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Title: Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects

Journal Article · · Journal of Materials Chemistry. A
DOI: https://doi.org/10.1039/c8ta02562b · OSTI ID:1461266

A polyoxometalate supported by the metal–organic framework, NU-1000, undergoes migration from the mesopore to the micropore when heated.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
U.S. Department of Defense (DOD) - Defense Threat Reduction Agency (DTRA); National Science Foundation (NSF); USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1461266
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 17 Vol. 6; ISSN JMCAET; ISSN 2050-7488
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (61)

Metathesis of 1-Butene to Propene over Mo/Al 2 O 3 @SBA-15: Influence of Alumina Introduction Methods on Catalytic Performance journal June 2015
Hydrolytic Stability and Hydrogen Peroxide Activation of Zirconium-Based Oxoclusters: Hydrolytic Stability of Zirconium-Based Oxoclusters journal November 2014
Hydrolytic Stability and Hydrogen Peroxide Activation of Zirconium‐Based Oxoclusters journal January 2015
Skeletal isomerization of 1-butene on 12-tungstophosphoric acid supported on zirconia journal December 1998
Thermal stability of 12-tungstophosphoric acid supported on zirconia journal February 2000
Revisiting active sites in heterogeneous catalysis: Their structure and their dynamic behaviour journal March 2014
Crystalline niobia with tailored porosity as support for cobalt catalysts for the Fischer–Tropsch synthesis journal November 2017
Host (aluminum incorporated mesocellulous silica foam (Al-MCF))-guest (tungsten polyoxometalate) nanocomposite material: an efficient and reusable catalyst for selective oxidation of sulfides to sulfoxides and sulfones journal December 2012
Toward Design Rules for Enzyme Immobilization in Hierarchical Mesoporous Metal-Organic Frameworks journal July 2016
Insights into the electrochemical behaviour of composite materials: Monovacant polyoxometalates @ porous metal-organic framework journal January 2013
Analysis of the sulphur mustard metabolites thiodiglycol and thiodiglycol sulphoxide in urine using isotope-dilution gas chromatography–ion trap tandem mass spectrometry journal January 2007
Phosphomolybdic acid functionalized covalent organic frameworks: Structure characterization and catalytic properties in olefin epoxidation journal September 2015
Polyoxometalate [γ-SiW10O34(H2O)2]4− on MCM-41 as catalysts for sulfide oxygenation with hydrogen peroxide journal October 2014
Synthesis, characterization and catalytic evaluation of H 3 PW 12 O 40 included in acrylic acid/acrylamide polymer for the selective oxidation of sulfides journal August 2016
High Stability of Immobilized Polyoxometalates on TiO 2 Nanoparticles and Nanoporous Films for Robust, Light-Induced Water Oxidation journal August 2015
Adsorption of a Catalytically Accessible Polyoxometalate in a Mesoporous Channel-type Metal–Organic Framework journal May 2017
Heterogeneous Diffusion of Alkanes in the Hierarchical Metal–Organic Framework NU-1000 journal August 2015
Role of a Modulator in the Synthesis of Phase-Pure NU-1000 journal November 2017
Aldehyde-Alcohol Reactions Catalyzed under Mild Conditions by Chromium(III) Terephthalate Metal Organic Framework (MIL-101) and Phosphotungstic Acid Composites journal November 2011
Heteropolyacid-Functionalized Aluminum 2-Aminoterephthalate Metal-Organic Frameworks As Reactive Aldehyde Sorbents and Catalysts journal June 2013
Design Strategies for the Molecular Level Synthesis of Supported Catalysts journal August 2011
Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis journal April 2013
Study of Guest Molecules in Metal–Organic Frameworks by Powder X-ray Diffraction: Analysis of Difference Envelope Density journal October 2014
Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties journal April 2012
Introduction to Metal–Organic Frameworks journal September 2011
Recent Developments in the Synthesis of Supported Catalysts journal June 2015
Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates journal February 1998
Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions journal February 1998
Selective Surface and Near-Surface Modification of a Noncatenated, Catalytically Active Metal-Organic Framework Material Based on Mn(salen) Struts journal April 2011
Resin-bound transition metal complexes journal March 1972
Active-Site-Accessible, Porphyrinic Metal−Organic Framework Materials journal April 2011
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828
journal May 2013
Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials journal January 2009
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes journal June 2015
Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions journal October 2016
A Fully Noble Metal-Free Photosystem Based on Cobalt-Polyoxometalates Immobilized in a Porphyrinic Metal–Organic Framework for Water Oxidation journal February 2018
Increased Electrical Conductivity in a Mesoporous Metal–Organic Framework Featuring Metallacarboranes Guests journal February 2018
Mechanism of H 2 O 2 Decomposition on Transition Metal Oxide Surfaces journal April 2012
Immobilization of Phosphotungstic Acid (PTA) on Imidazole Functionalized Silica: Evidence for the Nature of PTA Binding by Solid State NMR and Reaction Studies journal November 2009
Surface Behavior of Supported 12-Heteropoly Acid As Revealed by Nuclear Magnetic Resonance, X-ray Photoelectron Spectroscopy, and Fourier Transform Infrared Techniques journal January 1999
Chemical, thermal and mechanical stabilities of metal–organic frameworks journal February 2016
Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000 journal December 2015
Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices journal January 2007
31 P MAS NMR study of H 3 PW 12 O 40 supported on silica: formation of (SiOH 2 + )(H 2 PW 12 O 40 ) journal January 1992
Recent advances in porous polyoxometalate-based metal–organic framework materials journal January 2014
Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67 journal January 2015
Immobilization of Co-containing polyoxometalates in MIL-101(Cr): structural integrity versus chemical transformation journal January 2014
Nanoporous networks as caging supports for uniform, surfactant-free Co 3 O 4 nanocrystals and their applications in energy storage and conversion journal January 2015
Nanoporous networks as effective stabilisation matrices for nanoscale zero-valent iron and groundwater pollutant removal journal January 2016
Controllable design of tunable nanostructures inside metal–organic frameworks journal January 2017
Immobilization of polyoxometalates in crystalline solids for highly efficient heterogeneous catalysis journal January 2016
Efficient and selective oxidation of sulfides in batch and continuous flow using styrene-based polymer immobilised ionic liquid phase supported peroxotungstates journal January 2016
Polyoxometalate modified pine cone biochar carbon for supercapacitor electrodes journal January 2017
Polyoxometalates catalyst materials: X-ray thermal stability study of phosphorus-containing heteropolyacids H 3 +x PM 12 –x V x O 40 ·13–14H 2 O (M = Mo,W; x= 0–1) journal January 1992
Heterogeneous enantioselective catalysts: strategies for the immobilisation of homogeneous catalysts journal January 2004
Metal–organic frameworks as scaffolds for the encapsulation of active species: state of the art and future perspectives journal January 2012
Studies on the Mechanism of the Toxic Action of Organic Halogen Compounds journal June 1950
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area journal September 2005
Catalysis of Heteropoly Acids Entrapped in Activated Carbon journal May 1981
One-pot hydrothermal synthesis of H3PW12O40 supported on zeolite imidazolate frameworks (ZIF-8): a highly efficient heterogeneous catalyst for oxidation of sulfides to sulfoxides and sulfones journal March 2016
Synthesis, Characterization and Applications in Catalysis of Polyoxometalate/Zeolite Composites journal May 2016

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