Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites

Guo, Jing; Zhao, Xuetong; Herisson De Beauvoir, Thomas; Seo, Joo‐Hwan; Berbano, Seth S.; Baker, Amanda L.; Azina, Clio; Randall, Clive A.

doi:10.1002/adfm.201801724

Title: Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites

Abstract

Abstract Ceramic–polymer composites are of interest for designing enhanced and unique properties. However, the processing temperature windows of sintering ceramics are much higher than that of compaction, extrusion, or sintering of polymers, and thus traditionally there has been an inability to cosinter ceramic–polymer composites in a single step with high amounts of ceramics. The cold sintering process is a low‐temperature sintering technology recently developed for ceramics and ceramic‐based composites. A wide variety of ceramic materials have now been demonstrated to be densified under the cold sintering process and therefore can be all cosintered with polymers from room temperature to 300 °C. Here, the status, understanding, and application of cold cosintering, with different examples of ceramics and polymers, are discussed. One has to note that these types of cold sintering processes are yet new, and a full understanding will only emerge after more ceramic–polymer examples emerge and different research groups build upon these early observations. The general processing, property designs, and an outlook on cold sintering composites are outlined. Ultimately, the cold sintering process could open up a new multimaterial design space and impact the field of ceramic–polymer composites.

Authors:

Guo, Jing ^[1]; Zhao, Xuetong ^[2]; Herisson De Beauvoir, Thomas ^[1]; Seo, Joo‐Hwan ^[1]; Berbano, Seth S. ^[1]; Baker, Amanda L. ^[1]; Azina, Clio ^[3]; Randall, Clive A. ^[1]

Materials Research Institute and Department of Materials Science &, Engineering The Pennsylvania State University University Park PA 16802 USA
Materials Research Institute and Department of Materials Science &, Engineering The Pennsylvania State University University Park PA 16802 USA, State Key Laboratory of Power Transmission Equipment &, System Security and New Technology Chongqing University Shapingba District Chongqing 400044 P. R. China
CNRS University of Bordeaux ICMCB UMR 5026 F‐33600 Pessac France

Publication Date:: Wed Aug 01 00:00:00 EDT 2018

Sponsoring Org.:: USDOE

OSTI Identifier:: 1462778

Grant/Contract Number:: DE‐AR0000766

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Name: Advanced Functional Materials Journal Volume: 28 Journal Issue: 39; Journal ID: ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Guo, Jing, Zhao, Xuetong, Herisson De Beauvoir, Thomas, Seo, Joo‐Hwan, Berbano, Seth S., Baker, Amanda L., Azina, Clio, and Randall, Clive A. Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites.  Germany: N. p., 2018. 
Web.  doi:10.1002/adfm.201801724.

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                    Guo, Jing, Zhao, Xuetong, Herisson De Beauvoir, Thomas, Seo, Joo‐Hwan, Berbano, Seth S., Baker, Amanda L., Azina, Clio, & Randall, Clive A. Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites.  Germany.  https://doi.org/10.1002/adfm.201801724

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                    Guo, Jing, Zhao, Xuetong, Herisson De Beauvoir, Thomas, Seo, Joo‐Hwan, Berbano, Seth S., Baker, Amanda L., Azina, Clio, and Randall, Clive A. Wed .  
"Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites".  Germany.  https://doi.org/10.1002/adfm.201801724.

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@article{osti_1462778,

  title        = {Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites},

  author       = {Guo, Jing and Zhao, Xuetong and Herisson De Beauvoir, Thomas and Seo, Joo‐Hwan and Berbano, Seth S. and Baker, Amanda L. and Azina, Clio and Randall, Clive A.},

  abstractNote = {Abstract Ceramic–polymer composites are of interest for designing enhanced and unique properties. However, the processing temperature windows of sintering ceramics are much higher than that of compaction, extrusion, or sintering of polymers, and thus traditionally there has been an inability to cosinter ceramic–polymer composites in a single step with high amounts of ceramics. The cold sintering process is a low‐temperature sintering technology recently developed for ceramics and ceramic‐based composites. A wide variety of ceramic materials have now been demonstrated to be densified under the cold sintering process and therefore can be all cosintered with polymers from room temperature to 300 °C. Here, the status, understanding, and application of cold cosintering, with different examples of ceramics and polymers, are discussed. One has to note that these types of cold sintering processes are yet new, and a full understanding will only emerge after more ceramic–polymer examples emerge and different research groups build upon these early observations. The general processing, property designs, and an outlook on cold sintering composites are outlined. Ultimately, the cold sintering process could open up a new multimaterial design space and impact the field of ceramic–polymer composites.},

  doi          = {10.1002/adfm.201801724},

  journal      = {Advanced Functional Materials},

  number       = 39,

  volume       = 28,

  place        = {Germany},

  year         = {Wed Aug 01 00:00:00 EDT 2018},

  month        = {Wed Aug 01 00:00:00 EDT 2018}

}

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Works referenced in this record:

MATERIALS SCIENCE: Talking Ceramics
journal, November 2002

Vanderah, T. A.
Science, Vol. 298, Issue 5596
DOI: 10.1126/science.1078489

Polymer nanocomposites
journal, January 2007

Krishnamoorti, Ramanan; Vaia, Richard A.
Journal of Polymer Science Part B: Polymer Physics, Vol. 45, Issue 24
DOI: 10.1002/polb.21319

The role of viscoelasticity in polymer sintering
journal, June 1998

Bellehumeur, C. T.; Kontopoulou, Marianne; Vlachopoulos, J.
Rheologica Acta, Vol. 37, Issue 3
DOI: 10.1007/s003970050114

