Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: High order harmonic generation from SF6: Deconvolution of macroscopic effects

Abstract

In this paper, we measure high order harmonics from the molecule SF6 over a large range of phase matching conditions and observe several features in the harmonics that are largely independent of such macroscopic conditions. The experimental data are then compared to the quantitative rescattering theory for the generation of harmonics from three orbitals. Finally, with this comparison, we are able to assign spectroscopic features in the harmonics to contributions from 1t1g (HOMO) and 5t1u (HOMO-1) orbitals.

Authors:
 [1]; ORCiD logo [1];  [2];  [2];  [2]; ORCiD logo [1];  [3];  [2]; ORCiD logo [4];  [2]
+ Show Author Affiliations
  1. Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Chemistry
  2. Kansas State Univ., Manhattan, KS (United States). J.R. Macdonald Lab.
  3. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; Indian Inst. of Technology Patna (IITP), Bihta (India). Dept. of Physics
  4. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); Robert A. Welch Foundation (United States)
OSTI Identifier:
1461112
Alternate Identifier(s):
OSTI ID: 1335708
Grant/Contract Number:  
SC0012198; FG02-86ER13491; A-1020
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 145; Journal Issue: 22; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; focal points; ionization; tunneling; photoionization; photons; optical coherence; fluid jets; atomic spectra; molecular spectra; orbital dynamics

Citation Formats

Wilson, B. P., Fulfer, K. D., Mondal, S., Ren, X., Tross, J., Poliakoff, E. D., Jose, J., Le, Anh-Thu, Lucchese, R. R., and Trallero-Herrero, C. High order harmonic generation from SF6: Deconvolution of macroscopic effects. United States: N. p., 2016. Web. doi:10.1063/1.4971244.
Copy to clipboard
Wilson, B. P., Fulfer, K. D., Mondal, S., Ren, X., Tross, J., Poliakoff, E. D., Jose, J., Le, Anh-Thu, Lucchese, R. R., & Trallero-Herrero, C. High order harmonic generation from SF6: Deconvolution of macroscopic effects. United States. https://doi.org/10.1063/1.4971244
Copy to clipboard
Wilson, B. P., Fulfer, K. D., Mondal, S., Ren, X., Tross, J., Poliakoff, E. D., Jose, J., Le, Anh-Thu, Lucchese, R. R., and Trallero-Herrero, C. Tue . "High order harmonic generation from SF6: Deconvolution of macroscopic effects". United States. https://doi.org/10.1063/1.4971244. https://www.osti.gov/servlets/purl/1461112.
Copy to clipboard
@article{osti_1461112,
title = {High order harmonic generation from SF6: Deconvolution of macroscopic effects},
author = {Wilson, B. P. and Fulfer, K. D. and Mondal, S. and Ren, X. and Tross, J. and Poliakoff, E. D. and Jose, J. and Le, Anh-Thu and Lucchese, R. R. and Trallero-Herrero, C.},
abstractNote = {In this paper, we measure high order harmonics from the molecule SF6 over a large range of phase matching conditions and observe several features in the harmonics that are largely independent of such macroscopic conditions. The experimental data are then compared to the quantitative rescattering theory for the generation of harmonics from three orbitals. Finally, with this comparison, we are able to assign spectroscopic features in the harmonics to contributions from 1t1g (HOMO) and 5t1u (HOMO-1) orbitals.},
doi = {10.1063/1.4971244},
journal = {Journal of Chemical Physics},
number = 22,
volume = 145,
place = {United States},
year = {Tue Dec 13 00:00:00 EST 2016},
month = {Tue Dec 13 00:00:00 EST 2016}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1063/1.4971244
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Cross section and asymmetry parameter calculation for sulfur 1s photoionization of SF6
journal, September 1999

  • Natalense, Alexandra P. P.; Lucchese, Robert R.
  • The Journal of Chemical Physics, Vol. 111, Issue 12
  • DOI: 10.1063/1.479794

Effects of phase-matching on high-order harmonic generation from aligned N 2
journal, September 2009

High-order-harmonic generation from molecular isomers with midinfrared intense laser pulses
journal, August 2013

Theoretical studies of high-order harmonic generation: Effects of symmetry, degeneracy, and orientation
journal, October 2007

Retrieving photorecombination cross sections of atoms from high-order harmonic spectra
journal, December 2008

The angular distribution of the 3p electrons and the partial cross section of the 3s electrons of argon from threshold to 70 eV
journal, January 1976

  • Houlgate, R. G.; West, J. B.; Codling, K.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 9, Issue 2
  • DOI: 10.1016/0368-2048(76)81030-4

Influence of phase matching on the Cooper minimum in Ar high-order harmonic spectra
journal, February 2011

Interchannel coupling effects in the valence photoionization of SF 6
journal, May 2014

  • Jose, J.; Lucchese, R. R.; Rescigno, T. N.
  • The Journal of Chemical Physics, Vol. 140, Issue 20
  • DOI: 10.1063/1.4876576

Universality of Returning Electron Wave Packet in High-Order Harmonic Generation with Midinfrared Laser Pulses
journal, July 2014

Above threshold ionization beyond the high harmonic cutoff
journal, March 1993

Threshold photoelectron spectroscopy of SF6
journal, March 1997

Harnessing Attosecond Science in the Quest for Coherent X-rays
journal, August 2007

Separation of target structure and medium propagation effects in high-harmonic generation
journal, April 2011

  • Jin, Cheng; Wörner, Hans Jakob; Tosa, V.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 44, Issue 9
  • DOI: 10.1088/0953-4075/44/9/095601

Measurement and laser control of attosecond charge migration in ionized iodoacetylene
journal, October 2015

