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Title: Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas

Abstract

Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising route to enhance the quantum yield of exciton emission and can lead to single-photon emission at room temperature.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1];  [1];  [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Stevens Inst. of Technology, Hoboken, NJ (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1461375
Alternate Identifier(s):
OSTI ID: 1457200; OSTI ID: 1475343
Report Number(s):
NREL/JA-5K00-71992; LA-UR-18-24661
Journal ID: ISSN 2040-3364; NANOHL
Grant/Contract Number:  
AC36-08GO28308; LDRD program; AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 10; Journal Issue: 26; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; single-walled carbon nanotubes; quantum yield; exciton emission

Citation Formats

Shayan, Kamran, He, Xiaowei, Luo, Yue, Rabut, Claire, Li, Xiangzhi, Hartmann, Nicolai F., Blackburn, Jeffrey L., Doorn, Stephen K., Htoon, Han, and Strauf, Stefan. Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas. United States: N. p., 2018. Web. https://doi.org/10.1039/C8NR03542C.
Shayan, Kamran, He, Xiaowei, Luo, Yue, Rabut, Claire, Li, Xiangzhi, Hartmann, Nicolai F., Blackburn, Jeffrey L., Doorn, Stephen K., Htoon, Han, & Strauf, Stefan. Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas. United States. https://doi.org/10.1039/C8NR03542C
Shayan, Kamran, He, Xiaowei, Luo, Yue, Rabut, Claire, Li, Xiangzhi, Hartmann, Nicolai F., Blackburn, Jeffrey L., Doorn, Stephen K., Htoon, Han, and Strauf, Stefan. Mon . "Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas". United States. https://doi.org/10.1039/C8NR03542C. https://www.osti.gov/servlets/purl/1461375.
@article{osti_1461375,
title = {Suppression of exciton dephasing in sidewall-functionalized carbon nanotubes embedded into metallo-dielectric antennas},
author = {Shayan, Kamran and He, Xiaowei and Luo, Yue and Rabut, Claire and Li, Xiangzhi and Hartmann, Nicolai F. and Blackburn, Jeffrey L. and Doorn, Stephen K. and Htoon, Han and Strauf, Stefan},
abstractNote = {Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising route to enhance the quantum yield of exciton emission and can lead to single-photon emission at room temperature.},
doi = {10.1039/C8NR03542C},
journal = {Nanoscale},
number = 26,
volume = 10,
place = {United States},
year = {2018},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 2 works
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Figures / Tables:

Fig. 1 Fig. 1: Low-temperature PL characterization of individual SWCNTs. (a) Schematic representation of a SWCNT with a 3,5-dichlorobenzene aryl group attached to the sidewall shown enlarged for clarity (upper panel). Level scheme for quasi-resonant pumping of excitons into their excited states via one-phonon absorption processes involving the zone-center optical phonons (lowermore » panel). (b) Low temperature PL spectra of 3,5-dichlorobenzene-functionalized LV-grown SWCNTs wrapped in PFO-BPy with (5,4) chirality (upper panel) and (6,4) chirality (lower panel). G and D: Raman signature of G-mode and D-mode phonons. (c) Overview of PL spectra from 10 individual 3,5-dichlorobenzene-functionalized (5,4) and (6,4) LV-grown SWCNTs wrapped in PFO-BPy.« less

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Works referenced in this record:

Suppression of Blinking and Enhanced Exciton Emission from Individual Carbon Nanotubes
journal, March 2011

  • Ai, Nan; Walden-Newman, William; Song, Qiang
  • ACS Nano, Vol. 5, Issue 4
  • DOI: 10.1021/nn102885p

Excitonic Effects and Optical Spectra of Single-Walled Carbon Nanotubes
journal, February 2004


Solid-State Approach for Fabrication of Photostable, Oxygen-Doped Carbon Nanotubes
journal, September 2015

  • Ma, Xuedan; Baldwin, Jon K. S.; Hartmann, Nicolai F.
  • Advanced Functional Materials, Vol. 25, Issue 39
  • DOI: 10.1002/adfm.201502580

Electronic Structure and Chemical Nature of Oxygen Dopant States in Carbon Nanotubes
journal, October 2014