An Interfacial Complex in ZnO and Its Influence on Charge Transport
journal, October 2003

Carlsson, Johan M.; Domingos, Helder S.; Bristowe, Paul D.
Physical Review Letters, Vol. 91, Issue 16
DOI: 10.1103/PhysRevLett.91.165506

Polyethylene nanocomposite dielectrics: Implications of nanofiller orientation on high field properties and energy storage
journal, April 2011

Tomer, V.; Polizos, G.; Randall, C. A.
Journal of Applied Physics, Vol. 109, Issue 7
DOI: 10.1063/1.3569696

Polymer Layered Silicate Nanocomposites
journal, January 1996

Giannelis, Emmanuel P.
Advanced Materials, Vol. 8, Issue 1
DOI: 10.1002/adma.19960080104

Cold Sintering Process: A Novel Technique for Low-Temperature Ceramic Processing of Ferroelectrics
journal, October 2016

Guo, Hanzheng; Baker, Amanda; Guo, Jing
Journal of the American Ceramic Society, Vol. 99, Issue 11
DOI: 10.1111/jace.14554

Connectivity and piezoelectric-pyroelectric composites
journal, May 1978

Newnham, R. E.; Skinner, D. P.; Cross, L. E.
Materials Research Bulletin, Vol. 13, Issue 5
DOI: 10.1016/0025-5408(78)90161-7

Semiconducting properties of cold sintered V2O5 ceramics and Co-sintered V2O5-PEDOT:PSS composites
journal, April 2017

Guo, Jing; Guo, Hanzheng; Heidary, Damoon Sohrabi Baba
Journal of the European Ceramic Society, Vol. 37, Issue 4
DOI: 10.1016/j.jeurceramsoc.2016.11.021

A hydrothermal hot-pressing method: Apparatus and application
journal, March 1986

Yamasaki, N.; Yanagisawa, K.; Nishioka, M.
Journal of Materials Science Letters, Vol. 5, Issue 3
DOI: 10.1007/BF01748104

Recent advances in ZnO materials and devices
journal, March 2001

Look, D. C.
Materials Science and Engineering: B, Vol. 80, Issue 1-3
DOI: 10.1016/S0921-5107(00)00604-8

Polar Nanoregions and Dielectric Properties of BaTiO ₃ -Based Y5V Multilayer Ceramic Capacitors
journal, March 2014

Hong, Jian-Yu; Lu, Hong-Yang
Journal of the American Ceramic Society, Vol. 97, Issue 7
DOI: 10.1111/jace.12896

Geologically-inspired strong bulk ceramics made with water at room temperature
journal, March 2017

Bouville, Florian; Studart, André R.
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms14655

Methods for predicting the thermal conductivity of composite systems: A review
journal, September 1976

Progelhof, R. C.; Throne, J. L.; Ruetsch, R. R.
Polymer Engineering and Science, Vol. 16, Issue 9
DOI: 10.1002/pen.760160905

Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions
journal, March 2003

Vayssieres, L.
Advanced Materials, Vol. 15, Issue 5
DOI: 10.1002/adma.200390108

A Statistical Distribution Function of Wide Applicability
journal, September 1951

Weibull, Waloddi
Journal of Applied Mechanics, Vol. 18, Issue 3
DOI: 10.1115/1.4010337

Cold sintering of a Li-ion cathode: LiFePO4-composite with high volumetric capacity
journal, December 2017

Seo, Joo-Hwan; Guo, Jing; Guo, Hanzheng
Ceramics International, Vol. 43, Issue 17
DOI: 10.1016/j.ceramint.2017.08.077

Tape Casting and Dielectric Properties of Zn ₂ Te ₃ O ₈ -Based Ceramics with an Ultra-Low Sintering Temperature
journal, July 2009

Honkamo, Johanna; Jantunen, Heli; Subodh, Ganesanpotti
International Journal of Applied Ceramic Technology, Vol. 6, Issue 4
DOI: 10.1111/j.1744-7402.2008.02296.x

Temperature coefficients of capacitance of solids
journal, April 1969

Harrop, P. J.
Journal of Materials Science, Vol. 4, Issue 4
DOI: 10.1007/BF00550407

Microwave Dielectric Properties and Low-Temperature Cofiring of BaTe4O9 with Aluminum Metal Electrode
journal, December 2005

Kwon, Do-Kyun; Lanagan, Michael T.; Shrout, Thomas R.
Journal of the American Ceramic Society, Vol. 88, Issue 12
DOI: 10.1111/j.1551-2916.2005.00613.x

Fabrication, characterization, properties and theoretical analysis of ceramic/PVDF composite flexible films with high dielectric constant and low dielectric loss
journal, January 2014

Luo, Bingcheng; Wang, Xiaohui; Wang, Yueping
J. Mater. Chem. A, Vol. 2, Issue 2
DOI: 10.1039/C3TA14107A

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics
journal, August 2016

Guo, Jing; Guo, Hanzheng; Baker, Amanda L.
Angewandte Chemie International Edition, Vol. 55, Issue 38
DOI: 10.1002/anie.201605443

Dielectric characterisation of ceramics from the TiO2–TeO2 system
journal, January 2001

Udovic, M.; Valant, M.; Suvorov, D.
Journal of the European Ceramic Society, Vol. 21, Issue 10-11
DOI: 10.1016/S0955-2219(01)00105-4

Chemical State Analysis of Grain Boundaries in ZnO Varistors by Auger Electron Spectroscopy
journal, July 1993

Tanaka, Shigeru; Akita, Chiyoshi; Ohashi, Naoki
Journal of Solid State Chemistry, Vol. 105, Issue 1
DOI: 10.1006/jssc.1993.1191

