Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons

Nguyen, Giang D.; Toma, Francesca M.; Cao, Ting; Pedramrazi, Zahra; Chen, Chen; Rizzo, Daniel J.; Joshi, Trinity; Bronner, Christopher; Chen, Yen-Chia; Favaro, Marco; Louie, Steven G.; Fischer, Felix R.; Crommie, Michael F.

doi:10.1021/acs.jpcc.5b09986

Title: Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons

Abstract

Substitutional doping of graphene nanoribbons (GNRs) with heteroatoms is a principal strategy to fine-tune the electronic structure of GNRs for future device applications. In this paper, we report the fabrication and nanoscale characterization of atomically precise N = 13 armchair GNRs featuring regioregular edge-doping with sulfur atoms (S-13-AGNRs) on a Au(111) surface. Finally, scanning tunneling spectroscopy and first-principle calculations reveal modification of the electronic structure of S-13-AGNRs when compared to undoped N = 13 AGNRs.

Authors:

Nguyen, Giang D. ^[1]; Toma, Francesca M. ^[2]; Cao, Ting ^[1]; Pedramrazi, Zahra ^[1]; Chen, Chen ^[2]; Rizzo, Daniel J. ^[1]; Joshi, Trinity ^[1]; Bronner, Christopher ^[1]; Chen, Yen-Chia ^[1]; Favaro, Marco ^[3]; Louie, Steven G. ^[4]; Fischer, Felix R. ^[5]; Crommie, Michael F. ^[4]

Univ. of California, Berkeley, CA (United States). Dept. of Physics
Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
Univ. of California, Berkeley, CA (United States). Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division

Publication Date:: Wed Jan 20 00:00:00 EST 2016

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Office of Naval Research (ONR) (United States); National Science Foundation (NSF); German National Academy of Sciences Leopoldina

OSTI Identifier:: 1461105

Grant/Contract Number:: AC02-05CH11231; SC0010409; DMR-1206512; DMR15-1508412; DGE 1106400; LPDS 2014-09

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physical Chemistry. C

Additional Journal Information:: Journal Volume: 120; Journal Issue: 5; Journal ID: ISSN 1932-7447

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Nguyen, Giang D., Toma, Francesca M., Cao, Ting, Pedramrazi, Zahra, Chen, Chen, Rizzo, Daniel J., Joshi, Trinity, Bronner, Christopher, Chen, Yen-Chia, Favaro, Marco, Louie, Steven G., Fischer, Felix R., and Crommie, Michael F. Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.jpcc.5b09986.

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                    Nguyen, Giang D., Toma, Francesca M., Cao, Ting, Pedramrazi, Zahra, Chen, Chen, Rizzo, Daniel J., Joshi, Trinity, Bronner, Christopher, Chen, Yen-Chia, Favaro, Marco, Louie, Steven G., Fischer, Felix R., & Crommie, Michael F. Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons.  United States.  https://doi.org/10.1021/acs.jpcc.5b09986

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                    Nguyen, Giang D., Toma, Francesca M., Cao, Ting, Pedramrazi, Zahra, Chen, Chen, Rizzo, Daniel J., Joshi, Trinity, Bronner, Christopher, Chen, Yen-Chia, Favaro, Marco, Louie, Steven G., Fischer, Felix R., and Crommie, Michael F. Wed .  
"Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons".  United States.  https://doi.org/10.1021/acs.jpcc.5b09986.  https://www.osti.gov/servlets/purl/1461105.

