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Title: Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects

Abstract

A polyoxometalate supported by the metal–organic framework, NU-1000, undergoes migration from the mesopore to the micropore when heated.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [1]; ORCiD logo [1]; ORCiD logo [2];  [3]
  1. Northwestern Univ., Evanston, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
U.S. Department of Defense (DOD) - Defense Threat Reduction Agency (DTRA); National Science Foundation (NSF); USDOE
OSTI Identifier:
1461266
Alternate Identifier(s):
OSTI ID: 1434147
Grant/Contract Number:  
[AC02-06CH11357]
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
[ Journal Volume: 6; Journal Issue: 17]; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalyst location; cobalt oxide; metal organic frameworks; oxidative dehydrogenation of propane; post-synthetic modification

Citation Formats

Buru, Cassandra T., Platero-Prats, Ana. E., Chica, Daniel G., Kanatzidis, Mercouri G., Chapman, Karena W., and Farha, Omar K. Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects. United States: N. p., 2018. Web. doi:10.1039/c8ta02562b.
Buru, Cassandra T., Platero-Prats, Ana. E., Chica, Daniel G., Kanatzidis, Mercouri G., Chapman, Karena W., & Farha, Omar K. Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects. United States. doi:10.1039/c8ta02562b.
Buru, Cassandra T., Platero-Prats, Ana. E., Chica, Daniel G., Kanatzidis, Mercouri G., Chapman, Karena W., and Farha, Omar K. Thu . "Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects". United States. doi:10.1039/c8ta02562b. https://www.osti.gov/servlets/purl/1461266.
@article{osti_1461266,
title = {Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects},
author = {Buru, Cassandra T. and Platero-Prats, Ana. E. and Chica, Daniel G. and Kanatzidis, Mercouri G. and Chapman, Karena W. and Farha, Omar K.},
abstractNote = {A polyoxometalate supported by the metal–organic framework, NU-1000, undergoes migration from the mesopore to the micropore when heated.},
doi = {10.1039/c8ta02562b},
journal = {Journal of Materials Chemistry. A},
number = [17],
volume = [6],
place = {United States},
year = {2018},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 7 works
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Figures / Tables:

Figure 1 Figure 1: Structural representations (left) of the PW12@NU1000 previously published, also referred to as PW12@NU-1000-120°C. Structures of the corresponding POM [(PW12O40)3-], MOF node [(Zr63-O)43-OH)4(H2O)4(OH)4)8+], and MOF linker [1,3,6,8-tetrakis(p-benzoate)pyrene, (TBAPy)4-] given (right). Light blue prisms=WO5, pink prisms=PO4, green=Zr, red=O, gray=C, hydrogen atoms omitted for clarity.

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