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Title: Hierarchically Controlled Inside-Out Doping of Mg Nanocomposites for Moderate Temperature Hydrogen Storage

Abstract

Abstract not provided.

Authors:
 [1];  [2];  [3];  [4];  [4];  [5];  [6];  [3];  [6];  [7];  [4];  [3];  [4];  [2]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry; Korea Advanced Inst. of Science and Technology (KAIST), Daejeon (Republic of Korea). Dept. of Chemical and Biomolecular Engineering
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
  3. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Materials Science Division
  4. Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry; Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  7. Korea Advanced Inst. of Science and Technology (KAIST), Daejeon (Republic of Korea). Dept. of Chemical and Biomolecular Engineering
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office; Ministry Of Science And Technology, Dept. of Science and Technology (DST) (India)
Contributing Org.:
Bay Area Photovoltaic Consortium (BAPVC); Partnership to Advance Clean Energy Research (PACE-R)
OSTI Identifier:
1461741
Alternate Identifier(s):
OSTI ID: 1402521; OSTI ID: 1474048
Report Number(s):
LLNL-JRNL-722239; SAND2018-10164J
Journal ID: ISSN 1616-301X; 861906
Grant/Contract Number:  
AC52-07NA27344; AC02‐05CH11231; EE0004946; AC36‐08GO28308; IUSSTF/JCERDC‐SERIIUS/2012; AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Volume: 27; Journal Issue: 47; Journal ID: ISSN 1616-301X
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 08 HYDROGEN; dual doping; fuel cell electric vehicle (FCEV); hydrogen storage; magnesium

Citation Formats

Cho, Eun Seon, Ruminski, Anne M., Liu, Yi -Sheng, Shea, Patrick T., Kang, Shin Young, Zaia, Edmond W., Park, Jae Yeol, Chuang, Yi -De, Yuk, Jong Min, Zhou, Xiaowang, Heo, Tae Wook, Guo, Jinghua, Wood, Brandon C., and Urban, Jeffrey J. Hierarchically Controlled Inside-Out Doping of Mg Nanocomposites for Moderate Temperature Hydrogen Storage. United States: N. p., 2017. Web. doi:10.1002/adfm.201704316.
Cho, Eun Seon, Ruminski, Anne M., Liu, Yi -Sheng, Shea, Patrick T., Kang, Shin Young, Zaia, Edmond W., Park, Jae Yeol, Chuang, Yi -De, Yuk, Jong Min, Zhou, Xiaowang, Heo, Tae Wook, Guo, Jinghua, Wood, Brandon C., & Urban, Jeffrey J. Hierarchically Controlled Inside-Out Doping of Mg Nanocomposites for Moderate Temperature Hydrogen Storage. United States. doi:https://doi.org/10.1002/adfm.201704316
Cho, Eun Seon, Ruminski, Anne M., Liu, Yi -Sheng, Shea, Patrick T., Kang, Shin Young, Zaia, Edmond W., Park, Jae Yeol, Chuang, Yi -De, Yuk, Jong Min, Zhou, Xiaowang, Heo, Tae Wook, Guo, Jinghua, Wood, Brandon C., and Urban, Jeffrey J. Tue . "Hierarchically Controlled Inside-Out Doping of Mg Nanocomposites for Moderate Temperature Hydrogen Storage". United States. doi:https://doi.org/10.1002/adfm.201704316. https://www.osti.gov/servlets/purl/1461741.
@article{osti_1461741,
title = {Hierarchically Controlled Inside-Out Doping of Mg Nanocomposites for Moderate Temperature Hydrogen Storage},
author = {Cho, Eun Seon and Ruminski, Anne M. and Liu, Yi -Sheng and Shea, Patrick T. and Kang, Shin Young and Zaia, Edmond W. and Park, Jae Yeol and Chuang, Yi -De and Yuk, Jong Min and Zhou, Xiaowang and Heo, Tae Wook and Guo, Jinghua and Wood, Brandon C. and Urban, Jeffrey J.},
abstractNote = {Abstract not provided.},
doi = {10.1002/adfm.201704316},
journal = {Advanced Functional Materials},
number = 47,
volume = 27,
place = {United States},
year = {2017},
month = {10}
}

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Cited by: 8 works
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Works referenced in this record:

Metal hydride materials for solid hydrogen storage: A review☆
journal, June 2007


Size-Dependent Hydrogen Storage Properties of Mg Nanocrystals Prepared from Solution
journal, July 2011

  • Norberg, Nick S.; Arthur, Timothy S.; Fredrick, Sarah J.
  • Journal of the American Chemical Society, Vol. 133, Issue 28
  • DOI: 10.1021/ja201791y

Hydrogen diffusion in Mg–H and Mg–Ni–H alloys
journal, July 2008


Understanding the Role of Few-Layer Graphene Nanosheets in Enhancing the Hydrogen Sorption Kinetics of Magnesium Hydride
journal, June 2014

