyimide OSN membranes
journal, September 2014

Siddique, H.; Bhole, Y.; Peeva, L. G.
Journal of Membrane Science, Vol. 465
DOI: 10.1016/j.memsci.2014.03.031

Organic solvent resistant poly(ether-ether-ketone) nanofiltration membranes
journal, April 2015

da Silva Burgal, João; Peeva, Ludmila G.; Kumbharkar, Santosh
Journal of Membrane Science, Vol. 479
DOI: 10.1016/j.memsci.2014.12.035

High throughput study of phase inversion parameters for polyimide-based SRNF membranes
journal, March 2009

Vandezande, Pieter; Li, Xianfeng; Gevers, Lieven E. M.
Journal of Membrane Science, Vol. 330, Issue 1-2
DOI: 10.1016/j.memsci.2008.12.068

Cross-linked polyimide membranes for solvent resistant nanofiltration in aprotic solvents
journal, July 2008

Vanherck, Katrien; Vandezande, Pieter; Aldea, Steliana O.
Journal of Membrane Science, Vol. 320, Issue 1-2
DOI: 10.1016/j.memsci.2008.04.026

High flux membranes for organic solvent nanofiltration (OSN)—Interfacial polymerization with solvent activation
journal, December 2012

Jimenez Solomon, Maria Fernanda; Bhole, Yogesh; Livingston, Andrew Guy
Journal of Membrane Science, Vol. 423-424
DOI: 10.1016/j.memsci.2012.08.030

High flux hydrophobic membranes for organic solvent nanofiltration (OSN)—Interfacial polymerization, surface modification and solvent activation
journal, May 2013

Jimenez Solomon, Maria F.; Bhole, Yogesh; Livingston, Andrew G.
Journal of Membrane Science, Vol. 434
DOI: 10.1016/j.memsci.2013.01.055

Beneath the surface: Influence of supports on thin film composite membranes by interfacial polymerization for organic solvent nanofiltration
journal, December 2013

Jimenez-Solomon, Maria F.; Gorgojo, Patricia; Munoz-Ibanez, Marta
Journal of Membrane Science, Vol. 448
DOI: 10.1016/j.memsci.2013.06.030

Sub-10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation
journal, June 2015

Karan, S.; Jiang, Z.; Livingston, A. G.
Science, Vol. 348, Issue 6241
DOI: 10.1126/science.aaa5058

Preparation of thin film composite nanofiltration membrane with improved structural stability through the mediation of polydopamine
journal, February 2015

Li, Yafei; Su, Yanlei; Li, Jianyu
Journal of Membrane Science, Vol. 476
DOI: 10.1016/j.memsci.2014.11.011

Dopamine composite nanofiltration membranes prepared by self-polymerization and interfacial polymerization
journal, September 2014

Zhao, Jiaojiao; Su, Yanlei; He, Xin
Journal of Membrane Science, Vol. 465
DOI: 10.1016/j.memsci.2014.04.018

Polydopamine-Enabled Approach toward Tailored Plasmonic Nanogapped Nanoparticles: From Nanogap Engineering to Multifunctionality
journal, November 2016

Zhou, Jiajing; Xiong, Qirong; Ma, Jielin
ACS Nano, Vol. 10, Issue 12
DOI: 10.1021/acsnano.6b05951

Mussel-Inspired Synthesis of Polydopamine-Functionalized Graphene Hydrogel as Reusable Adsorbents for Water Purification
journal, December 2012

Gao, Hongcai; Sun, Yimin; Zhou, Jiajing
ACS Applied Materials & Interfaces, Vol. 5, Issue 2
DOI: 10.1021/am302500v

Polydopamine and Its Derivative Materials: Synthesis and Promising Applications in Energy, Environmental, and Biomedical Fields
journal, February 2014

Liu, Yanlan; Ai, Kelong; Lu, Lehui
Chemical Reviews, Vol. 114, Issue 9
DOI: 10.1021/cr400407a

Realizing Mussel-Inspired Polydopamine Selective Layer with Strong Solvent Resistance in Nanofiltration toward Sustainable Reclamation
journal, May 2017

Xu, Yanchao; You, Fangjie; Sun, Hongguang
ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 6
DOI: 10.1021/acssuschemeng.7b00871

Novel methodology for facile fabrication of nanofiltration membranes based on nucleophilic nature of polydopamine
journal, August 2016

