Shock-induced amorphization in silicon carbide
- Univ. of California, San Diego, CA (United States); The Regents of the Univ. of Calif.,U.C. San Diego
- Univ. of California, San Diego, CA (United States)
- Univ. of California, San Diego, CA (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
While silicon carbide (SiC) has been predicted to undergo pressure-induced amorphization, the microstructural evidence of such a drastic phase change is absent as its brittleness usually prevents its successful recovery from high-pressure experiments. In this paper we report on the observation of amorphous SiC recovered from laser-ablation-driven shock compression with a peak stress of approximately 50 GPa. Transmission electron microscopy reveals that the amorphous regions are extremely localized, forming bands as narrow as a few nanometers. In addition to these amorphous bands, planar stacking faults are observed. Large-scale non-equilibrium molecular dynamic simulations elucidate the process and suggest that the planar stacking faults serve as the precursors to amorphization. Finally, our results suggest that the amorphous phase produced is a high-density form, which enhances its thermodynamical stability under the high pressures combined with the shear stresses generated by the uniaxial strain state in shock compression.
- Research Organization:
- Univ. of California, San Diego, CA (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Univ. of California (United States)
- Grant/Contract Number:
- NA0002930; FG52-09NA29043; AC52-07NA27344
- OSTI ID:
- 1462276
- Journal Information:
- Acta Materialia, Journal Name: Acta Materialia Vol. 158; ISSN 1359-6454
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Plasticity without dislocations in a polycrystalline intermetallic
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journal | August 2019 |
Plasticity without dislocations in a polycrystalline intermetallic
|
journal | August 2019 |
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