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Title: Adhesion Energies of 2D Graphene and MoS 2 to Silicon and Metal Substrates

Abstract

In this work, results for the adhesion energy of graphene and MoS 2 to silicon based and metal substrates using the intercalation of nanoparticles method are presented. In this method, nanoparticles are dispersed onto the substrates before transferring the 2D material onto the substrate. This causes a blister to form, the width and height of which can be measured by AFM. Using a simple model then allows for the adhesion energy to be found. The substrates tested are SiO 2, Si 3N 4, gold, and platinum. Gold is found to have the highest adhesion energy per area of 7687.10 and 1207.26mJm -2 for graphene and MoS 2 respectively.

Authors:
ORCiD logo [1];  [2];  [1]; ORCiD logo [3]; ORCiD logo [1]
  1. Univ. of Pittsburgh, PA (United States). Dept. of Electrical and Computer Engineering
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
  3. Sungkyunkwan Univ., Suwon (Republic of Korea). Dept. of Energy Science; Inst. of Basic Science, Suwon (Korea, Republic of). Center for Integrated Nanostructure Physics
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE; National Science Foundation (NSF)
OSTI Identifier:
1461293
Grant/Contract Number:  
AC02-06CH11357; ECCS 1709307; HRD 1434012
Resource Type:
Accepted Manuscript
Journal Name:
Physica Status Solidi. A, Applications and Materials Science
Additional Journal Information:
Journal Volume: 215; Journal Issue: 1; Journal ID: ISSN 1862-6300
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 42 ENGINEERING; adhesion; MoS2; graphene

Citation Formats

Torres, Jorge, Zhu, Yisi, Liu, Pei, Lim, Seong Chu, and Yun, Minhee. Adhesion Energies of 2D Graphene and MoS2 to Silicon and Metal Substrates. United States: N. p., 2017. Web. doi:10.1002/pssa.201700512.
Torres, Jorge, Zhu, Yisi, Liu, Pei, Lim, Seong Chu, & Yun, Minhee. Adhesion Energies of 2D Graphene and MoS2 to Silicon and Metal Substrates. United States. doi:10.1002/pssa.201700512.
Torres, Jorge, Zhu, Yisi, Liu, Pei, Lim, Seong Chu, and Yun, Minhee. Fri . "Adhesion Energies of 2D Graphene and MoS2 to Silicon and Metal Substrates". United States. doi:10.1002/pssa.201700512. https://www.osti.gov/servlets/purl/1461293.
@article{osti_1461293,
title = {Adhesion Energies of 2D Graphene and MoS2 to Silicon and Metal Substrates},
author = {Torres, Jorge and Zhu, Yisi and Liu, Pei and Lim, Seong Chu and Yun, Minhee},
abstractNote = {In this work, results for the adhesion energy of graphene and MoS2 to silicon based and metal substrates using the intercalation of nanoparticles method are presented. In this method, nanoparticles are dispersed onto the substrates before transferring the 2D material onto the substrate. This causes a blister to form, the width and height of which can be measured by AFM. Using a simple model then allows for the adhesion energy to be found. The substrates tested are SiO2, Si3N4, gold, and platinum. Gold is found to have the highest adhesion energy per area of 7687.10 and 1207.26mJm-2 for graphene and MoS2 respectively.},
doi = {10.1002/pssa.201700512},
journal = {Physica Status Solidi. A, Applications and Materials Science},
number = 1,
volume = 215,
place = {United States},
year = {2017},
month = {12}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 3 works
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Figures / Tables:

Figure 1 Figure 1: The substrate creation process. a) A growth substrate is chosen and cleaned. b) The 2D material is grown on the substrate using a CVD method. c) PMMA is spun on top of the 2D material and the backside of the substrate is cleaned of any excess 2D materialmore » growth. d) The prepared substrate is put into an etchant bath. e) The substrate is etched away and the remaining 2D material and PMMA hybrid is cleaned. f) A substrate is chosen to deposit nanoparticles onto. g) Gold nanoparticles are deposited onto the substrate. h) The 2D material is transferred onto the prepared substrate, sandwiching the nanoparticle in between the substrate and the 2D material and creating a blister.« less

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    Works referencing / citing this record:

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