Cold sintering approach to fabrication of high rate performance binderless LiFePO4 cathode with high volumetric capacity
journal, March 2018

Seo, Joo-Hwan; Verlinde, Kris; Guo, Jing
Scripta Materialia, Vol. 146
DOI: 10.1016/j.scriptamat.2017.12.005

Thermal conductivity, elastic modulus, and coefficient of thermal expansion of polymer composites filled with ceramic particles for electronic packaging
journal, December 1999

Wong, C. P.; Bollampally, Raja S.
Journal of Applied Polymer Science, Vol. 74, Issue 14
DOI: 10.1002/(SICI)1097-4628(19991227)74:14<3396::AID-APP13>3.0.CO;2-3

Size-dependence of the dielectric breakdown strength from nano- to millimeter scale
journal, February 2014

Neusel, Claudia; Schneider, Gerold A.
Journal of the Mechanics and Physics of Solids, Vol. 63
DOI: 10.1016/j.jmps.2013.09.009

Solution-Processed Metallic Conducting Polymer Films as Transparent Electrode of Optoelectronic Devices
journal, April 2012

Xia, Yijie; Sun, Kuan; Ouyang, Jianyong
Advanced Materials, Vol. 24, Issue 18
DOI: 10.1002/adma.201104795

Low-temperature fabrication of titanium metal/barium titanate composite capacitors via hydrothermal method and their dielectric properties
journal, January 2014

Ueno, Shintaro; Sakamoto, Yasunao; Nakashima, Kouichi
Journal of the Ceramic Society of Japan, Vol. 122, Issue 1426
DOI: 10.2109/jcersj2.122.447

Overview of Fine-Scale Piezoelectric Ceramic/Polymer Composite Processing
journal, November 1995

Janas, Victor F.; Safari, Ahmad
Journal of the American Ceramic Society, Vol. 78, Issue 11
DOI: 10.1111/j.1151-2916.1995.tb09068.x

Dielectric materials for applications in microwave communications
journal, January 2001

Cava, R. J.
Journal of Materials Chemistry, Vol. 11, Issue 1
DOI: 10.1039/b003681l

Physical Properties of Composites Near Percolation
journal, June 2010

Nan, C. -W.; Shen, Y.; Ma, Jing
Annual Review of Materials Research, Vol. 40, Issue 1
DOI: 10.1146/annurev-matsci-070909-104529

Small-Polaron Hopping Motion in Some Chalcogenide Glasses
journal, March 1972

Emin, David; Seager, C. H.; Quinn, Rod K.
Physical Review Letters, Vol. 28, Issue 13
DOI: 10.1103/PhysRevLett.28.813

Piezotronically Modified Double Schottky Barriers in ZnO Varistors
journal, February 2015

Raidl, Nadine; Supancic, Peter; Danzer, Robert
Advanced Materials, Vol. 27, Issue 12
DOI: 10.1002/adma.201403707

Low temperature hydrothermal sintering process for the quasi-complete densification of nanometric α-quartz
journal, March 2018

Ndayishimiye, Arnaud; Largeteau, Alain; Prakasam, Mythili
Scripta Materialia, Vol. 145
DOI: 10.1016/j.scriptamat.2017.10.023

Low temperature co-fired ceramics with ultra-low sintering temperature: A review
journal, June 2016

Sebastian, Mailadil Thomas; Wang, Hong; Jantunen, Heli
Current Opinion in Solid State and Materials Science, Vol. 20, Issue 3
DOI: 10.1016/j.cossms.2016.02.004

Grain Growth of ZnO during Bi2O3 Liquid-Phase Sintering
journal, September 1992

Dey, Debashis; Bradt, Richard C.
Journal of the American Ceramic Society, Vol. 75, Issue 9
DOI: 10.1111/j.1151-2916.1992.tb05607.x

New prospects in flame retardant polymer materials: From fundamentals to nanocomposites
journal, January 2009

Laoutid, F.; Bonnaud, L.; Alexandre, M.
Materials Science and Engineering: R: Reports, Vol. 63, Issue 3
DOI: 10.1016/j.mser.2008.09.002

Utilizing the Cold Sintering Process for Flexible-Printable Electroceramic Device Fabrication
journal, August 2016

Baker, Amanda; Guo, Hanzheng; Guo, Jing
Journal of the American Ceramic Society, Vol. 99, Issue 10
DOI: 10.1111/jace.14467

Reactive Hydrothermal Liquid-Phase Densification (rHLPD) of Ceramics - A Study of the BaTiO ₃ [TiO ₂ ] Composite System
journal, August 2016

Vakifahmetoglu, Cekdar; Anger, Jean Francois; Atakan, Vahit
Journal of the American Ceramic Society, Vol. 99, Issue 12
DOI: 10.1111/jace.14468

Polymer/layered silicate nanocomposites: a review from preparation to processing
journal, November 2003

Sinha Ray, Suprakas; Okamoto, Masami
Progress in Polymer Science, Vol. 28, Issue 11
DOI: 10.1016/j.progpolymsci.2003.08.002

Microwave dielectric properties of cold sintered Al 2 O 3 -NaCl composite
journal, January 2018

Induja, I. J.; Sebastian, M. T.
Materials Letters, Vol. 211
DOI: 10.1016/j.matlet.2017.09.083

Characterization of individual interfacial barriers in a ZnO varistor material
journal, October 1989

Olsson, E.; Dunlop, G. L.
Journal of Applied Physics, Vol. 66, Issue 8
DOI: 10.1063/1.344453

Hydrothermal Preparation and Sintering of Fine Ceramic Powders
journal, January 1983