  • Liu, Guang; Wang, Yijing; Jiao, Lifang
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 14
  • DOI: 10.1021/am502755s

First-Principle Study of Adsorption of Hydrogen on Ti-Doped Mg(0001) Surface
journal, November 2006

  • Du, A. J.; Smith, Sean C.; Yao, X. D.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 43
  • DOI: 10.1021/jp063286o

Mechanically alloyed metal hydride systems
journal, February 2001

  • Huot, J.; Liang, G.; Schulz, R.
  • Applied Physics A Materials Science & Processing, Vol. 72, Issue 2
  • DOI: 10.1007/s003390100772

An experimental study of the interaction of hydrogen with the Mg(0001) surface
journal, December 1991


Hydrogen storage in Mg: A most promising material
journal, May 2010


Understanding the Origin of Li 2 MnO 3 Activation in Li-Rich Cathode Materials for Lithium-Ion Batteries
journal, November 2015

  • Ye, Delai; Zeng, Guang; Nogita, Kazuhiro
  • Advanced Functional Materials, Vol. 25, Issue 48
  • DOI: 10.1002/adfm.201503276

The impact of carbon materials on the hydrogen storage properties of light metal hydrides
journal, January 2011

  • Adelhelm, Philipp; de Jongh, Petra E.
  • J. Mater. Chem., Vol. 21, Issue 8
  • DOI: 10.1039/C0JM02593C

The current status of hydrogen storage in metal–organic frameworks
journal, January 2008

  • Zhao, Dan; Yuan, Daqiang; Zhou, Hong-Cai
  • Energy & Environmental Science, Vol. 1, Issue 2
  • DOI: 10.1039/b808322n

Stable Hydrogen Storage Cycling in Magnesium Hydride, in the Range of Room Temperature to 300 °C, Achieved Using a New Bimetallic Cr-V Nanoscale Catalyst
journal, January 2012

  • Zahiri, Beniamin; Danaie, Mohsen; Tan, XueHai
  • The Journal of Physical Chemistry C, Vol. 116, Issue 4
  • DOI: 10.1021/jp211254k

Ultrathin, Molecular-Sieving Graphene Oxide Membranes for Selective Hydrogen Separation
journal, October 2013


Hydrogen vehicles: Fuel of the future?
journal, April 2010


Hydrogen sorption properties of magnesium particles decorated with metallic nanoparticles as catalyst
journal, May 2009


Monodisperse Magnesium Hydride Nanoparticles Uniformly Self-Assembled on Graphene
journal, August 2015

  • Xia, Guanglin; Tan, Yingbin; Chen, Xiaowei
  • Advanced Materials, Vol. 27, Issue 39
  • DOI: 10.1002/adma.201502005

Hydrogen Storage Properties of a Mg–Ni Nanocomposite Coprecipitated from Solution
journal, July 2014

  • Liu, Yana; Zou, Jianxin; Zeng, Xiaoqin
  • The Journal of Physical Chemistry C, Vol. 118, Issue 32
  • DOI: 10.1021/jp504918x

Metallic and Carbon Nanotube-Catalyzed Coupling of Hydrogenation in Magnesium
journal, December 2007

  • Yao, Xiangdong; Wu, Chengzhang; Du, Aijun
  • Journal of the American Chemical Society, Vol. 129, Issue 50
  • DOI: 10.1021/ja0751431

Synergistic enhancement of hydrogen storage and air stability via Mg nanocrystal–polymer interfacial interactions
journal, January 2013

  • Ruminski, Anne M.; Bardhan, Rizia; Brand, Alyssa
  • Energy & Environmental Science, Vol. 6, Issue 11
  • DOI: 10.1039/c3ee41977k

Catalytic Effect of Nanoparticle 3d-Transition Metals on Hydrogen Storage Properties in Magnesium Hydride MgH 2 Prepared by Mechanical Milling
journal, April 2005

  • Hanada, Nobuko; Ichikawa, Takayuki; Fujii, Hironobu
  • The Journal of Physical Chemistry B, Vol. 109, Issue 15
  • DOI: 10.1021/jp044576c

Nanoconfined light metal hydrides for reversible hydrogen storage
journal, June 2013

  • de Jongh, Petra E.; Allendorf, Mark; Vajo, John J.
  • MRS Bulletin, Vol. 38, Issue 6
  • DOI: 10.1557/mrs.2013.108

Misfit-energy-increasing dislocations in vapor-deposited CoFe/NiFe multilayers
journal, April 2004


Defect formation dynamics during CdTe overlayer growth
journal, June 2012


Emerging concepts in solid-state hydrogen storage: the role of nanomaterials design
journal, January 2012