Wang, Tunyu; Qiblawey, Hazim; Sivaniah, Easan
Journal of Membrane Science, Vol. 511
DOI: 10.1016/j.memsci.2016.03.043

Novel reverse osmosis membranes incorporated with a hydrophilic additive for seawater desalination
journal, April 2014

Zhao, Lin; Ho, W. S. Winston
Journal of Membrane Science, Vol. 455
DOI: 10.1016/j.memsci.2013.12.066

Polyimide thin film composite (TFC) membranes via interfacial polymerization on hydrolyzed polyacrylonitrile support for solvent resistant nanofiltration
journal, January 2017

Yang, Shanshan; Zhen, Hongyan; Su, Baowei
RSC Advances, Vol. 7, Issue 68
DOI: 10.1039/C7RA08133B

Preparation and performance of dynamic layer-by-layer PDADMAC/PSS nanofiltration membrane
journal, December 2012

Su, Baowei; Wang, Tingting; Wang, Zongwen
Journal of Membrane Science, Vol. 423-424
DOI: 10.1016/j.memsci.2012.08.041

Hybrid polymer/MOF membranes for Organic Solvent Nanofiltration (OSN): Chemical modification and the quest for perfection
journal, April 2016

Campbell, James; Burgal, Joao Da Silvao; Szekely, Gyorgy
Journal of Membrane Science, Vol. 503
DOI: 10.1016/j.memsci.2016.01.024

Modelling of membrane nanofiltration—pore size distribution effects
journal, April 2002

Bowen, W. Richard; Welfoot, Julian S.
Chemical Engineering Science, Vol. 57, Issue 8
DOI: 10.1016/S0009-2509(01)00412-2

Modelling the performance of membrane nanofiltration—critical assessment and model development
journal, April 2002

Bowen, W. Richard; Welfoot, Julian S.
Chemical Engineering Science, Vol. 57, Issue 7
DOI: 10.1016/S0009-2509(01)00413-4

Use of the log-normal probability density function to analyze membrane pore size distributions: functional forms and discrepancies
journal, June 1994

Zydney, Andrew L.; Aimar, Pierre; Meireles, Martine
Journal of Membrane Science, Vol. 91, Issue 3
DOI: 10.1016/0376-7388(94)80090-1

Diagnosis of membrane fouling using a rotating annular filter. 1. Cell culture media
journal, February 1993

Belfort, Georges; Pimbley, Joseph M.; Greiner, Anthony
Journal of Membrane Science, Vol. 77, Issue 1
DOI: 10.1016/0376-7388(93)85231-K

Correlation of diffusion coefficients in dilute solutions
journal, June 1955

Wilke, C. R.; Chang, Pin
AIChE Journal, Vol. 1, Issue 2
DOI: 10.1002/aic.690010222

The effect of membrane formation parameters on performance of polyimide membranes for organic solvent nanofiltration (OSN). Part C. Effect of polyimide characteristics
journal, September 2011

Soroko, Iwona; Sairam, Malladi; Livingston, A. G.
Journal of Membrane Science, Vol. 381, Issue 1-2
DOI: 10.1016/j.memsci.2011.07.029

Novel diamine-modified composite nanofiltration membranes with chlorine resistance using monomers of 1,2,4,5-benzene tetracarbonyl chloride and m-phenylenediamine
journal, January 2015

Zhang, Jinli; Hai, Yuyan; Zuo, Yi
Journal of Materials Chemistry A, Vol. 3, Issue 16
DOI: 10.1039/C4TA07159J

Chemical modification of P84 copolyimide membranes by polyethylenimine for nanofiltration
journal, February 2009

Ba, Chaoyi; Langer, James; Economy, James
Journal of Membrane Science, Vol. 327, Issue 1-2
DOI: 10.1016/j.memsci.2008.10.051

P84 polyimide membranes modified by a tripodal amine for enhanced pervaporation dehydration of acetone
journal, January 2015

Mangindaan, Dave W.; Woon, Nelson Minyang; Shi, Gui Min
Chemical Engineering Science, Vol. 122
DOI: 10.1016/j.ces.2014.09.014

Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes
journal, May 2016

Yurekli, Yilmaz
Journal of Hazardous Materials, Vol. 309
DOI: 10.1016/j.jhazmat.2016.01.064

In situ regulation of micro-pore to design high performance polyimide membranes for pervaporation dehydration of isopropanol
journal, November 2015

