The Interfacial Assembly of Polyoxometalate Nanoparticle Surfactants

Huang, Caili; Chai, Yu; Jiang, Yufeng; Forth, Joe; Ashby, Paul D.; Arras, Matthias M. L.; Hong, Kunlun; Smith, Gregory S.; Yin, Panchao; Russell, Thomas P.

doi:10.1021/acs.nanolett.8b00208

Title: The Interfacial Assembly of Polyoxometalate Nanoparticle Surfactants

Journal Article · 20 March 2018 · Nano Letters

DOI: https://doi.org/10.1021/acs.nanolett.8b00208 · OSTI ID:1461058

^[1]; Chai, Yu ^[2]; Jiang, Yufeng ^[2]; Forth, Joe ^[2];

^[2];

^[3];

^[3]; Smith, Gregory S. ^[3];

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^[5]

Univ. of Massachusetts, Amherst, MA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
South China Univ. of Technology, Guangzhou (China)
Univ. of Massachusetts, Amherst, MA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Beijing Univ. of Chemical Technology, Beijing (China)

Polyoxometalates (POMs) using {Mo₇₂V₃₀} as an example, dissolved in water, can interact with amine-terminated polydimethylsiloxane (PDMS-NH₂) dissolved in toluene at the water/toluene interface to form POM-surfactants that significantly lower the interfacial tension and can be used to stabilize liquids via interfacial elasticity. The jamming of the POM-surfactants at the water/oil interface with consequent wrinkling occurs with a decrease in the interfacial area. Furthermore, the packing density of the POM-surfactants at the interface can be tuned by varying the strength of screening with the addition of cations with differing hydrated radii.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1461058

Journal Information:: Nano Letters, Journal Name: Nano Letters Journal Issue: 4 Vol. 18; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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