Reversible Surface Patterning by Dynamic Crosslink Gradients: Controlling Buckling in 2D
Abstract
Abstract Harnessing the self‐organization of soft materials to make complex, well‐ordered surface patterns in a noninvasive manner is challenging. The wrinkling of thin films provides a compelling strategy to achieve this. Despite much attention, however, a simple, single‐step, reversible method that gives rise to controlled, two‐dimensional (2D) ordered, continuous, and discontinuous patterns has proven to be elusive. Here a novel, robust method is described to achieve this using an ultraviolet‐light‐sensitive anthracene‐containing polymer thin film. The origin of the patterns is the local buckling of the thin film, where the control over the topology is given by laterally patterning out‐of‐plane gradients in the crosslink density of the film. The underlying buckling mechanics and formation of the surface features are well‐described by finite element analysis. By illuminating the film with a photomask, local and long‐range patterns that can be both continuous and discontinuous are able to be written. Furthermore, the patterning is fully reversible over multiple cycles. The results demonstrate a simple strategy for erasable storage of information in a surface topography that has applications in memory, anticounterfeiting, and plasmonics.
- Authors:
-
- School of Chemistry and Chemical Engineering State Key Laboratory for Metal Matrix Composite Materials Shanghai Jiao Tong University Shanghai 200240 China, Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
- State Key Laboratory of Mechanical Systems and Vibration School of Mechanical Engineering Shanghai Jiao Tong University Shanghai 200240 China
- School of Chemistry and Chemical Engineering State Key Laboratory for Metal Matrix Composite Materials Shanghai Jiao Tong University Shanghai 200240 China
- Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
- Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA, Polymer Science and Engineering Department University of Massachusetts Amherst MA 01003 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1462447
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Name: Advanced Materials Journal Volume: 30 Journal Issue: 36; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Hou, Honghao, Hu, Kaiming, Lin, Hongbo, Forth, Joe, Zhang, Wenming, Russell, Thomas P., Yin, Jie, and Jiang, Xuesong. Reversible Surface Patterning by Dynamic Crosslink Gradients: Controlling Buckling in 2D. Germany: N. p., 2018.
Web. doi:10.1002/adma.201803463.
Hou, Honghao, Hu, Kaiming, Lin, Hongbo, Forth, Joe, Zhang, Wenming, Russell, Thomas P., Yin, Jie, & Jiang, Xuesong. Reversible Surface Patterning by Dynamic Crosslink Gradients: Controlling Buckling in 2D. Germany. https://doi.org/10.1002/adma.201803463
Hou, Honghao, Hu, Kaiming, Lin, Hongbo, Forth, Joe, Zhang, Wenming, Russell, Thomas P., Yin, Jie, and Jiang, Xuesong. Tue .
"Reversible Surface Patterning by Dynamic Crosslink Gradients: Controlling Buckling in 2D". Germany. https://doi.org/10.1002/adma.201803463.
@article{osti_1462447,
title = {Reversible Surface Patterning by Dynamic Crosslink Gradients: Controlling Buckling in 2D},
author = {Hou, Honghao and Hu, Kaiming and Lin, Hongbo and Forth, Joe and Zhang, Wenming and Russell, Thomas P. and Yin, Jie and Jiang, Xuesong},
abstractNote = {Abstract Harnessing the self‐organization of soft materials to make complex, well‐ordered surface patterns in a noninvasive manner is challenging. The wrinkling of thin films provides a compelling strategy to achieve this. Despite much attention, however, a simple, single‐step, reversible method that gives rise to controlled, two‐dimensional (2D) ordered, continuous, and discontinuous patterns has proven to be elusive. Here a novel, robust method is described to achieve this using an ultraviolet‐light‐sensitive anthracene‐containing polymer thin film. The origin of the patterns is the local buckling of the thin film, where the control over the topology is given by laterally patterning out‐of‐plane gradients in the crosslink density of the film. The underlying buckling mechanics and formation of the surface features are well‐described by finite element analysis. By illuminating the film with a photomask, local and long‐range patterns that can be both continuous and discontinuous are able to be written. Furthermore, the patterning is fully reversible over multiple cycles. The results demonstrate a simple strategy for erasable storage of information in a surface topography that has applications in memory, anticounterfeiting, and plasmonics.},
doi = {10.1002/adma.201803463},
journal = {Advanced Materials},
number = 36,
volume = 30,
place = {Germany},
year = {Tue Jul 31 00:00:00 EDT 2018},
month = {Tue Jul 31 00:00:00 EDT 2018}
}
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https://doi.org/10.1002/adma.201803463
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Works referenced in this record:
Deterministic Order in Surface Micro-Topologies through Sequential Wrinkling
journal, August 2012
- Yin, Jie; Yagüe, Jose Luis; Eggenspieler, Damien
- Advanced Materials, Vol. 24, Issue 40
Capillary Wrinkling of Floating Thin Polymer Films
journal, August 2007
- Huang, J.; Juszkiewicz, M.; de Jeu, W. H.
- Science, Vol. 317, Issue 5838
Harnessing Instabilities to Design Tunable Architected Cellular Materials
journal, July 2017
- Bertoldi, Katia
- Annual Review of Materials Research, Vol. 47, Issue 1
Light-reversible hierarchical patterns by dynamic photo-dimerization induced wrinkles
journal, January 2017
- Hou, Honghao; Li, Fudong; Su, Zhilong
- Journal of Materials Chemistry C, Vol. 5, Issue 34
Well-Ordered Wrinkling Patterns on Chemically Oxidized Poly(dimethylsiloxane) Surfaces
journal, August 2012
- Watanabe, Masashi; Mizukami, Koujirou
- Macromolecules, Vol. 45, Issue 17
Tailoring the wrinkle pattern of a microstructured membrane
journal, August 2014
- Yan, Dong; Zhang, Kai; Peng, Fujun
- Applied Physics Letters, Vol. 105, Issue 7
Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer
journal, May 1998
- Whitesides, George M.; Bowden, Ned; Brittain, Scott
- Nature, Vol. 393, Issue 6681, p. 146-149
An ultra-lightweight design for imperceptible plastic electronics
journal, July 2013
- Kaltenbrunner, Martin; Sekitani, Tsuyoshi; Reeder, Jonathan
- Nature, Vol. 499, Issue 7459
Tuning and Erasing Surface Wrinkles by Reversible Visible-Light-Induced Photoisomerization
journal, February 2016
- Zong, Chuanyong; Zhao, Yan; Ji, Haipeng
- Angewandte Chemie International Edition, Vol. 55, Issue 12
Stimuli-responsive buckling mechanics of polymer films
journal, September 2014
- Chen, Dayong; Yoon, Jinhwan; Chandra, Dinesh
- Journal of Polymer Science Part B: Polymer Physics, Vol. 52, Issue 22
Large-Scale Regioselective Formation of Well-Defined Stable Wrinkles of Multilayered Films via Embossing
journal, November 2008
- Lu, Conghua; Möhwald, Helmuth; Fery, Andreas
- Chemistry of Materials, Vol. 20, Issue 22
Self-organization of maze-like structures via guided wrinkling
journal, June 2017
- Bae, Hyung Jong; Bae, Sangwook; Yoon, Jinsik
- Science Advances, Vol. 3, Issue 6
Patterned Polymer Films via Reactive Silane Infusion-Induced Wrinkling
journal, March 2013
- Li, Yinyong; Peterson, Joseph J.; Jhaveri, Sarav B.
- Langmuir, Vol. 29, Issue 14
Mechanical Buckling: Mechanics, Metrology, and Stretchable Electronics
journal, May 2009
- Khang, Dahl-Young; Rogers, John A.; Lee, Hong H.