Sōmiya, Shigeyuki
MRS Proceedings, Vol. 24
DOI: 10.1557/PROC-24-255

Composite electroceramics
journal, January 1986

Newnham, R. E.
Ferroelectrics, Vol. 68, Issue 1
DOI: 10.1080/00150198608238734

The temperature coefficient of capacitance
journal, September 1968

Cockbain, A. G.; Harrop, P. J.
Journal of Physics D: Applied Physics, Vol. 1, Issue 9
DOI: 10.1088/0022-3727/1/9/302

Engineered doping of organic semiconductors for enhanced thermoelectric efficiency
journal, May 2013

Kim, G-H.; Shao, L.; Zhang, K.
Nature Materials, Vol. 12, Issue 8
DOI: 10.1038/nmat3635

Water-assisted flash sintering: Flashing ZnO at room temperature to achieve ~ 98% density in seconds
journal, January 2018

Nie, Jiuyuan; Zhang, Yuanyao; Chan, Jonathan M.
Scripta Materialia, Vol. 142
DOI: 10.1016/j.scriptamat.2017.08.032

Reoxidation Effects of Ba-Excessive Barium Titanate Ceramics for Laminated Positive Temperature Coefficient Thermistors
journal, January 2012

Liu, Jianqiao; Gong, Shuping; Quan, Lin
Journal of the American Ceramic Society, Vol. 95, Issue 5
DOI: 10.1111/j.1551-2916.2011.05041.x

Cold sintering and electrical characterization of lead zirconate titanate piezoelectric ceramics
journal, January 2018

Wang, Dixiong; Guo, Hanzheng; Morandi, Carl S.
APL Materials, Vol. 6, Issue 1
DOI: 10.1063/1.5004420

Ceramic–Polymer Composites with High Dielectric Constant
journal, May 2007

Arbatti, M.; Shan, X.; Cheng, Z. -Y.
Advanced Materials, Vol. 19, Issue 10
DOI: 10.1002/adma.200601996

Overview of low temperature co-fired ceramics tape technology for meso-system technology (MsST)
journal, April 2001

Gongora-Rubio, M. R.; Espinoza-Vallejos, P.; Sola-Laguna, L.
Sensors and Actuators A: Physical, Vol. 89, Issue 3
DOI: 10.1016/S0924-4247(00)00554-9

On the temperature coefficient of resonant frequency in microwave dielectrics
journal, February 2001

Reaney, I. M.; Wise, P.; Ubic, R.
Philosophical Magazine A, Vol. 81, Issue 2
DOI: 10.1080/01418610108214318

Current progress and perspectives of applying cold sintering process to ZrO2-based ceramics
journal, July 2017

Guo, Hanzheng; Bayer, Thorsten J. M.; Guo, Jing
Scripta Materialia, Vol. 136
DOI: 10.1016/j.scriptamat.2017.02.004

HREM and STEM of intergranular films at zinc oxide varistor grain boundaries
journal, September 1998

Chiang,
Journal of Microscopy, Vol. 191, Issue 3
DOI: 10.1046/j.1365-2818.1998.00377.x

Intercalated clay nanocomposites: Morphology, mechanics, and fracture behavior
journal, January 2001

Zerda, Adam S.; Lesser, Alan J.
Journal of Polymer Science Part B: Polymer Physics, Vol. 39, Issue 11
DOI: 10.1002/polb.1090

Microwave dielectric properties of mineral sillimanite obtained by conventional and cold sintering process
journal, May 2017

Induja, I. J.; Sebastian, M. T.
Journal of the European Ceramic Society, Vol. 37, Issue 5
DOI: 10.1016/j.jeurceramsoc.2017.01.007

Highly Conductive PEDOT:PSS Electrode with Optimized Solvent and Thermal Post-Treatment for ITO-Free Organic Solar Cells
journal, February 2011

Kim, Yong Hyun; Sachse, Christoph; Machala, Michael L.
Advanced Functional Materials, Vol. 21, Issue 6
DOI: 10.1002/adfm.201002290

The microstructure of a ZnO varistor material
journal, November 1985

Olsson, E.; Falk, L. K. L.; Dunlop, G. L.
Journal of Materials Science, Vol. 20, Issue 11
DOI: 10.1007/BF00552403

A review of particulate reinforcement theories for polymer composites
journal, December 1990

Ahmed, S.; Jones, F. R.
Journal of Materials Science, Vol. 25, Issue 12
DOI: 10.1007/BF00580110

Cold sintering and co-firing of a multilayer device with thermoelectric materials
journal, April 2017

Funahashi, Shuichi; Guo, Hanzheng; Guo, Jing
Journal of the American Ceramic Society, Vol. 100, Issue 8
DOI: 10.1111/jace.14852

Physical model for breakdown structures in solid dielectrics
journal, December 1993

Dissado, L. A.; Sweeney, P. J. J.
Physical Review B, Vol. 48, Issue 22
DOI: 10.1103/PhysRevB.48.16261

Polymer-Ceramic Composites of 0-3 Connectivity for Circuits in Electronics: A Review
journal, January 2010

Sebastian, Mailadil T.; Jantunen, Heli
International Journal of Applied Ceramic Technology
DOI: 10.1111/j.1744-7402.2009.02482.x

Design of 0–3 type nanocomposites using hydrothermal sintering
journal, April 2018

Ndayishimiye, Arnaud; Buffière, Sonia; Dourges, Marie-Anne
Scripta Materialia, Vol. 148
DOI: 10.1016/j.scriptamat.2018.01.013

