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Title: Quantifying X-Ray Fluorescence Data Using MAPS

Abstract

Here, the quantification of X-ray fluorescence (XRF) microscopy maps by fitting the raw spectra to a known standard is crucial for evaluating chemical composition and elemental distribution within a material. Synchrotron-based XRF has become an integral characterization technique for a variety of research topics, particularly due to its non-destructive nature and its high sensitivity. Today, synchrotrons can acquire fluorescence data at spatial resolutions well below a micron, allowing for the evaluation of compositional variations at the nanoscale. Through proper quantification, it is then possible to obtain an in-depth, high-resolution understanding of elemental segregation, stoichiometric relationships, and clustering behavior. This article explains how to use the MAPS fitting software developed by Argonne National Laboratory for the quantification of full 2-D XRF maps. We use as an example results from a Cu(In,Ga)Se-2 solar cell, taken at the Advanced Photon Source beamline 2-ID-D at Argonne National Laboratory. We show the standard procedure for fitting raw data, demonstrate how to evaluate the quality of a fit and present the typical outputs generated by the program. In addition, we discuss in this manuscript certain software limitations and offer suggestions for how to further correct the data to be numerically accurate and representative of spatially resolved,more » elemental concentrations.« less

Authors:
 [1];  [1];  [1];  [2];  [2];  [1]
  1. Arizona State Univ., Tempe, AZ (United States)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
OSTI Identifier:
1461335
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Visualized Experiments
Additional Journal Information:
Journal Volume: 132; Journal Issue: 132; Journal ID: ISSN 1940-087X
Publisher:
MyJoVE Corp.
Country of Publication:
United States
Language:
English
Subject:
47 OTHER INSTRUMENTATION; X-ray fluorescence; quantification; synchrotron; fitting; solar cell; defects; impurities; software; maps

Citation Formats

Nietzold, Tara, West, Bradley M., Stuckelberger, Michael, Lai, Barry, Vogt, Stefan, and Bertoni, Mariana I. Quantifying X-Ray Fluorescence Data Using MAPS. United States: N. p., 2018. Web. doi:10.3791/56042.
Nietzold, Tara, West, Bradley M., Stuckelberger, Michael, Lai, Barry, Vogt, Stefan, & Bertoni, Mariana I. Quantifying X-Ray Fluorescence Data Using MAPS. United States. doi:10.3791/56042.
Nietzold, Tara, West, Bradley M., Stuckelberger, Michael, Lai, Barry, Vogt, Stefan, and Bertoni, Mariana I. Mon . "Quantifying X-Ray Fluorescence Data Using MAPS". United States. doi:10.3791/56042. https://www.osti.gov/servlets/purl/1461335.
@article{osti_1461335,
title = {Quantifying X-Ray Fluorescence Data Using MAPS},
author = {Nietzold, Tara and West, Bradley M. and Stuckelberger, Michael and Lai, Barry and Vogt, Stefan and Bertoni, Mariana I.},
abstractNote = {Here, the quantification of X-ray fluorescence (XRF) microscopy maps by fitting the raw spectra to a known standard is crucial for evaluating chemical composition and elemental distribution within a material. Synchrotron-based XRF has become an integral characterization technique for a variety of research topics, particularly due to its non-destructive nature and its high sensitivity. Today, synchrotrons can acquire fluorescence data at spatial resolutions well below a micron, allowing for the evaluation of compositional variations at the nanoscale. Through proper quantification, it is then possible to obtain an in-depth, high-resolution understanding of elemental segregation, stoichiometric relationships, and clustering behavior. This article explains how to use the MAPS fitting software developed by Argonne National Laboratory for the quantification of full 2-D XRF maps. We use as an example results from a Cu(In,Ga)Se-2 solar cell, taken at the Advanced Photon Source beamline 2-ID-D at Argonne National Laboratory. We show the standard procedure for fitting raw data, demonstrate how to evaluate the quality of a fit and present the typical outputs generated by the program. In addition, we discuss in this manuscript certain software limitations and offer suggestions for how to further correct the data to be numerically accurate and representative of spatially resolved, elemental concentrations.},
doi = {10.3791/56042},
journal = {Journal of Visualized Experiments},
number = 132,
volume = 132,
place = {United States},
year = {2018},
month = {1}
}

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