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Title: Approaches for Achieving Superlubricity in Two-Dimensional Materials

Abstract

Controlling friction and reducing wear of moving mechanical systems is important in many applications, from nanoscale electromechanical systems to large-scale car engines and wind turbines. Accordingly, multiple efforts are dedicated to design materials and surfaces for efficient friction and wear manipulation. Recent advances in two-dimensional (2D) materials, such as graphene, hexagonal boron nitride, molybdenum disulfide, and other 2D materials opened an era for conformal, atomically thin solid lubricants. However, the process of effectively incorporating 2D films requires a fundamental understanding of the atomistic origins of friction. In this review, we outline basic mechanisms for frictional energy dissipation during sliding of two surfaces against each other, and the procedures for manipulating friction and wear by introducing 2D materials at the tribological interface. Lastly, we highlight recent progress in implementing 2D materials for friction reduction to near-zero values-superlubricity-across scales from nano- up to macroscale contacts.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2]
  1. Univ. of North Texas, Denton, TX (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1461198
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ACS Nano
Additional Journal Information:
Journal Volume: 12; Journal Issue: 3; Journal ID: ISSN 1936-0851
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 2D materials; energy dissipation; friction; graphene; macroscale; nanoscale; sliding interfaces; solid lubricants; superlubricity; wear

Citation Formats

Berman, Diana, Erdemir, Ali, and Sumant, Anirudha V. Approaches for Achieving Superlubricity in Two-Dimensional Materials. United States: N. p., 2018. Web. https://doi.org/10.1021/acsnano.7b09046.
Berman, Diana, Erdemir, Ali, & Sumant, Anirudha V. Approaches for Achieving Superlubricity in Two-Dimensional Materials. United States. https://doi.org/10.1021/acsnano.7b09046
Berman, Diana, Erdemir, Ali, and Sumant, Anirudha V. Fri . "Approaches for Achieving Superlubricity in Two-Dimensional Materials". United States. https://doi.org/10.1021/acsnano.7b09046. https://www.osti.gov/servlets/purl/1461198.
@article{osti_1461198,
title = {Approaches for Achieving Superlubricity in Two-Dimensional Materials},
author = {Berman, Diana and Erdemir, Ali and Sumant, Anirudha V.},
abstractNote = {Controlling friction and reducing wear of moving mechanical systems is important in many applications, from nanoscale electromechanical systems to large-scale car engines and wind turbines. Accordingly, multiple efforts are dedicated to design materials and surfaces for efficient friction and wear manipulation. Recent advances in two-dimensional (2D) materials, such as graphene, hexagonal boron nitride, molybdenum disulfide, and other 2D materials opened an era for conformal, atomically thin solid lubricants. However, the process of effectively incorporating 2D films requires a fundamental understanding of the atomistic origins of friction. In this review, we outline basic mechanisms for frictional energy dissipation during sliding of two surfaces against each other, and the procedures for manipulating friction and wear by introducing 2D materials at the tribological interface. Lastly, we highlight recent progress in implementing 2D materials for friction reduction to near-zero values-superlubricity-across scales from nano- up to macroscale contacts.},
doi = {10.1021/acsnano.7b09046},
journal = {ACS Nano},
number = 3,
volume = 12,
place = {United States},
year = {2018},
month = {3}
}

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Cited by: 30 works
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Figures / Tables:

Figure 1 Figure 1: Representative schematics of possible mechanisms for energy dissipation during sliding: (a) wear, (b) molecular deformation, (c) thermal effect, (d) electronic effect, (e) bonding, (f) phonons, (g) environment/chemistry, and (h) structural effect. All of these mechanisms are discussed further in this paper.

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Works referencing / citing this record:

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journal, January 2018

  • Vanossi, Andrea; Dietzel, Dirk; Schirmeisen, Andre
  • Beilstein Journal of Nanotechnology, Vol. 9
  • DOI: 10.3762/bjnano.9.190

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  • Vanossi, Andrea; Dietzel, Dirk; Schirmeisen, Andre
  • Beilstein Journal of Nanotechnology, Vol. 9
  • DOI: 10.3762/bjnano.9.190

Nanomaterials in Superlubricity
journal, April 2019


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  • Berman, Diana; Mutyala, Kalyan C.; Srinivasan, Srilok
  • Advanced Materials Interfaces, Vol. 6, Issue 23
  • DOI: 10.1002/admi.201901416

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Tribovoltaic Effect on Metal–Semiconductor Interface for Direct‐Current Low‐Impedance Triboelectric Nanogenerators
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  • Zhang, Zhi; Jiang, Dongdong; Zhao, Junqing
  • Advanced Energy Materials, Vol. 10, Issue 9
  • DOI: 10.1002/aenm.201903713

Effect of atomic oxygen on corrosion and friction and wear behavior of polyimide composites
journal, August 2019

  • Duan, Chunjian; He, Ren; Li, Song
  • Journal of Applied Polymer Science, Vol. 137, Issue 10
  • DOI: 10.1002/app.48441

Structural Superlubricity Based on Crystalline Materials
journal, October 2019


DLC and Glycerol: Superlubricity in Rolling/Sliding Elastohydrodynamic Lubrication
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Effect of Water Incorporation on the Lubrication Characteristics of Synthetic Oils
journal, September 2019


Friction and wear property of lithium grease contained with copper oxide nanoparticles
journal, November 2019


Metal-containing nanomaterials as lubricant additives: State-of-the-art and future development
journal, March 2019


Nature-Guided Synthesis of Advanced Bio-Lubricants
journal, August 2019


Nanoindentation unidirectional sliding and lateral force microscopy: Evaluation of experimental techniques to measure friction at the nanoscale
journal, December 2018

  • Echeverrigaray, F. G.; Sales de Mello, S. R.; Boeira, C. D.
  • AIP Advances, Vol. 8, Issue 12
  • DOI: 10.1063/1.5047801

Emerging superlubricity: A review of the state of the art and perspectives on future research
journal, December 2018

  • Baykara, Mehmet Z.; Vazirisereshk, Mohammad R.; Martini, Ashlie
  • Applied Physics Reviews, Vol. 5, Issue 4
  • DOI: 10.1063/1.5051445

Negative Friction Coefficients in Superlubric Graphite–Hexagonal Boron Nitride Heterojunctions
journal, February 2019