Strong-field rescattering physics—self-imaging of a molecule by its own electrons
journal, June 2010

  • Lin, C. D.; Le, Anh-Thu; Chen, Zhangjin
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 43, Issue 12
  • DOI: 10.1088/0953-4075/43/12/122001

Self-probing of molecules with high harmonic generation
journal, September 2011

  • Haessler, S.; Caillat, J.; Salières, P.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 44, Issue 20
  • DOI: 10.1088/0953-4075/44/20/203001

One-electron resonances in electron scattering from polyatomic molecules
journal, September 1996

  • Lucchese, Robert R.; Gianturco, F. A.
  • International Reviews in Physical Chemistry, Vol. 15, Issue 2
  • DOI: 10.1080/01442359609353190

Generation of broad XUV continuous high harmonic spectra and isolated attosecond pulses with intense mid-infrared lasers
journal, December 2011

  • Trallero-Herrero, C.; Jin, Cheng; Schmidt, B. E.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 45, Issue 1
  • DOI: 10.1088/0953-4075/45/1/011001

Continuum basis functions in the complex Kohn variational method
journal, February 1991

Macroscopic aspects of attosecond pulse generation
journal, June 2008

  • Gaarde, Mette B.; Tate, Jennifer L.; Schafer, Kenneth J.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 41, Issue 13
  • DOI: 10.1088/0953-4075/41/13/132001

Time dependent density functional study of the photoionization dynamics of SF6
journal, March 2006

  • Stener, M.; Toffoli, D.; Fronzoni, G.
  • The Journal of Chemical Physics, Vol. 124, Issue 11
  • DOI: 10.1063/1.2178799

Precision measurements of the total photoionization cross-sections of He, Ne, Ar, Kr, and Xe
journal, May 2002

An experimental and theoretical study of the valence shell photoelectron spectrum of sulphur hexafluoride
journal, March 1995

Self-Probing Spectroscopy of the SF 6 Molecule: A Study of the Spectral Amplitude and Phase of the High Harmonic Emission
journal, November 2014

  • Manschwetus, Bastian; Lin, Nan; Rothhardt, Jan
  • The Journal of Physical Chemistry A, Vol. 119, Issue 23
  • DOI: 10.1021/acs.jpca.5b00446

Spatiotemporal separation of high harmonic radiation into two quantum path components
journal, February 1999

High harmonic generation in SF 6 : Raman-excited vibrational quantum beats
journal, September 2007

  • Walters, Zachary B.; Tonzani, Stefano; Greene, Chris H.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 40, Issue 18
  • DOI: 10.1088/0953-4075/40/18/F01

A comparison of valence level photoelectron cross sections for SF6, SeF6 and “F6” from 21 eV to 100 eV photon energy
journal, January 1989

  • Addison-Jones, B. M.; Tan, K. H.; Yates, B. W.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 48, Issue 1
  • DOI: 10.1016/0368-2048(89)80013-1

Calculation of low‐energy elastic cross sections for electron‐CF 4 scattering
journal, May 1994

  • Gianturco, F. A.; Lucchese, R. R.; Sanna, N.
  • The Journal of Chemical Physics, Vol. 100, Issue 9
  • DOI: 10.1063/1.467237

High-harmonic spectroscopy of isoelectronic molecules: Wavelength scaling of electronic-structure and multielectron effects
journal, March 2013

Phase matching of high harmonic generation in the soft and hard X-ray regions of the spectrum
journal, June 2009

  • Popmintchev, T.; Chen, M. -C.; Bahabad, A.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 26
  • DOI: 10.1073/pnas.0903748106

High-order harmonic generation in the presence of a resonance
journal, July 2011

Vibrational effects in the shape resonant photoionization leading to the A2T1 state of SF 6 +
journal, February 2015

Medium propagation effects in high-order harmonic generation of Ar and N 2
journal, February 2011

Monitoring molecular dynamics using coherent electrons from high harmonic generation
journal, August 2006

  • Wagner, N. L.; Wuest, A.; Christov, I. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 36
  • DOI: 10.1073/pnas.0605178103

Attosecond physics
journal, February 2009

Probing Proton Dynamics in Molecules on an Attosecond Time Scale
journal, March 2006

Plasma perspective on strong field multiphoton ionization
journal, September 1993

Coherence Control of High-Order Harmonics
journal, May 1995

Attosecond metrology
journal, November 2001

  • Hentschel, M.; Kienberger, R.; Spielmann, Ch.
  • Nature, Vol. 414, Issue 6863, p. 509-513
  • DOI: 10.1038/35107000

Probing collective multi-electron dynamics in xenon with high-harmonic spectroscopy
journal, March 2011

  • Shiner, A. D.; Schmidt, B. E.; Trallero-Herrero, C.
  • Nature Physics, Vol. 7, Issue 6
  • DOI: 10.1038/nphys1940

Multi-channel electronic and vibrational dynamics in polyatomic resonant high-order harmonic generation
journal, January 2015

  • Ferré, A.; Boguslavskiy, A. E.; Dagan, M.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms6952

Photoelectron branching ratios and angular distributions for the valence levels of S F 6 in the range 16 ≤ h ν ≤ 30 eV
journal, December 1982

Energy-dependent valence photoelectron spectra of SF6. Ab initio calculations and measurements
journal, June 1998

  • Yang, Li; Ågren, Hans; Carravetta, Vincenzo
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 94, Issue 1-2
  • DOI: 10.1016/S0368-2048(98)00085-1

High-order harmonic spectroscopy of the Cooper minimum in argon: Experimental and theoretical study
journal, May 2011

    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: