Cross-plane coherent acoustic phonons in two-dimensional organic-inorganic hybrid perovskites

Guo, Peijun; Stoumpos, Constantinos C.; Mao, Lingling; Sadasivam, Sridhar; Ketterson, John B.; Darancet, Pierre; Kanatzidis, Mercouri G.; Schaller, Richard D.

doi:10.1038/s41467-018-04429-9

Title: Cross-plane coherent acoustic phonons in two-dimensional organic-inorganic hybrid perovskites

Journal Article · 22 May 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-04429-9 · OSTI ID:1461512

Guo, Peijun ^[1];

^[2]; Mao, Lingling ^[2]; Sadasivam, Sridhar ^[1]; Ketterson, John B. ^[2]; Darancet, Pierre ^[1]; Kanatzidis, Mercouri G. ^[2]; Schaller, Richard D. ^[3]

Argonne National Lab. (ANL), Lemont, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Northwestern Univ., Evanston, IL (United States)

Two-dimensional, Ruddlesden-Popper organic-inorganic hybrid layered perovskites (2D-RPs) are solution-grown semiconductors with prospective applications in next-generation optoelectronics. The heat-carrying, low-energy acoustic vibrations of 2D-RPs, which are important for heat management of 2D-RP-based devices, have remained unexplored. Here we report on the propagation of coherent longitudinal acoustic phonons along the cross-plane direction of 2D-RPs, following separate characterizations of below-bandgap refractive index for each 2D-RP. Through experiments on crystals of systematically varied perovskite layer thickness, we demonstrate significant reduction in both group velocity and propagation length of acoustic phonons in 2D-RPs as compared to the three-dimensional methylammonium lead iodide. As borne out by a minimal coarse-grained model, these vibrational properties arise from a large acoustic impedance mismatch between the alternating layers of perovskite sheets and bulky organic cations. Furthermore, our results inform on thermal transport in highly impedance-mismatched crystal sub-lattices and provide insights towards design of materials that exhibit highly anisotropic thermal dissipation properties.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1461512

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 52 works

Citation information provided by
Web of Science

References (97)