  • Ma, Xuedan; Adamska, Lyudmyla; Yamaguchi, Hisato
  • ACS Nano, Vol. 8, Issue 10
  • DOI: 10.1021/nn504553y

Strong Acoustic Phonon Localization in Copolymer-Wrapped Carbon Nanotubes
journal, May 2015

  • Sarpkaya, Ibrahim; Ahmadi, Ehsaneh D.; Shepard, Gabriella D.
  • ACS Nano, Vol. 9, Issue 6
  • DOI: 10.1021/acsnano.5b01997

Brightening of the Lowest Exciton in Carbon Nanotubes via Chemical Functionalization
journal, April 2012

  • Kilina, Svetlana; Ramirez, Jessica; Tretiak, Sergei
  • Nano Letters, Vol. 12, Issue 5
  • DOI: 10.1021/nl300165w

Photoluminescence Imaging of Suspended Single-Walled Carbon Nanotubes
journal, August 2006

  • Lefebvre, Jacques; Austing, David G.; Bond, Jeffery
  • Nano Letters, Vol. 6, Issue 8
  • DOI: 10.1021/nl060530e

Purcell-enhanced quantum yield from carbon nanotube excitons coupled to plasmonic nanocavities
journal, November 2017


Widely Tunable Single-Photon Source from a Carbon Nanotube in the Purcell Regime
journal, June 2016


A planar dielectric antenna for directional single-photon emission and near-unity collection efficiency
journal, January 2011


Low-Temperature Single Carbon Nanotube Spectroscopy of sp 3 Quantum Defects
journal, September 2017


Room-temperature single-photon generation from solitary dopants of carbon nanotubes
journal, July 2015

  • Ma, Xuedan; Hartmann, Nicolai F.; Baldwin, Jon K. S.
  • Nature Nanotechnology, Vol. 10, Issue 8
  • DOI: 10.1038/nnano.2015.136

Confirmation of K-Momentum Dark Exciton Vibronic Sidebands Using 13 C-labeled, Highly Enriched (6,5) Single-walled Carbon Nanotubes
journal, February 2012

  • Blackburn, Jeffrey L.; Holt, Josh M.; Irurzun, Veronica M.
  • Nano Letters, Vol. 12, Issue 3
  • DOI: 10.1021/nl204072x

Oxygen Doping Modifies Near-Infrared Band Gaps in Fluorescent Single-Walled Carbon Nanotubes
journal, November 2010


Brightening of excitons in carbon nanotubes on dimensionality modification
journal, July 2013

  • Miyauchi, Yuhei; Iwamura, Munechiyo; Mouri, Shinichiro
  • Nature Photonics, Vol. 7, Issue 9
  • DOI: 10.1038/nphoton.2013.179

Quantum Light Signatures and Nanosecond Spectral Diffusion from Cavity-Embedded Carbon Nanotubes
journal, January 2012

  • Walden-Newman, William; Sarpkaya, Ibrahim; Strauf, Stefan
  • Nano Letters, Vol. 12, Issue 4
  • DOI: 10.1021/nl204402v

Role of Surfactants and Salt in Aqueous Two-Phase Separation of Carbon Nanotubes toward Simple Chirality Isolation
journal, January 2014

  • Subbaiyan, Navaneetha K.; Cambré, Sofie; Parra-Vasquez, A. Nicholas G.
  • ACS Nano, Vol. 8, Issue 2
  • DOI: 10.1021/nn405934y

Elastic Exciton-Exciton Scattering in Photoexcited Carbon Nanotubes
journal, September 2011


Brightening of carbon nanotube photoluminescence through the incorporation of sp3 defects
journal, July 2013

  • Piao, Yanmei; Meany, Brendan; Powell, Lyndsey R.
  • Nature Chemistry, Vol. 5, Issue 10
  • DOI: 10.1038/nchem.1711

Prolonged spontaneous emission and dephasing of localized excitons in air-bridged carbon nanotubes
journal, July 2013

  • Sarpkaya, Ibrahim; Zhang, Zhengyi; Walden-Newman, William
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3152

Tunable room-temperature single-photon emission at telecom wavelengths from sp3 defects in carbon nanotubes
journal, July 2017


Stepwise Quenching of Exciton Fluorescence in Carbon Nanotubes by Single-Molecule Reactions
journal, June 2007


