Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy
Abstract
In this paper, we report on spectral intensity and group delay measurements of the highest-occupied molecular-orbital (HOMO) recombination dipole moment of $${\mathrm{N}}_{2}$$ in the molecular-frame using high harmonic spectroscopy. We take advantage of the long-wavelength $$1.3\text{ }\text{ }{\mu}\mathrm{m}$$ driving laser to isolate the HOMO in the near threshold region, 19–67 eV. Finally, the precision of our group delay measurements reveals previously unseen angle-resolved spectral features associated with autoionizing resonances, and allows quantitative comparison with cutting-edge correlated 8-channel photoionization dipole moment calculations.
- Authors:
-
- The Ohio State Univ., Columbus, OH (United States). Dept. of Physics
- Alternative Energies and Atomic Energy Commission (CEA), Saclay (France). Interactions, Dynamics and Lasers Lab. (LIDYL)
- Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Center for Scientific Research (CNRS) International Project of Scientific Cooperation (PICS) (France)
- OSTI Identifier:
- 1461115
- Alternate Identifier(s):
- OSTI ID: 1341314
- Grant/Contract Number:
- FG02-04ER15614; FG02-06ER15833; 5460
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Letters
- Additional Journal Information:
- Journal Volume: 118; Journal Issue: 3; Journal ID: ISSN 0031-9007
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 74 ATOMIC AND MOLECULAR PHYSICS; electronic structure of atoms & molecules; high-order harmonic generation
Citation Formats
Schoun, S. B., Camper, A., Salieres, P., Lucchese, R. R., Agostini, P., and DiMauro, L. F. Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy. United States: N. p., 2017.
Web. doi:10.1103/PhysRevLett.118.033201.
Schoun, S. B., Camper, A., Salieres, P., Lucchese, R. R., Agostini, P., & DiMauro, L. F. Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy. United States. https://doi.org/10.1103/PhysRevLett.118.033201
Schoun, S. B., Camper, A., Salieres, P., Lucchese, R. R., Agostini, P., and DiMauro, L. F. Thu .
"Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy". United States. https://doi.org/10.1103/PhysRevLett.118.033201. https://www.osti.gov/servlets/purl/1461115.
@article{osti_1461115,
title = {Precise Access to the Molecular-Frame Complex Recombination Dipole through High-Harmonic Spectroscopy},
author = {Schoun, S. B. and Camper, A. and Salieres, P. and Lucchese, R. R. and Agostini, P. and DiMauro, L. F.},
abstractNote = {In this paper, we report on spectral intensity and group delay measurements of the highest-occupied molecular-orbital (HOMO) recombination dipole moment of ${\mathrm{N}}_{2}$ in the molecular-frame using high harmonic spectroscopy. We take advantage of the long-wavelength $1.3\text{ }\text{ }{\mu}\mathrm{m}$ driving laser to isolate the HOMO in the near threshold region, 19–67 eV. Finally, the precision of our group delay measurements reveals previously unseen angle-resolved spectral features associated with autoionizing resonances, and allows quantitative comparison with cutting-edge correlated 8-channel photoionization dipole moment calculations.},
doi = {10.1103/PhysRevLett.118.033201},
journal = {Physical Review Letters},
number = 3,
volume = 118,
place = {United States},
year = {Thu Jan 19 00:00:00 EST 2017},
month = {Thu Jan 19 00:00:00 EST 2017}
}
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