Local Polar Fluctuations in Lead Halide Perovskite Crystals Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z. Physical Review Letters, Vol. 118, Issue 13 https://doi.org/10.1103/PhysRevLett.118.136001	journal	March 2017
Effect of reduced dimensionality on the optical band gap of SrTiO ₃ Lee, Che-Hui; Podraza, Nikolas J.; Zhu, Ye Applied Physics Letters, Vol. 102, Issue 12 https://doi.org/10.1063/1.4798241	journal	March 2013
Ultralow Self-Doping in Two-dimensional Hybrid Perovskite Single Crystals Peng, Wei; Yin, Jun; Ho, Kang-Ting Nano Letters, Vol. 17, Issue 8 https://doi.org/10.1021/acs.nanolett.7b01475	journal	June 2017
Ultralow Thermal Conductivity in Disordered, Layered WSe₂ Crystals Chiritescu, C.; Cahill, D. G.; Nguyen, N. Science, Vol. 315, Issue 5810, p. 351-353 https://doi.org/10.1126/science.1136494	journal	January 2007
Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies Guo, Peijun; Xia, Yi; Gong, Jue ACS Energy Letters, Vol. 2, Issue 10 https://doi.org/10.1021/acsenergylett.7b00790	journal	September 2017
Phonon wave interference and thermal bandgap materials Maldovan, Martin Nature Materials, Vol. 14, Issue 7 https://doi.org/10.1038/nmat4308	journal	June 2015
Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide Whitfield, P. S.; Herron, N.; Guise, W. E. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep35685	journal	October 2016
Elastic Constants, Optical Phonons, and Molecular Relaxations in the High Temperature Plastic Phase of the CH ₃ NH ₃ PbBr ₃ Hybrid Perovskite Létoublon, Antoine; Paofai, Serge; Rufflé, Benoît The Journal of Physical Chemistry Letters, Vol. 7, Issue 19 https://doi.org/10.1021/acs.jpclett.6b01709	journal	September 2016
Metal halide perovskites for energy applications Zhang, Wei; Eperon, Giles E.; Snaith, Henry J. Nature Energy, Vol. 1, Issue 6 https://doi.org/10.1038/nenergy.2016.48	journal	May 2016
Heat Capacities, Speeds of Sound, and Isothermal Compressibilities of Some n -Amines and Tri- n -amines at 298.15 K Góralski, P.; Wasiak, M.; Bald, A. Journal of Chemical & Engineering Data, Vol. 47, Issue 1 https://doi.org/10.1021/je010206v	journal	January 2002
Elastic Moduli of Organic Electronic Materials by the Buckling Method Tahk, Dongha; Lee, Hong H.; Khang, Dahl-Young Macromolecules, Vol. 42, Issue 18 https://doi.org/10.1021/ma900137k	journal	September 2009
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology Love, J. Christopher; Estroff, Lara A.; Kriebel, Jennah K. Chemical Reviews, Vol. 105, Issue 4 https://doi.org/10.1021/cr0300789	journal	April 2005
Atomically thin two-dimensional organic-inorganic hybrid perovskites Dou, L.; Wong, A. B.; Yu, Y. Science, Vol. 349, Issue 6255 https://doi.org/10.1126/science.aac7660	journal	September 2015
Bright light-emitting diodes based on organometal halide perovskite Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.149	journal	August 2014
Phonon Speed, Not Scattering, Differentiates Thermal Transport in Lead Halide Perovskites Elbaz, Giselle A.; Ong, Wee-Liat; Doud, Evan A. Nano Letters, Vol. 17, Issue 9 https://doi.org/10.1021/acs.nanolett.7b02696	journal	August 2017
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Exceptional elastic anisotropy of hybrid organic-inorganic perovskite CH ₃ NH ₃ PbBr ₃ measured by laser ultrasonic technique Lomonosov, Alexey M.; Yan, Xiaoliang; Sheng, Chuanxiang physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8 https://doi.org/10.1002/pssr.201600156	journal	July 2016
Thermal properties of AlAs/GaAs superlattices Yao, Takafumi Applied Physics Letters, Vol. 51, Issue 22 https://doi.org/10.1063/1.98526	journal	November 1987
Screening in crystalline liquids protects energetic carriers in hybrid perovskites Zhu, H.; Miyata, K.; Fu, Y. Science, Vol. 353, Issue 6306 https://doi.org/10.1126/science.aaf9570	journal	September 2016