  • Reardon, Hazel; Hanlon, James M.; Hughes, Robert W.
  • Energy & Environmental Science, Vol. 5, Issue 3
  • DOI: 10.1039/c2ee03138h

Hydrogen futures: toward a sustainable energy system
journal, March 2002


Hydrogen-storage materials for mobile applications
journal, November 2001

  • Schlapbach, Louis; Züttel, Andreas
  • Nature, Vol. 414, Issue 6861
  • DOI: 10.1038/35104634

Nanotechnology in Mg-based materials for hydrogen storage
journal, July 2012


Rate determining step in the absorption and desorption of hydrogen by magnesium
journal, June 2002


Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts
journal, March 2011

  • Jeon, Ki-Joon; Moon, Hoi Ri; Ruminski, Anne M.
  • Nature Materials, Vol. 10, Issue 4
  • DOI: 10.1038/nmat2978

Synthesis of porous Ni@rGO nanocomposite and its synergetic effect on hydrogen sorption properties of MgH2
journal, January 2012

  • Liu, Guang; Wang, Yijing; Qiu, Fangyuan
  • Journal of Materials Chemistry, Vol. 22, Issue 42
  • DOI: 10.1039/c2jm34730j

Phase, microstructure and hydrogen storage properties of Mg–Ni materials synthesized from metal nanoparticles
journal, February 2014


H 2 Desorption from MgH 2 Surfaces with Steps and Catalyst-Dopants
journal, March 2014

  • Reich, J. M.; Wang, Lin-Lin; Johnson, Duane D.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 13
  • DOI: 10.1021/jp412826u

Magnesium nanoparticles with transition metal decoration for hydrogen storage
journal, July 2011

  • Pasquini, Luca; Callini, Elsa; Brighi, Matteo
  • Journal of Nanoparticle Research, Vol. 13, Issue 11
  • DOI: 10.1007/s11051-011-0509-6

Atomic scale structure of sputtered metal multilayers
journal, November 2001


Perspectives of in situ/operando resonant inelastic X-ray scattering in catalytic energy materials science
journal, April 2015

  • Liu, Yi-Sheng; Glans, Per-Anders; Chuang, Cheng-Hao
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 200
  • DOI: 10.1016/j.elspec.2015.07.004

Hydrogen storage properties of magnesium ultrafine particles prepared by hydrogen plasma-metal reaction
journal, July 2004


Catalytic Effects of Subsurface Carbon in the Chemisorption of Hydrogen on a Mg(0001) Surface:  an Ab-initio Study
journal, February 2006

  • Du, A. J.; Smith, Sean C.; Yao, X. D.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 4
  • DOI: 10.1021/jp055972d

Activated carbons derived from coconut shells as high energy density cathode material for Li-ion capacitors
journal, October 2013

  • Jain, Akshay; Aravindan, Vanchiappan; Jayaraman, Sundaramurthy
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep03002

Robust Locally Weighted Regression and Smoothing Scatterplots
journal, December 1979


Graphene oxide/metal nanocrystal multilaminates as the atomic limit for safe and selective hydrogen storage
journal, February 2016

  • Cho, Eun Seon; Ruminski, Anne M.; Aloni, Shaul
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10804

Hydrogen dissociation and diffusion on transition metal (=Ti, Zr, V, Fe, Ru, Co, Rh, Ni, Pd, Cu, Ag)-doped Mg(0001) surfaces
journal, February 2009


Thermodynamic Changes in Mechanochemically Synthesized Magnesium Hydride Nanoparticles
journal, April 2010

  • Paskevicius, Mark; Sheppard, Drew A.; Buckley, Craig E.
  • Journal of the American Chemical Society, Vol. 132, Issue 14
  • DOI: 10.1021/ja908398u

    Works referencing / citing this record:

    An Analytical Bond Order Potential for Mg−H Systems
    journal, January 2019


    In‐Situ/Operando X‐ray Characterization of Metal Hydrides
    journal, March 2019


    Improved Hydrogen Absorption/Desorption Properties of MgH 2 by Co–Catalyzing of YH 2 and Co@C
    journal, July 2019


    Microtopography‐Guided Radial Gradient Circle Array Film with Nanoscale Resolution
    journal, October 2019


    Recent advances on the thermal destabilization of Mg-based hydrogen storage materials
    journal, January 2019

    • Zhang, Jianfeng; Li, Zhinian; Wu, Yuanfang
    • RSC Advances, Vol. 9, Issue 1
    • DOI: 10.1039/c8ra05596c

    The effect of co-adsorbed solvent molecules on H 2 binding to metal alkoxides
    journal, January 2019

    • Colón, Yamil J.; Snurr, Randall Q.
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 18
    • DOI: 10.1039/c9cp00754g

    Catalysis and Downsizing in Mg-Based Hydrogen Storage Materials
    journal, February 2018