- Advanced Functional Materials, Vol. 19, Issue 10
Diffusion-Controlled, Self-Organized Growth of Symmetric Wrinkling Patterns
journal, April 2009
- Chung, Jun Young; Nolte, Adam J.; Stafford, Christopher M.
- Advanced Materials, Vol. 21, Issue 13
The smectic order of wrinkles
journal, July 2017
- Aharoni, Hillel; Todorova, Desislava V.; Albarrán, Octavio
- Nature Communications, Vol. 8, Issue 1
Reversible Photochemically Gated Transformation of a Hemicarcerand to a Carcerand
journal, November 2012
- Wang, Hao; Liu, Fang; Helgeson, Roger C.
- Angewandte Chemie International Edition, Vol. 52, Issue 2
Wellenlängengesteuerte dynamische kovalente Chemie
journal, January 2018
- Frisch, Hendrik; Marschner, David E.; Goldmann, Anja S.
- Angewandte Chemie, Vol. 130, Issue 8
Thermochemical Patterning of Polymer Thin Films With Tunable Size-Reduction Effects Using Metal-Coated Poly(dimethylsiloxane) Stamps
journal, June 2009
- Wang, Fangfang; Xue, Mianqi; Cao, Tingbing
- Advanced Materials, Vol. 21, Issue 21
Reversible Diels-Alder Reaction To Control Wrinkle Patterns: From Dynamic Chemistry to Dynamic Patterns
journal, August 2016
- Hou, Honghao; Yin, Jie; Jiang, Xuesong
- Advanced Materials, Vol. 28, Issue 41
Mechanics of stretchable batteries and supercapacitors
journal, June 2015
- Zhang, Yihui; Huang, Yonggang; Rogers, John A.
- Current Opinion in Solid State and Materials Science, Vol. 19, Issue 3
Biomimetic Microfingerprints for Anti-Counterfeiting Strategies
journal, February 2015
- Bae, Hyung Jong; Bae, Sangwook; Park, Cheolheon
- Advanced Materials, Vol. 27, Issue 12
Anisotropic, Hierarchical Surface Patterns via Surface Wrinkling of Nanopatterned Polymer Films
journal, October 2012
- Lee, Jung-Hyun; Ro, Hyun Wook; Huang, Rui
- Nano Letters, Vol. 12, Issue 11
Synthesis of a Covalent Monolayer Sheet by Photochemical Anthracene Dimerization at the Air/Water Interface and its Mechanical Characterization by AFM Indentation
journal, December 2013
- Payamyar, Payam; Kaja, Khaled; Ruiz-Vargas, Carlos
- Advanced Materials, Vol. 26, Issue 13
Surface Wrinkling: A Versatile Platform for Measuring Thin-Film Properties
journal, September 2010
- Chung, Jun Young; Nolte, Adam J.; Stafford, Christopher M.
- Advanced Materials, Vol. 23, Issue 3
Near-infrared light–responsive dynamic wrinkle patterns
journal, April 2018
- Li, Fudong; Hou, Honghao; Yin, Jie
- Science Advances, Vol. 4, Issue 4
Anthracene-Based Thiol–Ene Networks with Thermo-Degradable and Photo-Reversible Properties
journal, February 2017
- Van Damme, Jonas; van den Berg, Otto; Brancart, Joost
- Macromolecules, Vol. 50, Issue 5
Morphable 3D mesostructures and microelectronic devices by multistable buckling mechanics
journal, January 2018
- Fu, Haoran; Nan, Kewang; Bai, Wubin
- Nature Materials, Vol. 17, Issue 3
A Stretchable Form of Single-Crystal Silicon for High-Performance Electronics on Rubber Substrates
journal, January 2006
- Khang, Dahl-Young; Jiang, Hanqing; Huang, Young
- Science, Vol. 311, Issue 5758, p. 208-212
Harnessing Surface Wrinkle Patterns in Soft Matter
journal, July 2010
- Yang, Shu; Khare, Krishnacharya; Lin, Pei-Chun
- Advanced Functional Materials, Vol. 20, Issue 16
Mechanically Gated Electrical Switches by Creasing of Patterned Metal/Elastomer Bilayer Films
journal, April 2014
- Xu, Ben; Chen, Dayong; Hayward, Ryan C.