Phonon Dynamics at Surfaces and Interfaces and Its Implications in Energy Transport in Nanostructured Materials—An opinion Paper Li, Deyu; McGaughey, Alan J. H. Nanoscale and Microscale Thermophysical Engineering, Vol. 19, Issue 2 https://doi.org/10.1080/15567265.2015.1035199	journal	April 2015
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Science, Vol. 286, Issue 5441, p. 945-947 https://doi.org/10.1126/science.286.5441.945	journal	October 1999
Surface generation and detection of phonons by picosecond light pulses Thomsen, C.; Grahn, H. T.; Maris, H. J. Physical Review B, Vol. 34, Issue 6 https://doi.org/10.1103/PhysRevB.34.4129	journal	September 1986
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01312	journal	March 2017
Orientational order controls crystalline and amorphous thermal transport in superatomic crystals Ong, Wee-Liat; O’Brien, Evan S.; Dougherty, Patrick S. M. Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4739	journal	September 2016
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe Nature, Vol. 536, Issue 7616 https://doi.org/10.1038/nature18306	journal	July 2016
Electron–Phonon Scattering in Atomically Thin 2D Perovskites Guo, Zhi; Wu, Xiaoxi; Zhu, Tong ACS Nano, Vol. 10, Issue 11 https://doi.org/10.1021/acsnano.6b04265	journal	October 2016
Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites Blancon, J. -C.; Tsai, H.; Nie, W. Science, Vol. 355, Issue 6331 https://doi.org/10.1126/science.aal4211	journal	March 2017
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites Hu, Te; Smith, Matthew D.; Dohner, Emma R. The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00793	journal	May 2016
Surface chemistry mediates thermal transport in three-dimensional nanocrystal arrays Ong, Wee-Liat; Rupich, Sara M.; Talapin, Dmitri V. Nature Materials, Vol. 12, Issue 5 https://doi.org/10.1038/nmat3596	journal	March 2013
Direct–indirect character of the bandgap in methylammonium lead iodide perovskite Hutter, Eline M.; Gélvez-Rueda, María C.; Osherov, Anna Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4765	journal	October 2016
Coherent Phonon Heat Conduction in Superlattices Luckyanova, M. N.; Garg, J.; Esfarjani, K. Science, Vol. 338, Issue 6109 https://doi.org/10.1126/science.1225549	journal	November 2012
Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons Mante, Pierre-Adrien; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14398	journal	February 2017
Thermal conductivity of Si–Ge superlattices Lee, S. -M.; Cahill, David G.; Venkatasubramanian, Rama Applied Physics Letters, Vol. 70, Issue 22 https://doi.org/10.1063/1.118755	journal	June 1997
Van der Waals heterostructures Geim, A. K.; Grigorieva, I. V. Nature, Vol. 499, Issue 7459, p. 419-425 https://doi.org/10.1038/nature12385	journal	July 2013
Three- and low-dimensional inorganic semiconductors Papavassiliou, G. C. Progress in Solid State Chemistry, Vol. 25, Issue 3-4, p. 125-270 https://doi.org/10.1016/S0079-6786(97)80886-2	journal	January 1997
Acoustic-phonon propagation in superlattices Tamura, S.; Hurley, D. C.; Wolfe, J. P. Physical Review B, Vol. 38, Issue 2 https://doi.org/10.1103/PhysRevB.38.1427	journal	July 1988
Dielectric confinement effect on excitons in PbI 4 -based layered semiconductors Hong, X.; Ishihara, T.; Nurmikko, A. V. Physical Review B, Vol. 45, Issue 12 https://doi.org/10.1103/PhysRevB.45.6961	journal	March 1992
Minimum Thermal Conductivity of Superlattices Simkin, M. V.; Mahan, G. D. Physical Review Letters, Vol. 84, Issue 5 https://doi.org/10.1103/PhysRevLett.84.927	journal	January 2000
Ultra-Low Thermal Conductivity in Organic–Inorganic Hybrid Perovskite CH ₃ NH ₃ PbI ₃ Pisoni, Andrea; Jaćimović, Jaćim; Barišić, Osor S. The Journal of Physical Chemistry Letters, Vol. 5, Issue 14 https://doi.org/10.1021/jz5012109	journal	July 2014
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7, p. 992-1005 https://doi.org/10.1002/adma.201304138	journal	December 2013
