Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects
Abstract
A polyoxometalate supported by the metal–organic framework, NU-1000, undergoes migration from the mesopore to the micropore when heated.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- U.S. Department of Defense (DOD) - Defense Threat Reduction Agency (DTRA); National Science Foundation (NSF); USDOE
- OSTI Identifier:
- 1461266
- Alternate Identifier(s):
- OSTI ID: 1434147
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 17; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalyst location; cobalt oxide; metal organic frameworks; oxidative dehydrogenation of propane; post-synthetic modification
Citation Formats
Buru, Cassandra T., Platero-Prats, Ana. E., Chica, Daniel G., Kanatzidis, Mercouri G., Chapman, Karena W., and Farha, Omar K. Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects. United States: N. p., 2018.
Web. doi:10.1039/c8ta02562b.
Buru, Cassandra T., Platero-Prats, Ana. E., Chica, Daniel G., Kanatzidis, Mercouri G., Chapman, Karena W., & Farha, Omar K. Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects. United States. https://doi.org/10.1039/c8ta02562b
Buru, Cassandra T., Platero-Prats, Ana. E., Chica, Daniel G., Kanatzidis, Mercouri G., Chapman, Karena W., and Farha, Omar K. Thu .
"Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects". United States. https://doi.org/10.1039/c8ta02562b. https://www.osti.gov/servlets/purl/1461266.
@article{osti_1461266,
title = {Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects},
author = {Buru, Cassandra T. and Platero-Prats, Ana. E. and Chica, Daniel G. and Kanatzidis, Mercouri G. and Chapman, Karena W. and Farha, Omar K.},
abstractNote = {A polyoxometalate supported by the metal–organic framework, NU-1000, undergoes migration from the mesopore to the micropore when heated.},
doi = {10.1039/c8ta02562b},
journal = {Journal of Materials Chemistry. A},
number = 17,
volume = 6,
place = {United States},
year = {Thu Apr 19 00:00:00 EDT 2018},
month = {Thu Apr 19 00:00:00 EDT 2018}
}
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Cited by: 63 works
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Figures / Tables:
Figure 1: Structural representations (left) of the PW12@NU1000 previously published, also referred to as PW12@NU-1000-120°C. Structures of the corresponding POM [(PW12O40)3-], MOF node [(Zr6(µ3-O)4(µ3-OH)4(H2O)4(OH)4)8+], and MOF linker [1,3,6,8-tetrakis(p-benzoate)pyrene, (TBAPy)4-] given (right). Light blue prisms=WO5, pink prisms=PO4, green=Zr, red=O, gray=C, hydrogen atoms omitted for clarity.
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