- Advanced Materials, Vol. 26, Issue 25
Physical Self-Assembly of Microstructures by Anisotropic Buckling
journal, October 2002
- Yoo, P. J.; Suh, K. Y.; Park, S. Y.
- Advanced Materials, Vol. 14, Issue 19
Superhydrophobic Surfaces from Hierarchically Structured Wrinkled Polymers
journal, October 2013
- Li, Yinyong; Dai, Shuxi; John, Jacob
- ACS Applied Materials & Interfaces, Vol. 5, Issue 21
Ordering and Printing Virus Arrays: A Straightforward Way to Functionalize Surfaces
journal, September 2010
- Horn, Anne; Hiltl, Stephanie; Fery, Andreas
- Small, Vol. 6, Issue 19
Photoinduced Formation of Wrinkled Microstructures with Long-Range Order in Thin Oxide Films
journal, December 2007
- Takahashi, M.; Maeda, T.; Uemura, K.
- Advanced Materials, Vol. 19, Issue 24
Evaporation-Induced Self-Alignment and Transfer of Semiconductor Nanowires by Wrinkled Elastomeric Templates
journal, January 2013
- Lee, Seung Goo; Kim, Haena; Choi, Hyun Ho
- Advanced Materials, Vol. 25, Issue 15
Wrinkled interfaces: Taking advantage of surface instabilities to pattern polymer surfaces
journal, March 2015
- Rodríguez-Hernández, Juan
- Progress in Polymer Science, Vol. 42
Photodirected Formation and Control of Wrinkles on a Thiol–ene Elastomer
journal, May 2013
- Ma, Stephen J.; Mannino, Samantha J.; Wagner, Norman J.
- ACS Macro Letters, Vol. 2, Issue 6
Dynamic Covalent Bond Based on Reversible Photo [4 + 4] Cycloaddition of Anthracene for Construction of Double-Dynamic Polymers
journal, November 2013
- Xu, Jiang-Fei; Chen, Yu-Zhe; Wu, Li-Zhu
- Organic Letters, Vol. 15, Issue 24
Geometry and Physics of Wrinkling
journal, February 2003
- Cerda, E.; Mahadevan, L.
- Physical Review Letters, Vol. 90, Issue 7
Transferred wrinkled Al2O3 for highly stretchable and transparent graphene–carbon nanotube transistors
journal, March 2013
- Chae, Sang Hoon; Yu, Woo Jong; Bae, Jung Jun
- Nature Materials, Vol. 12, Issue 5
Photodimerization of anthracenes in fluid solutions: (part 2) mechanistic aspects of the photocycloaddition and of the photochemical and thermal cleavage
journal, January 2001
- Bouas-Laurent, Henri; Desvergne, Jean-Pierre; Castellan, Alain
- Chemical Society Reviews, Vol. 30, Issue 4
Grayscale Photopatterning of an Amorphous Polymer Thin Film Prepared by Photopolymerization of a Bisanthracene-Functionalized Liquid-Crystalline Monomer
journal, May 2010
- Kihara, Hideyuki; Motohashi, Masashi; Matsumura, Kazunari
- Advanced Functional Materials, Vol. 20, Issue 10
Harnessing Localized Ridges for High-Aspect-Ratio Hierarchical Patterns with Dynamic Tunability and Multifunctionality
journal, December 2013
- Cao, Changyong; Chan, Hon Fai; Zang, Jianfeng
- Advanced Materials, Vol. 26, Issue 11