Impact strength of polymer-clay nanocomposites
journal, January 2009

Chen, Biqiong; Evans, Julian R. G.
Soft Matter, Vol. 5, Issue 19
DOI: 10.1039/b902073j

Demonstration of the cold sintering process study for the densification and grain growth of ZnO ceramics
journal, October 2016

Funahashi, Shuichi; Guo, Jing; Guo, Hanzheng
Journal of the American Ceramic Society, Vol. 100, Issue 2
DOI: 10.1111/jace.14617

Improvements and Modifications to Room-Temperature Fabrication Method for Dielectric Li ₂ MoO ₄ Ceramics
journal, January 2015

Kähäri, Hanna; Teirikangas, Merja; Juuti, Jari
Journal of the American Ceramic Society, Vol. 98, Issue 3
DOI: 10.1111/jace.13471

Unveiling the mechanisms of cold sintering of ZnO at 250 °C by varying applied stress and characterizing grain boundaries by Kelvin Probe Force Microscopy
journal, February 2018

Gonzalez-Julian, J.; Neuhaus, K.; Bernemann, M.
Acta Materialia, Vol. 144
DOI: 10.1016/j.actamat.2017.10.055

Hall-Effect Sign Anomaly and Small-Polaron Conduction in $({La}_{1 - x} {Gd}_{x})_{0.67} {Ca}_{0.33} {MnO}_{3}$
journal, February 1997

Jaime, M.; Hardner, H. T.; Salamon, M. B.
Physical Review Letters, Vol. 78, Issue 5
DOI: 10.1103/PhysRevLett.78.951

The microstructural location of the intergranular metal-oxide phase in a zinc oxide varistor
journal, January 1978

Clarke, David R.
Journal of Applied Physics, Vol. 49, Issue 4
DOI: 10.1063/1.325135

Overview on fabrication of three-dimensional structures in multi-layer ceramic substrate
journal, August 2010

Khoong, L. E.; Tan, Y. M.; Lam, Y. C.
Journal of the European Ceramic Society, Vol. 30, Issue 10
DOI: 10.1016/j.jeurceramsoc.2010.03.011

Equation for the effective permittivity of particle-filled composites for material design applications
journal, August 2007

Jylhä, Liisi; Sihvola, Ari
Journal of Physics D: Applied Physics, Vol. 40, Issue 16
DOI: 10.1088/0022-3727/40/16/032

Processing and Dielectric Properties of Sillenite Compounds Bi ₁₂ MO _20−δ (M = Si, Ge, Ti, Pb, Mn, B _1/2 P _1/2 )
journal, December 2001

Valant, Matjaz; Suvorov, Danilo
Journal of the American Ceramic Society, Vol. 84, Issue 12
DOI: 10.1111/j.1151-2916.2001.tb01112.x

Dielectric Properties of Lithium Molybdate Ceramic Fabricated at Room Temperature
journal, October 2014

Kähäri, Hanna; Teirikangas, Merja; Juuti, Jari
Journal of the American Ceramic Society, Vol. 97, Issue 11
DOI: 10.1111/jace.13277

Nonohmic Properties of Zinc Oxide Ceramics
journal, June 1971

Matsuoka, Michio
Japanese Journal of Applied Physics, Vol. 10, Issue 6
DOI: 10.1143/JJAP.10.736

Polymer Properties
book, December 2009

Van Krevelen, D. W.; Te Nijenhuis, K.
Properties of Polymers
DOI: 10.1016/B978-0-08-054819-7.00001-7

Cold-Sintered Temperature Stable Na _0.5 Bi _0.5 MoO ₄ –Li ₂ MoO ₄ Microwave Composite Ceramics
journal, December 2017

Wang, Dawei; Zhou, Di; Zhang, Shiyu
ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 2
DOI: 10.1021/acssuschemeng.7b03889

Electrical Resistivity of Composites
journal, August 1990

McLachlan, David S.; Blaszkiewicz, Michael; Newnham, Robert E.
Journal of the American Ceramic Society, Vol. 73, Issue 8
DOI: 10.1111/j.1151-2916.1990.tb07576.x

Flammability Properties of Polymer−Layered-Silicate Nanocomposites. Polypropylene and Polystyrene Nanocomposites ^†
journal, July 2000

Gilman, Jeffrey W.; Jackson, Catheryn L.; Morgan, Alexander B.
Chemistry of Materials, Vol. 12, Issue 7
DOI: 10.1021/cm0001760

Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials
journal, June 2000

Alexandre, Michael; Dubois, Philippe
Materials Science and Engineering: R: Reports, Vol. 28, Issue 1-2
DOI: 10.1016/S0927-796X(00)00012-7

Current Dependence of Voltage Non-linearity in SiC Varistors
journal, October 1968

Masuyama, Takeshi; Matsuoka, Michio
Japanese Journal of Applied Physics, Vol. 7, Issue 10
DOI: 10.1143/JJAP.7.1294

Cold Sintering Process of Composites: Bridging the Processing Temperature Gap of Ceramic and Polymer Materials
journal, August 2016

Guo, Jing; Berbano, Seth S.; Guo, Hanzheng
Advanced Functional Materials, Vol. 26, Issue 39
DOI: 10.1002/adfm.201602489

Microwave Dielectric Properties of Low Temperature Firing Bi ₂ Mo ₂ O ₉ Ceramic
journal, October 2008

Zhou, Di; Wang, Hong; Yao, Xi
Journal of the American Ceramic Society, Vol. 91, Issue 10
DOI: 10.1111/j.1551-2916.2008.02596.x

Cold sintering: Current status and prospects
journal, July 2017

Maria, Jon-Paul; Kang, Xiaoyu; Floyd, Richard D.
Journal of Materials Research, Vol. 32, Issue 17
DOI: 10.1557/jmr.2017.262