Exciton Localization and Optical Emission in Aryl-Functionalized Carbon Nanotubes
journal, November 2017

  • Gifford, Brendan J.; Kilina, Svetlana; Htoon, Han
  • The Journal of Physical Chemistry C, Vol. 122, Issue 3
  • DOI: 10.1021/acs.jpcc.7b09558

Broadband Light Collection Efficiency Enhancement of Carbon Nanotube Excitons Coupled to Metallo-Dielectric Antenna Arrays
journal, November 2017


Trion-Species-Resolved Quantum Beats in MoSe 2
journal, September 2017

  • Shepard, Gabriella D.; Ardelean, Jenny V.; Ajayi, Obafunso A.
  • ACS Nano, Vol. 11, Issue 11
  • DOI: 10.1021/acsnano.7b06444

Time-Resolved Fluorescence of Carbon Nanotubes and Its Implication for Radiative Lifetimes
journal, April 2004


Photoluminescence Dynamics of Aryl sp 3 Defect States in Single-Walled Carbon Nanotubes
journal, August 2016

  • Hartmann, Nicolai F.; Velizhanin, Kirill A.; Haroz, Erik H.
  • ACS Nano, Vol. 10, Issue 9
  • DOI: 10.1021/acsnano.6b02986

Highly selective dispersion of single-walled carbon nanotubes using aromatic polymers
journal, September 2007

  • Nish, Adrian; Hwang, Jeong-Yuan; Doig, James
  • Nature Nanotechnology, Vol. 2, Issue 10, p. 640-646
  • DOI: 10.1038/nnano.2007.290

Unconventional motional narrowing in the optical spectrum of a semiconductor quantum dot
journal, October 2006

  • Berthelot, A.; Favero, I.; Cassabois, G.
  • Nature Physics, Vol. 2, Issue 11
  • DOI: 10.1038/nphys433

Spectral diffusion and its influence on the emission linewidths of site-controlled GaN nanowire quantum dots
journal, September 2015


Fluorescence Imaging In Vivo at Wavelengths beyond 1500 nm
journal, October 2015

  • Diao, Shuo; Blackburn, Jeffrey L.; Hong, Guosong
  • Angewandte Chemie, Vol. 127, Issue 49
  • DOI: 10.1002/ange.201507473

Unifying the Low-Temperature Photoluminescence Spectra of Carbon Nanotubes: The Role of Acoustic Phonon Confinement
journal, July 2014


Tuning the driving force for exciton dissociation in single-walled carbon nanotube heterojunctions
journal, April 2016

  • Ihly, Rachelle; Mistry, Kevin S.; Ferguson, Andrew J.
  • Nature Chemistry, Vol. 8, Issue 6
  • DOI: 10.1038/nchem.2496

Photoluminescence imaging of solitary dopant sites in covalently doped single-wall carbon nanotubes
journal, January 2015

  • Hartmann, Nicolai F.; Yalcin, Sibel Ebru; Adamska, Lyudmyla
  • Nanoscale, Vol. 7, Issue 48
  • DOI: 10.1039/C5NR06343D

High-Yield Dispersions of Large-Diameter Semiconducting Single-Walled Carbon Nanotubes with Tunable Narrow Chirality Distributions
journal, February 2013

  • Mistry, Kevin S.; Larsen, Brian A.; Blackburn, Jeffrey L.
  • ACS Nano, Vol. 7, Issue 3, p. 2231-2239
  • DOI: 10.1021/nn305336x

High energetic excitons in carbon nanotubes directly probe charge-carriers
journal, May 2015

  • Soavi, Giancarlo; Scotognella, Francesco; Viola, Daniele
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep09681

Fluorescence Imaging In Vivo at Wavelengths beyond 1500 nm
journal, October 2015

  • Diao, Shuo; Blackburn, Jeffrey L.; Hong, Guosong
  • Angewandte Chemie International Edition, Vol. 54, Issue 49
  • DOI: 10.1002/anie.201507473

    Works referencing / citing this record:

    Intrinsic limits of defect-state photoluminescence dynamics in functionalized carbon nanotubes
    journal, January 2019

    • He, Xiaowei; Sun, Liuyang; Gifford, Brendan J.
    • Nanoscale, Vol. 11, Issue 18
    • DOI: 10.1039/c9nr02175b

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.