Charge-Carrier Dynamics in Organic-Inorganic Metal Halide Perovskites Herz, Laura M. Annual Review of Physical Chemistry, Vol. 67, Issue 1 https://doi.org/10.1146/annurev-physchem-040215-112222	journal	May 2016
Relations between the Refractive Index and Energy Gap of Semiconductors Moss, T. S. physica status solidi (b), Vol. 131, Issue 2 https://doi.org/10.1002/pssb.2221310202	journal	October 1985
Effects of chemical bonding on heat transport across interfaces Losego, Mark D.; Grady, Martha E.; Sottos, Nancy R. Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3303	journal	April 2012
Physical mechanisms of coherent acoustic phonons generation by ultrafast laser action Ruello, Pascal; Gusev, Vitalyi E. Ultrasonics, Vol. 56 https://doi.org/10.1016/j.ultras.2014.06.004	journal	February 2015
Atomic and molecular layer deposition: off the beaten track Van Bui, H.; Grillo, F.; van Ommen, J. R. Chemical Communications, Vol. 53, Issue 1 https://doi.org/10.1039/C6CC05568K	journal	January 2017
Targeted Magnetic Nanoparticles for Remote Magnetothermal Disruption of Amyloid-β Aggregates Loynachan, Colleen N.; Romero, Gabriela; Christiansen, Michael G. Advanced Healthcare Materials, Vol. 4, Issue 14 https://doi.org/10.1002/adhm.201500487	journal	August 2015
High Members of the 2D Ruddlesden-Popper Halide Perovskites: Synthesis, Optical Properties, and Solar Cells of (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) 4 Pb 5 I 16 Stoumpos, Constantinos C.; Soe, Chan Myae Myae; Tsai, Hsinhan Chem, Vol. 2, Issue 3 https://doi.org/10.1016/j.chempr.2017.02.004	journal	March 2017
Crossover from incoherent to coherent phonon scattering in epitaxial oxide superlattices Ravichandran, Jayakanth; Yadav, Ajay K.; Cheaito, Ramez Nature Materials, Vol. 13, Issue 2 https://doi.org/10.1038/nmat3826	journal	December 2013
Tailoring the Energy Landscape in Quasi-2D Halide Perovskites Enables Efficient Green-Light Emission Quan, Li Na; Zhao, Yongbiao; García de Arquer, F. Pelayo Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b00976	journal	May 2017
Low-Dimensional-Networked Metal Halide Perovskites: The Next Big Thing Saidaminov, Makhsud I.; Mohammed, Omar F.; Bakr, Osman M. ACS Energy Letters, Vol. 2, Issue 4 https://doi.org/10.1021/acsenergylett.6b00705	journal	March 2017
Size and Interface Effects on Thermal Conductivity of Superlattices and Periodic Thin-Film Structures Chen, G. Journal of Heat Transfer, Vol. 119, Issue 2 https://doi.org/10.1115/1.2824212	journal	May 1997
Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells Mao, Lingling; Tsai, Hsinhan; Nie, Wanyi Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03054	journal	October 2016
An overview of molecular layer deposition for organic and organic–inorganic hybrid materials: mechanisms, growth characteristics, and promising applications Meng, Xiangbo Journal of Materials Chemistry A, Vol. 5, Issue 35 https://doi.org/10.1039/C7TA04449F	journal	January 2017
Chemically diverse and multifunctional hybrid organic–inorganic perovskites Li, Wei; Wang, Zheming; Deschler, Felix Nature Reviews Materials, Vol. 2, Issue 3 https://doi.org/10.1038/natrevmats.2016.99	journal	February 2017
Direct Observation of Electron–Phonon Coupling and Slow Vibrational Relaxation in Organic–Inorganic Hybrid Perovskites Straus, Daniel B.; Hurtado Parra, Sebastian; Iotov, Natasha Journal of the American Chemical Society, Vol. 138, Issue 42 https://doi.org/10.1021/jacs.6b08175	journal	October 2016
Long-range hot-carrier transport in hybrid perovskites visualized by ultrafast microscopy Guo, Zhi; Wan, Yan; Yang, Mengjin Science, Vol. 356, Issue 6333 https://doi.org/10.1126/science.aam7744	journal	April 2017
Selective enhancement of optical nonlinearity in two-dimensional organic-inorganic lead iodide perovskites Saouma, F. O.; Stoumpos, C. C.; Wong, J. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00788-x	journal	September 2017
Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14120	journal	January 2017
Near infrared two photon imaging using a bright cationic Yb( iii ) bioprobe spontaneously internalized into live cells Bui, Anh Thy; Beyler, Maryline; Grichine, Alexei Chemical Communications, Vol. 53, Issue 44 https://doi.org/10.1039/C7CC02835K	journal	January 2017
Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology Love, J. Christopher; Estroff, Lara A.; Kriebel, Jennah K. ChemInform, Vol. 36, Issue 32 https://doi.org/10.1002/chin.200532281	journal	August 2005
Lattice thermal transport in two-dimensional alloys and fractal heterostructures Krishnamoorthy, Aravind; Baradwaj, Nitish; Nakano, Aiichiro Scientific Reports, Vol. 11, Issue 1 https://doi.org/10.1038/s41598-021-81055-4	journal	January 2021
Direct-indirect character of the bandgap in methylammonium lead iodide perovskite. Hutter, Em; Gélvez-Rueda, Mc; Osherov, A. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.12468	text	January 2017
Local polar fluctuations in lead halide perovskite crystals Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z. arXiv https://doi.org/10.48550/arxiv.1604.08107	text	January 2016
Relations between the Refractive Index and Energy Gap of Semiconductors Moss, T. S. physica status solidi (b), Vol. 131, Issue 2 https://doi.org/10.1002/pssb.2221310202	journal	October 1985
Exceptional elastic anisotropy of hybrid organic-inorganic perovskite CH ₃ NH ₃ PbBr ₃ measured by laser ultrasonic technique Lomonosov, Alexey M.; Yan, Xiaoliang; Sheng, Chuanxiang physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 8 https://doi.org/10.1002/pssr.201600156	journal	July 2016
High Members of the 2D Ruddlesden-Popper Halide Perovskites: Synthesis, Optical Properties, and Solar Cells of (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) 4 Pb 5 I 16 Stoumpos, Constantinos C.; Soe, Chan Myae Myae; Tsai, Hsinhan Chem, Vol. 2, Issue 3 https://doi.org/10.1016/j.chempr.2017.02.004	journal	March 2017
Physical mechanisms of coherent acoustic phonons generation by ultrafast laser action Ruello, Pascal; Gusev, Vitalyi E. Ultrasonics, Vol. 56 https://doi.org/10.1016/j.ultras.2014.06.004	journal	February 2015
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells Mao, Lingling; Tsai, Hsinhan; Nie, Wanyi Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03054	journal	October 2016
Tailoring the Energy Landscape in Quasi-2D Halide Perovskites Enables Efficient Green-Light Emission Quan, Li Na; Zhao, Yongbiao; García de Arquer, F. Pelayo Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b00976	journal	May 2017
Phonon Speed, Not Scattering, Differentiates Thermal Transport in Lead Halide Perovskites Elbaz, Giselle A.; Ong, Wee-Liat; Doud, Evan A. Nano Letters, Vol. 17, Issue 9 https://doi.org/10.1021/acs.nanolett.7b02696	journal	August 2017
Low-Dimensional-Networked Metal Halide Perovskites: The Next Big Thing Saidaminov, Makhsud I.; Mohammed, Omar F.; Bakr, Osman M. ACS Energy Letters, Vol. 2, Issue 4 https://doi.org/10.1021/acsenergylett.6b00705	journal	March 2017
Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies Guo, Peijun; Xia, Yi; Gong, Jue ACS Energy Letters, Vol. 2, Issue 10 https://doi.org/10.1021/acsenergylett.7b00790	journal	September 2017
Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology Love, J. Christopher; Estroff, Lara A.; Kriebel, Jennah K. Chemical Reviews, Vol. 105, Issue 4 https://doi.org/10.1021/cr0300789	journal	April 2005
Direct Observation of Electron–Phonon Coupling and Slow Vibrational Relaxation in Organic–Inorganic Hybrid Perovskites Straus, Daniel B.; Hurtado Parra, Sebastian; Iotov, Natasha Journal of the American Chemical Society, Vol. 138, Issue 42 https://doi.org/10.1021/jacs.6b08175	journal	October 2016
Elastic Moduli of Organic Electronic Materials by the Buckling Method Tahk, Dongha; Lee, Hong H.; Khang, Dahl-Young Macromolecules, Vol. 42, Issue 18 https://doi.org/10.1021/ma900137k	journal	September 2009
Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites Yang, Jianfeng; Wen, Xiaoming; Xia, Hongze Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14120	journal	January 2017
Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons Mante, Pierre-Adrien; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14398	journal	February 2017
Orientational order controls crystalline and amorphous thermal transport in superatomic crystals Ong, Wee-Liat; O’Brien, Evan S.; Dougherty, Patrick S. M. Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4739	journal	September 2016
Bright light-emitting diodes based on organometal halide perovskite Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.149	journal	August 2014
Selective enhancement of optical nonlinearity in two-dimensional organic-inorganic lead iodide perovskites Saouma, F. O.; Stoumpos, C. C.; Wong, J. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00788-x	journal	September 2017
Directed assembly of layered perovskite heterostructures as single crystals Aubrey, Michael L.; Saldivar Valdes, Abraham; Filip, Marina R. Nature, Vol. 597, Issue 7876 https://doi.org/10.1038/s41586-021-03810-x	journal	September 2021
Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide Whitfield, P. S.; Herron, N.; Guise, W. E. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep35685	journal	October 2016
Experimental and theoretical optical properties of methylammonium lead halide perovskites Leguy, Aurélien M. A.; Azarhoosh, Pooya; Alonso, M. Isabel Nanoscale, Vol. 8, Issue 12 https://doi.org/10.1039/c5nr05435d	journal	January 2016
Thermal conductivity of Si–Ge superlattices Lee, S. -M.; Cahill, David G.; Venkatasubramanian, Rama Applied Physics Letters, Vol. 70, Issue 22 https://doi.org/10.1063/1.118755	journal	June 1997
Effect of reduced dimensionality on the optical band gap of SrTiO ₃ Lee, Che-Hui; Podraza, Nikolas J.; Zhu, Ye Applied Physics Letters, Vol. 102, Issue 12 https://doi.org/10.1063/1.4798241	journal	March 2013
Phonon Dynamics at Surfaces and Interfaces and Its Implications in Energy Transport in Nanostructured Materials—An opinion Paper Li, Deyu; McGaughey, Alan J. H. Nanoscale and Microscale Thermophysical Engineering, Vol. 19, Issue 2 https://doi.org/10.1080/15567265.2015.1035199	journal	April 2015
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Ultrasonic study of liquid crystals Miyano, K.; Ketterson, J. B. Physical Review A, Vol. 12, Issue 2 https://doi.org/10.1103/physreva.12.615	journal	August 1975
Size and Interface Effects on Thermal Conductivity of Superlattices and Periodic Thin-Film Structures Chen, G. Journal of Heat Transfer, Vol. 119, Issue 2 https://doi.org/10.1115/1.2824212	journal	May 1997
Coherent Phonon Heat Conduction in Superlattices Luckyanova, M. N.; Garg, J.; Esfarjani, K. Science, Vol. 338, Issue 6109 https://doi.org/10.1126/science.1225549	journal	November 2012
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Science, Vol. 286, Issue 5441, p. 945-947 https://doi.org/10.1126/science.286.5441.945	journal	October 1999
Screening in crystalline liquids protects energetic carriers in hybrid perovskites Zhu, H.; Miyata, K.; Fu, Y. Science, Vol. 353, Issue 6306 https://doi.org/10.1126/science.aaf9570	journal	September 2016
Long-range hot-carrier transport in hybrid perovskites visualized by ultrafast microscopy Guo, Zhi; Wan, Yan; Yang, Mengjin Science, Vol. 356, Issue 6333 https://doi.org/10.1126/science.aam7744	journal	April 2017
Direct-indirect character of the bandgap in methylammonium lead iodide perovskite. Hutter, Em; Gélvez-Rueda, Mc; Osherov, A. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.12468	text	January 2017
Van der Waals heterostructures Geim, A. K.; Grigorieva, I. V. arXiv https://doi.org/10.48550/arxiv.1307.6718	text	January 2013