A comprehensive review of ZnO materials and devices
journal, August 2005

Özgür, Ü.; Alivov, Ya. I.; Liu, C.
Journal of Applied Physics, Vol. 98, Issue 4
DOI: 10.1063/1.1992666

Microwave Dielectric Ceramics in Li ₂ O-Bi ₂ O ₃ -MoO ₃ System with Ultra-Low Sintering Temperatures
journal, April 2010

Zhou, Di; Randall, Clive A.; Wang, Hong
Journal of the American Ceramic Society, Vol. 93, Issue 4
DOI: 10.1111/j.1551-2916.2009.03526.x

Cold sintering process: A new era for ceramic packaging and microwave device development
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Guo, Jing; Baker, Amanda L.; Guo, Hanzheng
Journal of the American Ceramic Society, Vol. 100, Issue 2
DOI: 10.1111/jace.14603

Microwave ceramics for resonators and filters
journal, October 1996

Wersing, Wolfram
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DOI: 10.1016/S1359-0286(96)80056-8

Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction
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Bachman, John Christopher; Muy, Sokseiha; Grimaud, Alexis
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DOI: 10.1021/acs.chemrev.5b00563

Microwave Dielectric Ceramics for Resonators and Filters in Mobile Phone Networks
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Journal of the American Ceramic Society, Vol. 0, Issue 0
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Cold sintering process of Li _1.5 Al _0.5 Ge _1.5 (PO ₄ ) ₃ solid electrolyte
journal, March 2017

Berbano, Seth S.; Guo, Jing; Guo, Hanzheng
Journal of the American Ceramic Society, Vol. 100, Issue 5
DOI: 10.1111/jace.14727

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Title: Recent Progress in Applications of the Cold Sintering Process for Ceramic–Polymer Composites

Abstract

Citation Formats

MATERIALS SCIENCE: Talking Ceramics journal, November 2002

Polymer nanocomposites journal, January 2007

The role of viscoelasticity in polymer sintering journal, June 1998

An Interfacial Complex in ZnO and Its Influence on Charge Transport journal, October 2003

Polyethylene nanocomposite dielectrics: Implications of nanofiller orientation on high field properties and energy storage journal, April 2011

Polymer Layered Silicate Nanocomposites journal, January 1996

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Connectivity and piezoelectric-pyroelectric composites journal, May 1978

Semiconducting properties of cold sintered V2O5 ceramics and Co-sintered V2O5-PEDOT:PSS composites journal, April 2017

A hydrothermal hot-pressing method: Apparatus and application journal, March 1986

Recent advances in ZnO materials and devices journal, March 2001

Polar Nanoregions and Dielectric Properties of BaTiO 3 -Based Y5V Multilayer Ceramic Capacitors journal, March 2014

Geologically-inspired strong bulk ceramics made with water at room temperature journal, March 2017

Methods for predicting the thermal conductivity of composite systems: A review journal, September 1976

Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions journal, March 2003

A Statistical Distribution Function of Wide Applicability journal, September 1951

Cold sintering of a Li-ion cathode: LiFePO4-composite with high volumetric capacity journal, December 2017

Tape Casting and Dielectric Properties of Zn 2 Te 3 O 8 -Based Ceramics with an Ultra-Low Sintering Temperature journal, July 2009

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Microwave Dielectric Properties and Low-Temperature Cofiring of BaTe4O9 with Aluminum Metal Electrode journal, December 2005

Fabrication, characterization, properties and theoretical analysis of ceramic/PVDF composite flexible films with high dielectric constant and low dielectric loss journal, January 2014

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics journal, August 2016

Dielectric characterisation of ceramics from the TiO2–TeO2 system journal, January 2001

Chemical State Analysis of Grain Boundaries in ZnO Varistors by Auger Electron Spectroscopy journal, July 1993

Cold sintering approach to fabrication of high rate performance binderless LiFePO4 cathode with high volumetric capacity journal, March 2018

Thermal conductivity, elastic modulus, and coefficient of thermal expansion of polymer composites filled with ceramic particles for electronic packaging journal, December 1999

Size-dependence of the dielectric breakdown strength from nano- to millimeter scale journal, February 2014

Solution-Processed Metallic Conducting Polymer Films as Transparent Electrode of Optoelectronic Devices journal, April 2012

Low-temperature fabrication of titanium metal/barium titanate composite capacitors via hydrothermal method and their dielectric properties journal, January 2014

Overview of Fine-Scale Piezoelectric Ceramic/Polymer Composite Processing journal, November 1995

Dielectric materials for applications in microwave communications journal, January 2001

Physical Properties of Composites Near Percolation journal, June 2010

Small-Polaron Hopping Motion in Some Chalcogenide Glasses journal, March 1972

Piezotronically Modified Double Schottky Barriers in ZnO Varistors journal, February 2015

Low temperature hydrothermal sintering process for the quasi-complete densification of nanometric α-quartz journal, March 2018

Low temperature co-fired ceramics with ultra-low sintering temperature: A review journal, June 2016

Grain Growth of ZnO during Bi2O3 Liquid-Phase Sintering journal, September 1992

New prospects in flame retardant polymer materials: From fundamentals to nanocomposites journal, January 2009

Utilizing the Cold Sintering Process for Flexible-Printable Electroceramic Device Fabrication journal, August 2016

Reactive Hydrothermal Liquid-Phase Densification (rHLPD) of Ceramics - A Study of the BaTiO 3 [TiO 2 ] Composite System journal, August 2016

Polymer/layered silicate nanocomposites: a review from preparation to processing journal, November 2003

