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Title: Role of water-rock interaction in the geochemical evolution of Marcellus Shale produced waters

Journal Article · · International Journal of Coal Geology
ORCiD logo [1];  [2];  [3]
  1. National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Univ. of Pittsburgh, PA (United States). Dept. of Geology and Environmental Science; Univ. of Waterloo, ON (Canada). Dept. of Earth and Environmental Sciences
  2. National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); California State Univ. (CalState), Sacramento, CA (United States). Geology Dept.
  3. National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

Gaining knowledge of geochemical processes that occur during hydraulic fracturing of shale resources for natural gas recovery can provide insight into in situ mineral precipitation and dissolution reactions that affect shale pore and fracture networks, and ultimately the ability to recover natural gas. Measurement of dissolved chemical species in produced waters, which serve as indicators of water-rock reactions in the reservoir, is one approach for monitoring subsurface geochemistry. However, an ability to distinguish effects of water-rock reactions versus reservoir fluid mixing on chemical concentration and speciation in produced waters requires experimental investigation to better understand natural geochemical tracer behavior.

Research Organization:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States); Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy and Carbon Management (FECM)
Contributing Organization:
AECOM, Los Angeles, CA (United States)
OSTI ID:
1461833
Alternate ID(s):
OSTI ID: 1548680
Report Number(s):
NETL-PUB-21099; PII: S0166516217306638
Journal Information:
International Journal of Coal Geology, Vol. 191, Issue C; ISSN 0166-5162
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 50 works
Citation information provided by
Web of Science

References (56)