Cited By (9)

Merits and Challenges of Ruddlesden-Popper Soft Halide Perovskites in Electro-Optics and Optoelectronics Chen, Zhizhong; Guo, Yuwei; Wertz, Esther Advanced Materials, Vol. 31, Issue 1 https://doi.org/10.1002/adma.201803514	journal	October 2018
Edge Effect on the Population of Free Carriers and Excitons in Single‐Crystal CH ₃ NH ₃ PbBr ₃ Perovskite Nanomaterials Zhang, Zhen‐Yu; Yu, Kuai; Wang, Guo‐Ping Advanced Electronic Materials, Vol. 5, Issue 7 https://doi.org/10.1002/aelm.201900216	journal	May 2019
Self-Assembled 2D Perovskite Layers for Efficient Printable Solar Cells Zuo, Chuantian; Scully, Andrew D.; Vak, Doojin Advanced Energy Materials, Vol. 9, Issue 4 https://doi.org/10.1002/aenm.201803258	journal	December 2018
Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices Guo, Peijun; Mannodi-Kanakkithodi, Arun; Gong, Jue Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08363-2	journal	January 2019
Hot carrier solar cells and the potential of perovskites for breaking the Shockley–Queisser limit Kahmann, Simon; Loi, Maria A. Journal of Materials Chemistry C, Vol. 7, Issue 9 https://doi.org/10.1039/c8tc04641g	journal	January 2019
Superlattices based on van der Waals 2D materials Ryu, Yu Kyoung; Frisenda, Riccardo; Castellanos-Gomez, Andres Chemical Communications, Vol. 55, Issue 77 https://doi.org/10.1039/c9cc04919c	journal	January 2019
Optical deformation potential and self-trapped excitons in 2D hybrid perovskites Yu, Zhi-Gang Physical Chemistry Chemical Physics, Vol. 21, Issue 40 https://doi.org/10.1039/c9cp03080h	journal	January 2019
Broadband white-light emission from supramolecular piperazinium-based lead halide perovskites linked by hydrogen bonds Jung, Mi-Hee; Ko, Kyoung Chul; Lee, Woo Ram Dalton Transactions, Vol. 48, Issue 40 https://doi.org/10.1039/c9dt03469b	journal	January 2019
Infrared-pump electronic-probe of methylammonium lead iodide reveals electronically decoupled organic and inorganic sublattices Guo, Peijun; Mannodi-Kanakkithodi, Arun; Gong, Jue Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08363-2	journal	January 2019

Similar Records

Signatures of Coherent Phonon Transport in Ultralow Thermal Conductivity Two-Dimensional Ruddlesden–Popper Phase Perovskites

Journal Article · 2021 · ACS Nano · OSTI ID:1864310

Christodoulides, Alexander D.; Guo, Peijun; Dai, Lingyun; +8 more

Incorporating Large A Cations into Lead Iodide Perovskite Cages: Relaxed Goldschmidt Tolerance Factor and Impact on Exciton–Phonon Interaction

Journal Article · 2019 · ACS Central Science · OSTI ID:1544598

Fu, Yongping; Hautzinger, Matthew P.; Luo, Ziyu; +7 more

Long periodic ripple in a 2D hybrid halide perovskite structure using branched organic spacers

Journal Article · 2020 · Chemical Science · OSTI ID:1761267

Hoffman, Justin M.; Malliakas, Christos D.; Sidhik, Siraj; +4 more

Related Subjects

36 MATERIALS SCIENCE

Title: Cross-plane coherent acoustic phonons in two-dimensional organic-inorganic hybrid perovskites

Citation Formats

References (97)

Cited By (9)

Similar Records

Related Subjects