Microwave dielectric properties of cold sintered Al 2 O 3 -NaCl composite journal, January 2018

Characterization of individual interfacial barriers in a ZnO varistor material journal, October 1989

Hydrothermal Preparation and Sintering of Fine Ceramic Powders journal, January 1983

Composite electroceramics journal, January 1986

The temperature coefficient of capacitance journal, September 1968

Engineered doping of organic semiconductors for enhanced thermoelectric efficiency journal, May 2013

Water-assisted flash sintering: Flashing ZnO at room temperature to achieve ~ 98% density in seconds journal, January 2018

Reoxidation Effects of Ba-Excessive Barium Titanate Ceramics for Laminated Positive Temperature Coefficient Thermistors journal, January 2012

Cold sintering and electrical characterization of lead zirconate titanate piezoelectric ceramics journal, January 2018

Ceramic–Polymer Composites with High Dielectric Constant journal, May 2007

Overview of low temperature co-fired ceramics tape technology for meso-system technology (MsST) journal, April 2001

On the temperature coefficient of resonant frequency in microwave dielectrics journal, February 2001

Current progress and perspectives of applying cold sintering process to ZrO2-based ceramics journal, July 2017

HREM and STEM of intergranular films at zinc oxide varistor grain boundaries journal, September 1998

Intercalated clay nanocomposites: Morphology, mechanics, and fracture behavior journal, January 2001

Microwave dielectric properties of mineral sillimanite obtained by conventional and cold sintering process journal, May 2017

Highly Conductive PEDOT:PSS Electrode with Optimized Solvent and Thermal Post-Treatment for ITO-Free Organic Solar Cells journal, February 2011

The microstructure of a ZnO varistor material journal, November 1985

A review of particulate reinforcement theories for polymer composites journal, December 1990

Cold sintering and co-firing of a multilayer device with thermoelectric materials journal, April 2017

Physical model for breakdown structures in solid dielectrics journal, December 1993

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Impact strength of polymer-clay nanocomposites journal, January 2009

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Unveiling the mechanisms of cold sintering of ZnO at 250 °C by varying applied stress and characterizing grain boundaries by Kelvin Probe Force Microscopy journal, February 2018

Hall-Effect Sign Anomaly and Small-Polaron Conduction in ( La 1 − x Gd x ) 0.67 Ca 0.33 MnO 3 journal, February 1997

The microstructural location of the intergranular metal-oxide phase in a zinc oxide varistor journal, January 1978

Overview on fabrication of three-dimensional structures in multi-layer ceramic substrate journal, August 2010

Equation for the effective permittivity of particle-filled composites for material design applications journal, August 2007

Processing and Dielectric Properties of Sillenite Compounds Bi 12 MO 20−δ (M = Si, Ge, Ti, Pb, Mn, B 1/2 P 1/2 ) journal, December 2001

Dielectric Properties of Lithium Molybdate Ceramic Fabricated at Room Temperature journal, October 2014

Nonohmic Properties of Zinc Oxide Ceramics journal, June 1971

Polymer Properties book, December 2009

Cold-Sintered Temperature Stable Na 0.5 Bi 0.5 MoO 4 –Li 2 MoO 4 Microwave Composite Ceramics journal, December 2017

MATERIALS SCIENCE: Talking Ceramics
journal, November 2002

Polymer nanocomposites
journal, January 2007

The role of viscoelasticity in polymer sintering
journal, June 1998

An Interfacial Complex in ZnO and Its Influence on Charge Transport
journal, October 2003

Polyethylene nanocomposite dielectrics: Implications of nanofiller orientation on high field properties and energy storage
journal, April 2011

Polymer Layered Silicate Nanocomposites
journal, January 1996

Cold Sintering Process: A Novel Technique for Low-Temperature Ceramic Processing of Ferroelectrics
journal, October 2016

Connectivity and piezoelectric-pyroelectric composites
journal, May 1978

Semiconducting properties of cold sintered V2O5 ceramics and Co-sintered V2O5-PEDOT:PSS composites
journal, April 2017

A hydrothermal hot-pressing method: Apparatus and application
journal, March 1986

Recent advances in ZnO materials and devices
journal, March 2001

Polar Nanoregions and Dielectric Properties of BaTiO ₃ -Based Y5V Multilayer Ceramic Capacitors
journal, March 2014

Geologically-inspired strong bulk ceramics made with water at room temperature
journal, March 2017

Methods for predicting the thermal conductivity of composite systems: A review
journal, September 1976

Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions
journal, March 2003

A Statistical Distribution Function of Wide Applicability
journal, September 1951

Cold sintering of a Li-ion cathode: LiFePO4-composite with high volumetric capacity
journal, December 2017

Tape Casting and Dielectric Properties of Zn ₂ Te ₃ O ₈ -Based Ceramics with an Ultra-Low Sintering Temperature
journal, July 2009

Temperature coefficients of capacitance of solids
journal, April 1969

Microwave Dielectric Properties and Low-Temperature Cofiring of BaTe4O9 with Aluminum Metal Electrode
journal, December 2005

Fabrication, characterization, properties and theoretical analysis of ceramic/PVDF composite flexible films with high dielectric constant and low dielectric loss
journal, January 2014

Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics
journal, August 2016

Dielectric characterisation of ceramics from the TiO2–TeO2 system
journal, January 2001

Chemical State Analysis of Grain Boundaries in ZnO Varistors by Auger Electron Spectroscopy
journal, July 1993

Cold sintering approach to fabrication of high rate performance binderless LiFePO4 cathode with high volumetric capacity
journal, March 2018