Organic and inorganic composition and microbiology of produced waters from Pennsylvania shale gas wells journal September 2015
A model describing flowback chemistry changes with time after Marcellus Shale hydraulic fracturing journal January 2015
Water resource impacts during unconventional shale gas development: The Pennsylvania experience journal June 2014
Impact of matrix effects on the accurate measurement of Li isotope ratios by inductively coupled plasma mass spectrometry (MC-ICP-MS) under “cold” plasma conditions journal January 2003
The strontium isotopic evolution of Marcellus Formation produced waters, southwestern Pennsylvania journal June 2014
Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction journal March 2012
Reservoir Modeling in Shale-Gas Reservoirs journal August 2010
Characterization of Marcellus Shale and Huntersville Chert before and after exposure to hydraulic fracturing fluid via feature relocation using field-emission scanning electron microscopy journal October 2016
Determination of the Formation Constants of Ternary Complexes of Uranyl and Carbonate with Alkaline Earth Metals (Mg 2+ , Ca 2+ , Sr 2+ , and Ba 2+ ) Using Anion Exchange Method journal August 2006
Experimental study of K-feldspar dissolution rates as a function of chemical affinity at 150°C and pH 9 journal November 1994
1994 Compilation of Working Values and Sample Description for 383 Geostandards journal July 1994
Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA journal January 2013
Element release and reaction-induced porosity alteration during shale-hydraulic fracturing fluid interactions journal July 2017
A reactive transport model for Marcellus shale weathering journal November 2017
Kinetic modelling of CO2–water–rock interactions journal July 2013
Adsorption of uranyl onto ferric oxyhydroxides: Application of the surface complexation site-binding model journal September 1985
Impact of Organics and Carbonates on the Oxidation and Precipitation of Iron during Hydraulic Fracturing of Shale journal March 2017
Evolution of porosity and geochemistry in Marcellus Formation black shale during weathering journal October 2013
Evidence of a Stable Uranyl Site in Ancient Organic-Rich Calcite journal April 2006
Strontium Isotopes Test Long-Term Zonal Isolation of Injected and Marcellus Formation Water after Hydraulic Fracturing journal July 2014
Hydraulic fracturing chemicals reporting: Analysis of available data and recommendations for policymakers journal January 2016
Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits journal June 1978
Chemical kinetics of water-rock interactions journal June 1984
A critical evaluation of unconventional gas recovery from the marcellus shale, northeastern United States journal April 2011
Carbon and sulfur relationships in Devonian shales from the Appalachian Basin as an indicator of environment of deposition journal January 1987
Accurate determination of lithium isotope ratios by MC-ICP-MS without strict matrix-matching by using a novel washing method journal January 2016
Temperature-dependent Li isotope ratios in Appalachian Plateau and Gulf Coast Sedimentary Basin saline water journal July 2014
Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale journal January 2017
Precise determination of δ 88 Sr in rocks, minerals, and waters by double-spike TIMS: a powerful tool in the study of geological, hydrological and biological processes journal January 2014
Rare earth element geochemistry of outcrop and core samples from the Marcellus Shale journal June 2015
Mineral Reactions in Shale Gas Reservoirs: Barite Scale Formation from Reusing Produced Water As Hydraulic Fracturing Fluid journal July 2017
Experimental and predicted geochemical shale-water reactions: Roseneath and Murteree shales of the Cooper Basin journal February 2018
Alteration of uraninite from the Nopal I deposit, Pen˜a Blanca District, Chihuahua, Mexico, compared to degradation of spent nuclear fuel in the proposed U.S. high-level nuclear waste repository at Yucca Mountain, Nevada journal November 1994
A field study of the chemical weathering of ancient sedimentary organic matter journal May 2000
Trace metal distribution and mobility in drill cuttings and produced waters from Marcellus Shale gas extraction: Uranium, arsenic, barium journal September 2015
Factors controlling Li concentration and isotopic composition in formation waters and host rocks of Marcellus Shale, Appalachian Basin journal January 2016
Geochemical and multi-isotopic (87Sr/86Sr, 143Nd/144Nd, 238U/235U) perspectives of sediment sources, depositional conditions, and diagenesis of the Marcellus Shale, Appalachian Basin, USA journal February 2018
Calcite, dolomite and magnesite dissolution kinetics in aqueous solutions at acid to circumneutral pH, 25 to 150 °C and 1 to 55 atm pCO2: New constraints on CO2 sequestration in sedimentary basins journal July 2009
Reductive weathering of black shale and release of barium during hydraulic fracturing journal February 2016
The kinetics of silica-water reactions journal November 1980
Geochemical and isotopic evolution of water produced from Middle Devonian Marcellus shale gas wells, Appalachian basin, Pennsylvania journal February 2015
An approach for assessing engineering risk from shale gas wells in the United States journal June 2014
Origin of brines, salts and carbonate from shales of the Marcellus Formation: Evidence from geochemical and Sr isotope study of sequentially extracted fluids journal September 2015
Tetravalent Uranium in Calcite journal August 1998
Nanometre-size products of uranium bioreduction journal September 2002
The structure of uranium (VI) sorption complexes on silica, alumina, and montmorillonite journal July 2000
Metal Associations in Marcellus Shale and Fate of Synthetic Hydraulic Fracturing Fluids Reacted at High Pressure and Temperature journal October 2016
Kinetics of corrosion and dissolution of uranium dioxide as a function of pH journal January 1997
Comparative dissolution kinetics of biogenic and chemogenic uraninite under oxidizing conditions in the presence of carbonate journal October 2009
Uranium Reduction journal October 2006
High throughput method for Sr extraction from variable matrix waters and 87Sr/86Sr isotope analysis by MC-ICP-MS journal January 2013
Methodology of organic-rich shale lithofacies identification and prediction: A case study from Marcellus Shale in the Appalachian basin journal December 2012
Geochemistry and depositional history of the Union Springs Member, Marcellus Formation in central Pennsylvania journal August 2015
Induced mobility of inorganic and organic solutes from black shales using water extraction: Implications for shale gas exploitation journal December 2015
Characterization and development of subsurface fractures observed in the Marcellus Formation, Appalachian Plateau, north-central Pennsylvania journal November 2014
TOUGHREACT—A simulation program for non-isothermal multiphase reactive geochemical transport in variably saturated geologic media: Applications to geothermal injectivity and CO2 geological sequestration journal March 2006

Cited By (4)

Effect of maturity and mineralogy on fluid-rock reactions in the Marcellus Shale journal January 2019
Effect of Dry-Wet Cycling on the Mechanical Properties of Rocks: A Laboratory-Scale Experimental Study journal October 2018
The origin of high hydrocarbon groundwater in shallow aquifer: experimental evidences from water-rock interaction journal October 2019
The Effect of Temperature on Flowback Data Analysis in Shale Gas Reservoirs: A Simulation-Based Study journal September 2019

Figures / Tables (4)