Salehian, Peyman; Chua, Mei Ling; Askari, Mohammad
Journal of Membrane Science, Vol. 493
DOI: 10.1016/j.memsci.2015.07.004

Interfacially synthesized chlorine-resistant polyimide thin film composite (TFC) reverse osmosis (RO) membranes
journal, January 2013

Hong, SungPyo; Kim, In-Chul; Tak, Taemoon
Desalination, Vol. 309
DOI: 10.1016/j.desal.2012.09.025

The effect of membrane formation parameters on performance of polyimide membranes for organic solvent nanofiltration (OSN): Part A. Effect of polymer/solvent/non-solvent system choice
journal, September 2011

Soroko, Iwona; Lopes, Mafalda Pessoa; Livingston, Andrew
Journal of Membrane Science, Vol. 381, Issue 1-2
DOI: 10.1016/j.memsci.2011.07.027

Novel polyimide-based electrospun carbon nanofibers prepared using ion-beam irradiation
journal, April 2012

Seki, Naoko; Arai, Takuma; Suzuki, Yoshiaki
Polymer, Vol. 53, Issue 10
DOI: 10.1016/j.polymer.2012.03.026

Effects of iron catalyst on gas transport properties of ion-irradiated asymmetric polyimide membranes
journal, June 2011

Muraoka, Daigo; Zhang, Lei; Suzuki, Yoshiaki
Journal of Membrane Science, Vol. 375, Issue 1-2
DOI: 10.1016/j.memsci.2011.02.047

Thin film composite nanofiltration membrane prepared by the interfacial polymerization of 1,2,4,5-benzene tetracarbonyl chloride on the mixed amines cross-linked poly(ether imide) support
journal, December 2016

Hai, Yuyan; Zhang, Jinli; Shi, Chang
Journal of Membrane Science, Vol. 520
DOI: 10.1016/j.memsci.2016.07.050

Novel thin-film composite membranes via manipulating the synergistic interaction of dopamine and m-phenylenediamine for highly efficient forward osmosis desalination
journal, January 2017

Xu, Lina; Xu, Jia; Shan, Baotian
Journal of Materials Chemistry A, Vol. 5, Issue 17
DOI: 10.1039/C7TA00492C

Cross-linked mixed matrix membranes consisting of carboxyl-functionalized multi-walled carbon nanotubes and P84 polyimide for organic solvent nanofiltration (OSN)
journal, October 2017

Davood Abadi Farahani, Mohammad Hossein; Hua, Dan; Chung, Tai-Shung
Separation and Purification Technology, Vol. 186
DOI: 10.1016/j.seppur.2017.06.021

Polyamide thin film composite membranes on cross-linked polyimide supports: Improvement of RO performance via activating solvent
journal, July 2014

Gorgojo, P.; Jimenez-Solomon, M. F.; Livingston, A. G.
Desalination, Vol. 344
DOI: 10.1016/j.desal.2014.02.009

High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination
journal, January 2013

Zhao, Lin; Chang, Philip C. -Y.; Ho, W. S. Winston
Desalination, Vol. 308
DOI: 10.1016/j.desal.2012.07.020

Effect of chemical structures of amines on physicochemical properties of active layers and dehydration of isopropanol through interfacially polymerized thin-film composite membranes
journal, January 2008

Huang, Shu-Hsien; Hsu, Chao-Jen; Liaw, Der-Jang
Journal of Membrane Science, Vol. 307, Issue 1
DOI: 10.1016/j.memsci.2007.09.014

Bioadhesion-inspired fabrication of robust thin-film composite membranes with tunable solvent permeation properties
journal, January 2016

Mu, Wenrui; Liu, Jindun; Wang, Jingtao
RSC Advances, Vol. 6, Issue 106
DOI: 10.1039/C6RA20341H

Diamine modification of P84 polyimide membranes for pervaporation dehydration of isopropanol
journal, January 2006

Qiao, Xiangyi; Chung, Tai-Shung
AIChE Journal, Vol. 52, Issue 10
DOI: 10.1002/aic.10964

Crosslinked polybenzimidazole membranes for organic solvent nanofiltration (OSN): Analysis of crosslinking reaction mechanism and effects of reaction parameters
journal, November 2015

Valtcheva, Irina B.; Marchetti, Patrizia; Livingston, Andrew G.
Journal of Membrane Science, Vol. 493
DOI: 10.1016/j.memsci.2015.06.056