Thermal conductivity, elastic modulus, and coefficient of thermal expansion of polymer composites filled with ceramic particles for electronic packaging
journal, December 1999

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journal, February 2014

Solution-Processed Metallic Conducting Polymer Films as Transparent Electrode of Optoelectronic Devices
journal, April 2012

Low-temperature fabrication of titanium metal/barium titanate composite capacitors via hydrothermal method and their dielectric properties
journal, January 2014

Overview of Fine-Scale Piezoelectric Ceramic/Polymer Composite Processing
journal, November 1995

Dielectric materials for applications in microwave communications
journal, January 2001

Physical Properties of Composites Near Percolation
journal, June 2010

Small-Polaron Hopping Motion in Some Chalcogenide Glasses
journal, March 1972

Piezotronically Modified Double Schottky Barriers in ZnO Varistors
journal, February 2015

Low temperature hydrothermal sintering process for the quasi-complete densification of nanometric α-quartz
journal, March 2018

Low temperature co-fired ceramics with ultra-low sintering temperature: A review
journal, June 2016

Grain Growth of ZnO during Bi2O3 Liquid-Phase Sintering
journal, September 1992

New prospects in flame retardant polymer materials: From fundamentals to nanocomposites
journal, January 2009

Utilizing the Cold Sintering Process for Flexible-Printable Electroceramic Device Fabrication
journal, August 2016

Reactive Hydrothermal Liquid-Phase Densification (rHLPD) of Ceramics - A Study of the BaTiO ₃ [TiO ₂ ] Composite System
journal, August 2016

Polymer/layered silicate nanocomposites: a review from preparation to processing
journal, November 2003

Microwave dielectric properties of cold sintered Al 2 O 3 -NaCl composite
journal, January 2018

Characterization of individual interfacial barriers in a ZnO varistor material
journal, October 1989

Hydrothermal Preparation and Sintering of Fine Ceramic Powders
journal, January 1983

Composite electroceramics
journal, January 1986

The temperature coefficient of capacitance
journal, September 1968

Engineered doping of organic semiconductors for enhanced thermoelectric efficiency
journal, May 2013

Water-assisted flash sintering: Flashing ZnO at room temperature to achieve ~ 98% density in seconds
journal, January 2018

Reoxidation Effects of Ba-Excessive Barium Titanate Ceramics for Laminated Positive Temperature Coefficient Thermistors
journal, January 2012

Cold sintering and electrical characterization of lead zirconate titanate piezoelectric ceramics
journal, January 2018

Ceramic–Polymer Composites with High Dielectric Constant
journal, May 2007

Overview of low temperature co-fired ceramics tape technology for meso-system technology (MsST)
journal, April 2001

On the temperature coefficient of resonant frequency in microwave dielectrics
journal, February 2001

Current progress and perspectives of applying cold sintering process to ZrO2-based ceramics
journal, July 2017

HREM and STEM of intergranular films at zinc oxide varistor grain boundaries
journal, September 1998

Intercalated clay nanocomposites: Morphology, mechanics, and fracture behavior
journal, January 2001

Microwave dielectric properties of mineral sillimanite obtained by conventional and cold sintering process
journal, May 2017

Highly Conductive PEDOT:PSS Electrode with Optimized Solvent and Thermal Post-Treatment for ITO-Free Organic Solar Cells
journal, February 2011

The microstructure of a ZnO varistor material
journal, November 1985

A review of particulate reinforcement theories for polymer composites
journal, December 1990

Cold sintering and co-firing of a multilayer device with thermoelectric materials
journal, April 2017

Physical model for breakdown structures in solid dielectrics
journal, December 1993

Polymer-Ceramic Composites of 0-3 Connectivity for Circuits in Electronics: A Review
journal, January 2010

Design of 0–3 type nanocomposites using hydrothermal sintering
journal, April 2018

Impact strength of polymer-clay nanocomposites
journal, January 2009

Demonstration of the cold sintering process study for the densification and grain growth of ZnO ceramics
journal, October 2016

Improvements and Modifications to Room-Temperature Fabrication Method for Dielectric Li ₂ MoO ₄ Ceramics
journal, January 2015

Unveiling the mechanisms of cold sintering of ZnO at 250 °C by varying applied stress and characterizing grain boundaries by Kelvin Probe Force Microscopy
journal, February 2018

Hall-Effect Sign Anomaly and Small-Polaron Conduction in $({La}_{1 - x} {Gd}_{x})_{0.67} {Ca}_{0.33} {MnO}_{3}$
journal, February 1997

The microstructural location of the intergranular metal-oxide phase in a zinc oxide varistor
journal, January 1978

Overview on fabrication of three-dimensional structures in multi-layer ceramic substrate
journal, August 2010

Equation for the effective permittivity of particle-filled composites for material design applications
journal, August 2007

Processing and Dielectric Properties of Sillenite Compounds Bi ₁₂ MO _20−δ (M = Si, Ge, Ti, Pb, Mn, B _1/2 P _1/2 )
journal, December 2001

Dielectric Properties of Lithium Molybdate Ceramic Fabricated at Room Temperature
journal, October 2014

Nonohmic Properties of Zinc Oxide Ceramics
journal, June 1971

Polymer Properties
book, December 2009

Cold-Sintered Temperature Stable Na _0.5 Bi _0.5 MoO ₄ –Li ₂ MoO ₄ Microwave Composite Ceramics
journal, December 2017

Electrical Resistivity of Composites
journal, August 1990

Flammability Properties of Polymer−Layered-Silicate Nanocomposites. Polypropylene and Polystyrene Nanocomposites ^†
journal, July 2000

Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials
journal, June 2000