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Title: High-Capacity Poly(4-vinylpyridine) Grafted PolyHIPE Foams for Efficient Plutonium Separation and Purification

Journal Article · · ACS Omega
ORCiD logo [1]; ORCiD logo [2];  [2]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, University of South Carolina, 541 Main Street, Horizon I Building, Columbia, South Carolina 29208, United States
  2. Environmental Stewardship, Savannah River National Laboratory, Savannah River Site, Building 773-A, Aiken, South Carolina 29808, United States

Not Available

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC09-08SR22470
OSTI ID:
1461245
Journal Information:
ACS Omega, Journal Name: ACS Omega Journal Issue: 7 Vol. 3; ISSN 2470-1343
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (36)

Architectural Control in“Living” Free Radical Polymerizations: Preparation of Star and Graft Polymers journal July 1995
Surface modification of monolithic PolyHIPE Polymers for anionic functionality and their ion exchange behavior journal April 2015
Using process intensification in the actinide processing industry journal January 2003
Ion-exchange macroporous hydrophilic gel monolith with grafted polymer brushes journal January 2006
Open-celled polymeric foam monoliths for heavy metal separations study journal September 1998
One-pot interfacial polymerization to prepare PolyHIPEs with functional surface journal March 2015
Preparation and characterisation of poly(high internal phase emulsion) methacrylate monoliths and their application as separation media journal February 2005
Separation of heavy metals from water by functionalized glycidyl methacrylate poly (high internal phase emulsions) journal March 2016
Synthesis and cation exchange properties of a new porous cation exchange resin having an open-celled monolith structure journal January 2004
Poly(4-vinylpyridine) polyHIPEs as catalysts for cycloaddition click reaction journal September 2017
Surface-initiated reversible addition-fragmentation chain transfer polymerization of chloroprene and mechanical properties of matrix-free polychloroprene nanocomposites journal January 2018
PolyHIPEs: Recent advances in emulsion-templated porous polymers journal January 2014
A continuous-flow electrophile scavenger prepared by a simple grafting procedure journal July 2010
Atrazine removal by covalent bonding to piperazine functionalized PolyHIPEs journal November 2007
Preparation of high loading PolyHIPE monoliths as scavengers for organic chemistry journal October 2003
Carbamoylmethylphosphine Oxide-Functionalized MIL-101(Cr) as Highly Selective Uranium Adsorbent journal May 2017
Photoinitiated Polymerization of 4-Vinylpyridine on polyHIPE Foam Surface toward Improved Pu Separations journal April 2017
Engineering the Surface Properties of Poly(dimethylsiloxane) Utilizing Aqueous RAFT Photografting of Acrylate/Methacrylate Monomers journal January 2018
Hybrid Inorganic−Organic Adsorbents Part 1: Synthesis and Characterization of Mesoporous Zirconium Titanate Frameworks Containing Coordinating Organic Functionalities journal November 2010
Hydrolytic Stability of Mesoporous Zirconium Titanate Frameworks Containing Coordinating Organic Functionalities journal May 2013
Selective Sorption of Actinides by Titania Nanoparticles Covalently Functionalized with Simple Organic Ligands journal November 2013
Chemistry of Diglycolamides: Promising Extractants for Actinide Partitioning journal November 2011
Application of a Macroporous Silica-Based CMPO-Impregnated Polymeric Composite in Group Partitioning of Long-Lived Minor Actinides from Highly Active Liquid by Extraction Chromatography journal July 2008
Molecular Weight Control by a "Living" Free-Radical Polymerization Process journal November 1994
Preparation of Hyperbranched and Star Polymers by a "Living", Self-Condensing Free Radical Polymerization journal November 1995
Emulsion stability and rigid foams from styrene or divinylbenzene water-in-oil emulsions journal February 1990
Surface-Initiated Reversible Addition–Fragmentation Chain Transfer (RAFT) Polymerization from Fine Particles Functionalized with Trithiocarbonates journal November 2011
Cellulose grafting by photoinduced controlled radical polymerisation journal January 2015
Supermacroporous polyHIPE and cryogel monolithic materials as stationary phases in separation science: a review journal January 2015
Rasta Resin-PPh3 and its Use in Chromatography-Free Wittig Reactions journal July 2010
REILLEX TM HPQ: A NEW, MACROPOROUS POLYVINYLPYRIDINE RESIN FOR SEPARATING PLUTONIUM USING NITRATE ANION EXCHANGE journal January 1989
Solvent Extraction and Extraction Chromatographic Separation of Am 3+ and Eu 3+ from Nitrate Medium using Cyanex ® 301 journal March 2007
Functionalized PolyHIPE polymer monoliths as an anion-exchange media for removal of nitrate ions from aqueous solutions journal April 2016
Plutonium(IV) sorption by soluble anion-exchange polymers journal March 2002
Sorption recovery of U(VI), Pu(IV), and Am(III) from nitric acid solutions with solid-phase extractants based on Taunit carbon nanotubes and polystyrene supports journal January 2014
Preparation and Characterization of Polyester–Glycidyl Methacrylate PolyHIPE Monoliths to Use in Heavy Metal Removal journal January 2012

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