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@article{osti_1461105,

  title        = {Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons},

  author       = {Nguyen, Giang D. and Toma, Francesca M. and Cao, Ting and Pedramrazi, Zahra and Chen, Chen and Rizzo, Daniel J. and Joshi, Trinity and Bronner, Christopher and Chen, Yen-Chia and Favaro, Marco and Louie, Steven G. and Fischer, Felix R. and Crommie, Michael F.},

  abstractNote = {Substitutional doping of graphene nanoribbons (GNRs) with heteroatoms is a principal strategy to fine-tune the electronic structure of GNRs for future device applications. In this paper, we report the fabrication and nanoscale characterization of atomically precise N = 13 armchair GNRs featuring regioregular edge-doping with sulfur atoms (S-13-AGNRs) on a Au(111) surface. Finally, scanning tunneling spectroscopy and first-principle calculations reveal modification of the electronic structure of S-13-AGNRs when compared to undoped N = 13 AGNRs.},

  doi          = {10.1021/acs.jpcc.5b09986},

  journal      = {Journal of Physical Chemistry. C},

  number       = 5,

  volume       = 120,

  place        = {United States},

  year         = {Wed Jan 20 00:00:00 EST 2016},

  month        = {Wed Jan 20 00:00:00 EST 2016}

}

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Title: Bottom-Up Synthesis of N = 13 Sulfur-Doped Graphene Nanoribbons

Abstract

Citation Formats

Half-metallic graphene nanoribbons journal, November 2006

Spatially resolving edge states of chiral graphene nanoribbons journal, May 2011

Bottom-up graphene nanoribbon field-effect transistors journal, December 2013

Molecular bandgap engineering of bottom-up synthesized graphene nanoribbon heterojunctions journal, January 2015

Atomically precise bottom-up fabrication of graphene nanoribbons journal, July 2010

Graphene nanoribbon heterojunctions journal, September 2014

Energy Band-Gap Engineering of Graphene Nanoribbons journal, May 2007

Tuning the Band Gap of Graphene Nanoribbons Synthesized from Molecular Precursors journal, June 2013

Energy Gaps in Graphene Nanoribbons journal, November 2006

On-Surface Synthesis of Rylene-Type Graphene Nanoribbons journal, March 2015

Aligning the Band Gap of Graphene Nanoribbons by Monomer Doping journal, March 2013

Direct visualization of atomically precise nitrogen-doped graphene nanoribbons journal, July 2014

Site-Specific Substitutional Boron Doping of Semiconducting Armchair Graphene Nanoribbons journal, July 2015

Atomically controlled substitutional boron-doping of graphene nanoribbons journal, August 2015

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials journal, September 2009

Scanning Tunneling Microscopy Observation of an Electronic Superlattice at the Surface of Clean Gold journal, February 1998

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Half-metallic graphene nanoribbons
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Spatially resolving edge states of chiral graphene nanoribbons
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Bottom-up graphene nanoribbon field-effect transistors
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Molecular bandgap engineering of bottom-up synthesized graphene nanoribbon heterojunctions
journal, January 2015

Atomically precise bottom-up fabrication of graphene nanoribbons
journal, July 2010

Graphene nanoribbon heterojunctions
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Energy Band-Gap Engineering of Graphene Nanoribbons
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Tuning the Band Gap of Graphene Nanoribbons Synthesized from Molecular Precursors
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QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
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The art of two-dimensional soft nanomaterials
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Selective on-surface covalent coupling based on metal-organic coordination template
journal, January 2019

On‐Surface Synthesis of 8‐ and 10‐Armchair Graphene Nanoribbons
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On-surface synthesis of graphene clusters from a Z-bar-linkage precursor with quaterphenyl branches
journal, January 2018

Surface-mediated assembly, polymerization and degradation of thiophene-based monomers
journal, January 2019

Multiple heteroatom substitution to graphene nanoribbon
journal, April 2018

Covalent on-surface polymerization
journal, January 2020

Diacetylene Linked Anthracene Oligomers Synthesized by One-Shot Homocoupling of Trimethylsilyl on Cu(111)
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journal, March 2019

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journal, August 2016

Lateral Fusion of Chemical Vapor Deposited N = 5 Armchair Graphene Nanoribbons
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Width-Dependent Band Gap in Armchair Graphene Nanoribbons Reveals Fermi Level Pinning on Au(111)
text, January 2017