A non-equilibrium thermodynamics model for combined adsorption and diffusion processes in micro- and nanopores
journal, January 2012

Santamaría-Holek, Ivan; Grzywna, Zbigniew J.; Miguel Rubi, J.
Journal of Non-Equilibrium Thermodynamics, Vol. 37, Issue 3
DOI: 10.1515/jnetdy-2011-0029

Polyamide-imide hollow fiber membranes crosslinked with amine-appended inorganic networks for application in solvent-resistant nanofiltration under low operating pressure
journal, March 2016

Lim, Siow Kee; Setiawan, Laurentia; Bae, Tae-Hyun
Journal of Membrane Science, Vol. 501
DOI: 10.1016/j.memsci.2015.11.016

A novel monoamine modification strategy toward high-performance organic solvent nanofiltration (OSN) membrane for sustainable molecular separations
journal, January 2016

Xu, Yan Chao; Cheng, Xi Quan; Long, Jun
Journal of Membrane Science, Vol. 497
DOI: 10.1016/j.memsci.2015.09.029

Positively charged nanofiltration membranes via economically mussel-substance-simulated co-deposition for textile wastewater treatment
journal, November 2016

Xu, Yan Chao; Wang, Zhen Xing; Cheng, Xi Quan
Chemical Engineering Journal, Vol. 303
DOI: 10.1016/j.cej.2016.06.024

Efficient synthesis of interfacially polymerized membranes for solvent resistant nanofiltration
journal, February 2015

Hermans, Sanne; Dom, Elke; Mariën, Hanne
Journal of Membrane Science, Vol. 476
DOI: 10.1016/j.memsci.2014.11.046

Transformation of cross-linked polyimide UF membranes into highly permeable SRNF membranes via solvent annealing
journal, November 2017

Mariën, Hanne; Vankelecom, Ivo F. J.
Journal of Membrane Science, Vol. 541
DOI: 10.1016/j.memsci.2017.06.080

A novel positively charged composite nanofiltration membrane prepared by bio-inspired adhesion of polydopamine and surface grafting of poly(ethylene imine)
journal, November 2014

Zhang, Runnan; Su, Yanlei; Zhao, Xueting
Journal of Membrane Science, Vol. 470
DOI: 10.1016/j.memsci.2014.07.006

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DOI: 10.1515/zpch-2018-1299

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DOI: 10.1039/c9ta01915d

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journal, November 2018

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Title: High solvent-resistant and integrally crosslinked polyimide-based composite membranes for organic solvent nanofiltration

Abstract

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Molecular Separation with Organic Solvent Nanofiltration: A Critical Review journal, October 2014

Solvent resistant nanofiltration: separating on a molecular level journal, January 2008

Recent developments in thin film (nano)composite membranes for solvent resistant nanofiltration journal, May 2015

Polymer nanofilms with enhanced microporosity by interfacial polymerization journal, May 2016

Sustainability assessment of organic solvent nanofiltration: from fabrication to application journal, January 2014

The influence of membrane formation on functional performance of organic solvent nanofiltration membranes journal, November 2006

Polymeric membranes for nanofiltration in polar aprotic solvents journal, September 2007

A simplified diamine crosslinking method for PI nanofiltration membranes journal, May 2010

Synthesis and characterization of new polyimides containing ethynylene linkages journal, April 2007

Solvent recovery from lube oil filtrates with a polyimide membrane journal, November 2000

Pore preserving crosslinkers for polyimide OSN membranes journal, September 2014

Organic solvent resistant poly(ether-ether-ketone) nanofiltration membranes journal, April 2015

High throughput study of phase inversion parameters for polyimide-based SRNF membranes journal, March 2009

Cross-linked polyimide membranes for solvent resistant nanofiltration in aprotic solvents journal, July 2008

High flux membranes for organic solvent nanofiltration (OSN)—Interfacial polymerization with solvent activation journal, December 2012

High flux hydrophobic membranes for organic solvent nanofiltration (OSN)—Interfacial polymerization, surface modification and solvent activation journal, May 2013

Beneath the surface: Influence of supports on thin film composite membranes by interfacial polymerization for organic solvent nanofiltration journal, December 2013

Sub-10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation journal, June 2015

Preparation of thin film composite nanofiltration membrane with improved structural stability through the mediation of polydopamine journal, February 2015

Dopamine composite nanofiltration membranes prepared by self-polymerization and interfacial polymerization journal, September 2014

Polydopamine-Enabled Approach toward Tailored Plasmonic Nanogapped Nanoparticles: From Nanogap Engineering to Multifunctionality journal, November 2016

Mussel-Inspired Synthesis of Polydopamine-Functionalized Graphene Hydrogel as Reusable Adsorbents for Water Purification journal, December 2012

Polydopamine and Its Derivative Materials: Synthesis and Promising Applications in Energy, Environmental, and Biomedical Fields journal, February 2014

Realizing Mussel-Inspired Polydopamine Selective Layer with Strong Solvent Resistance in Nanofiltration toward Sustainable Reclamation journal, May 2017

Novel methodology for facile fabrication of nanofiltration membranes based on nucleophilic nature of polydopamine journal, August 2016

Novel reverse osmosis membranes incorporated with a hydrophilic additive for seawater desalination journal, April 2014

Polyimide thin film composite (TFC) membranes via interfacial polymerization on hydrolyzed polyacrylonitrile support for solvent resistant nanofiltration journal, January 2017

Preparation and performance of dynamic layer-by-layer PDADMAC/PSS nanofiltration membrane journal, December 2012

Hybrid polymer/MOF membranes for Organic Solvent Nanofiltration (OSN): Chemical modification and the quest for perfection journal, April 2016

Modelling of membrane nanofiltration—pore size distribution effects journal, April 2002

Modelling the performance of membrane nanofiltration—critical assessment and model development journal, April 2002

Use of the log-normal probability density function to analyze membrane pore size distributions: functional forms and discrepancies journal, June 1994

Diagnosis of membrane fouling using a rotating annular filter. 1. Cell culture media journal, February 1993

Correlation of diffusion coefficients in dilute solutions journal, June 1955

The effect of membrane formation parameters on performance of polyimide membranes for organic solvent nanofiltration (OSN). Part C. Effect of polyimide characteristics journal, September 2011

Novel diamine-modified composite nanofiltration membranes with chlorine resistance using monomers of 1,2,4,5-benzene tetracarbonyl chloride and m-phenylenediamine journal, January 2015

Chemical modification of P84 copolyimide membranes by polyethylenimine for nanofiltration journal, February 2009

P84 polyimide membranes modified by a tripodal amine for enhanced pervaporation dehydration of acetone journal, January 2015

Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes journal, May 2016

In situ regulation of micro-pore to design high performance polyimide membranes for pervaporation dehydration of isopropanol journal, November 2015

Interfacially synthesized chlorine-resistant polyimide thin film composite (TFC) reverse osmosis (RO) membranes journal, January 2013

The effect of membrane formation parameters on performance of polyimide membranes for organic solvent nanofiltration (OSN): Part A. Effect of polymer/solvent/non-solvent system choice journal, September 2011

Novel polyimide-based electrospun carbon nanofibers prepared using ion-beam irradiation journal, April 2012

Effects of iron catalyst on gas transport properties of ion-irradiated asymmetric polyimide membranes journal, June 2011

Thin film composite nanofiltration membrane prepared by the interfacial polymerization of 1,2,4,5-benzene tetracarbonyl chloride on the mixed amines cross-linked poly(ether imide) support journal, December 2016

Novel thin-film composite membranes via manipulating the synergistic interaction of dopamine and m-phenylenediamine for highly efficient forward osmosis desalination journal, January 2017

Cross-linked mixed matrix membranes consisting of carboxyl-functionalized multi-walled carbon nanotubes and P84 polyimide for organic solvent nanofiltration (OSN) journal, October 2017

Polyamide thin film composite membranes on cross-linked polyimide supports: Improvement of RO performance via activating solvent journal, July 2014

High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination journal, January 2013

Effect of chemical structures of amines on physicochemical properties of active layers and dehydration of isopropanol through interfacially polymerized thin-film composite membranes journal, January 2008

Bioadhesion-inspired fabrication of robust thin-film composite membranes with tunable solvent permeation properties journal, January 2016

Diamine modification of P84 polyimide membranes for pervaporation dehydration of isopropanol journal, January 2006

Crosslinked polybenzimidazole membranes for organic solvent nanofiltration (OSN): Analysis of crosslinking reaction mechanism and effects of reaction parameters journal, November 2015

A non-equilibrium thermodynamics model for combined adsorption and diffusion processes in micro- and nanopores journal, January 2012

Polyamide-imide hollow fiber membranes crosslinked with amine-appended inorganic networks for application in solvent-resistant nanofiltration under low operating pressure journal, March 2016

A novel monoamine modification strategy toward high-performance organic solvent nanofiltration (OSN) membrane for sustainable molecular separations journal, January 2016

Positively charged nanofiltration membranes via economically mussel-substance-simulated co-deposition for textile wastewater treatment journal, November 2016

Efficient synthesis of interfacially polymerized membranes for solvent resistant nanofiltration journal, February 2015

Transformation of cross-linked polyimide UF membranes into highly permeable SRNF membranes via solvent annealing journal, November 2017

A novel positively charged composite nanofiltration membrane prepared by bio-inspired adhesion of polydopamine and surface grafting of poly(ethylene imine) journal, November 2014

Finding Solvent for Polyamide 11 Using a Computer Software journal, March 2020

Graphene oxide (GO)-interlayered thin-film nanocomposite (TFN) membranes with high solvent resistance for organic solvent nanofiltration (OSN) journal, January 2019

Silane-Crosslinked Asymmetric Polythiosemicarbazide Membranes for Organic Solvent Nanofiltration journal, November 2018

Molecular Separation with Organic Solvent Nanofiltration: A Critical Review
journal, October 2014

Solvent resistant nanofiltration: separating on a molecular level
journal, January 2008

Recent developments in thin film (nano)composite membranes for solvent resistant nanofiltration
journal, May 2015

Polymer nanofilms with enhanced microporosity by interfacial polymerization
journal, May 2016

Sustainability assessment of organic solvent nanofiltration: from fabrication to application
journal, January 2014

The influence of membrane formation on functional performance of organic solvent nanofiltration membranes
journal, November 2006

Polymeric membranes for nanofiltration in polar aprotic solvents
journal, September 2007

A simplified diamine crosslinking method for PI nanofiltration membranes
journal, May 2010

Synthesis and characterization of new polyimides containing ethynylene linkages
journal, April 2007

Solvent recovery from lube oil filtrates with a polyimide membrane
journal, November 2000

Pore preserving crosslinkers for polyimide OSN membranes
journal, September 2014

Organic solvent resistant poly(ether-ether-ketone) nanofiltration membranes
journal, April 2015

High throughput study of phase inversion parameters for polyimide-based SRNF membranes
journal, March 2009

Cross-linked polyimide membranes for solvent resistant nanofiltration in aprotic solvents
journal, July 2008

High flux membranes for organic solvent nanofiltration (OSN)—Interfacial polymerization with solvent activation
journal, December 2012

High flux hydrophobic membranes for organic solvent nanofiltration (OSN)—Interfacial polymerization, surface modification and solvent activation
journal, May 2013

Beneath the surface: Influence of supports on thin film composite membranes by interfacial polymerization for organic solvent nanofiltration
journal, December 2013

Sub-10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation
journal, June 2015

Preparation of thin film composite nanofiltration membrane with improved structural stability through the mediation of polydopamine
journal, February 2015

Dopamine composite nanofiltration membranes prepared by self-polymerization and interfacial polymerization
journal, September 2014

Polydopamine-Enabled Approach toward Tailored Plasmonic Nanogapped Nanoparticles: From Nanogap Engineering to Multifunctionality
journal, November 2016

Mussel-Inspired Synthesis of Polydopamine-Functionalized Graphene Hydrogel as Reusable Adsorbents for Water Purification
journal, December 2012

Polydopamine and Its Derivative Materials: Synthesis and Promising Applications in Energy, Environmental, and Biomedical Fields
journal, February 2014

Realizing Mussel-Inspired Polydopamine Selective Layer with Strong Solvent Resistance in Nanofiltration toward Sustainable Reclamation
journal, May 2017

Novel methodology for facile fabrication of nanofiltration membranes based on nucleophilic nature of polydopamine
journal, August 2016

Novel reverse osmosis membranes incorporated with a hydrophilic additive for seawater desalination
journal, April 2014

Polyimide thin film composite (TFC) membranes via interfacial polymerization on hydrolyzed polyacrylonitrile support for solvent resistant nanofiltration
journal, January 2017

Preparation and performance of dynamic layer-by-layer PDADMAC/PSS nanofiltration membrane
journal, December 2012

Hybrid polymer/MOF membranes for Organic Solvent Nanofiltration (OSN): Chemical modification and the quest for perfection
journal, April 2016

Modelling of membrane nanofiltration—pore size distribution effects
journal, April 2002

Modelling the performance of membrane nanofiltration—critical assessment and model development
journal, April 2002

Use of the log-normal probability density function to analyze membrane pore size distributions: functional forms and discrepancies
journal, June 1994

Diagnosis of membrane fouling using a rotating annular filter. 1. Cell culture media
journal, February 1993

Correlation of diffusion coefficients in dilute solutions
journal, June 1955

The effect of membrane formation parameters on performance of polyimide membranes for organic solvent nanofiltration (OSN). Part C. Effect of polyimide characteristics
journal, September 2011

Novel diamine-modified composite nanofiltration membranes with chlorine resistance using monomers of 1,2,4,5-benzene tetracarbonyl chloride and m-phenylenediamine
journal, January 2015

Chemical modification of P84 copolyimide membranes by polyethylenimine for nanofiltration
journal, February 2009

P84 polyimide membranes modified by a tripodal amine for enhanced pervaporation dehydration of acetone
journal, January 2015

Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes
journal, May 2016

In situ regulation of micro-pore to design high performance polyimide membranes for pervaporation dehydration of isopropanol
journal, November 2015

Interfacially synthesized chlorine-resistant polyimide thin film composite (TFC) reverse osmosis (RO) membranes
journal, January 2013

The effect of membrane formation parameters on performance of polyimide membranes for organic solvent nanofiltration (OSN): Part A. Effect of polymer/solvent/non-solvent system choice
journal, September 2011

Novel polyimide-based electrospun carbon nanofibers prepared using ion-beam irradiation
journal, April 2012

Effects of iron catalyst on gas transport properties of ion-irradiated asymmetric polyimide membranes
journal, June 2011

Thin film composite nanofiltration membrane prepared by the interfacial polymerization of 1,2,4,5-benzene tetracarbonyl chloride on the mixed amines cross-linked poly(ether imide) support
journal, December 2016

Novel thin-film composite membranes via manipulating the synergistic interaction of dopamine and m-phenylenediamine for highly efficient forward osmosis desalination
journal, January 2017

Cross-linked mixed matrix membranes consisting of carboxyl-functionalized multi-walled carbon nanotubes and P84 polyimide for organic solvent nanofiltration (OSN)
journal, October 2017

Polyamide thin film composite membranes on cross-linked polyimide supports: Improvement of RO performance via activating solvent
journal, July 2014

High-flux reverse osmosis membranes incorporated with hydrophilic additives for brackish water desalination
journal, January 2013

Effect of chemical structures of amines on physicochemical properties of active layers and dehydration of isopropanol through interfacially polymerized thin-film composite membranes
journal, January 2008

Bioadhesion-inspired fabrication of robust thin-film composite membranes with tunable solvent permeation properties
journal, January 2016

Diamine modification of P84 polyimide membranes for pervaporation dehydration of isopropanol
journal, January 2006

Crosslinked polybenzimidazole membranes for organic solvent nanofiltration (OSN): Analysis of crosslinking reaction mechanism and effects of reaction parameters
journal, November 2015

A non-equilibrium thermodynamics model for combined adsorption and diffusion processes in micro- and nanopores
journal, January 2012

Polyamide-imide hollow fiber membranes crosslinked with amine-appended inorganic networks for application in solvent-resistant nanofiltration under low operating pressure
journal, March 2016

A novel monoamine modification strategy toward high-performance organic solvent nanofiltration (OSN) membrane for sustainable molecular separations
journal, January 2016

Positively charged nanofiltration membranes via economically mussel-substance-simulated co-deposition for textile wastewater treatment
journal, November 2016

Efficient synthesis of interfacially polymerized membranes for solvent resistant nanofiltration
journal, February 2015

Transformation of cross-linked polyimide UF membranes into highly permeable SRNF membranes via solvent annealing
journal, November 2017

A novel positively charged composite nanofiltration membrane prepared by bio-inspired adhesion of polydopamine and surface grafting of poly(ethylene imine)
journal, November 2014

Finding Solvent for Polyamide 11 Using a Computer Software
journal, March 2020

Graphene oxide (GO)-interlayered thin-film nanocomposite (TFN) membranes with high solvent resistance for organic solvent nanofiltration (OSN)
journal, January 2019

Silane-Crosslinked Asymmetric Polythiosemicarbazide Membranes for Organic Solvent Nanofiltration
journal, November 2018