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Title: Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium

Abstract

The isostructural, two-dimensional metal–organic frameworks (H2NMe2)2M2(Cl2dhbq)3 (M = Ti, V; Cl2dhbqn- = deprotonated 2,5-dichloro-3,6-dihydroxybenzoquinone) and (H2NMe2)1.5Cr2(dhbq)3 (dhbqn- = deprotonated 2,5-dihydroxybenzoquinone) are synthesized and investigated by spectroscopic, magnetic, and electrochemical methods. The three frameworks exhibit substantial differences in their electronic structures, and the bulk electronic conductivities of these phases correlate with the extent of delocalization observed via UV–vis–NIR and IR spectroscopies. Notably, substantial metal–ligand covalency in the vanadium phase results in the quenching of ligand-based spins, the observation of simultaneous metal- and ligand-based redox processes, and a high electronic conductivity of 0.45 S/cm. In conclusion, a molecular orbital analysis of these materials and a previously reported iron congener suggests that the differences in conductivity can be explained by correlating the metal–ligand energy alignment with the energy of intervalence charge transfer transitions, which should determine the barrier to charge hopping in the mixed-valence frameworks.

Authors:
 [1];  [1]; ORCiD logo [2]
+ Show Author Affiliations
  1. Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
  2. Univ. of California, Berkeley, CA (United States). Dept. of Chemistry and Dept. of Chemical and Biomolecular Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
Publication Date:
Research Org.:
Univ. of Minnesota, Minneapolis, MN (United States). Nanoporous Materials Genome Center
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
OSTI Identifier:
1460997
Grant/Contract Number:  
SC0008688
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 140; Journal Issue: 8; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Ziebel, Michael E., Darago, Lucy E., and Long, Jeffrey R.. Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium. United States: N. p., 2018. Web. doi:10.1021/jacs.7b13510.
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Ziebel, Michael E., Darago, Lucy E., & Long, Jeffrey R.. Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium. United States. https://doi.org/10.1021/jacs.7b13510
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Ziebel, Michael E., Darago, Lucy E., and Long, Jeffrey R.. Mon . "Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium". United States. https://doi.org/10.1021/jacs.7b13510. https://www.osti.gov/servlets/purl/1460997.
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@article{osti_1460997,
title = {Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium},
author = {Ziebel, Michael E. and Darago, Lucy E. and Long, Jeffrey R.},
abstractNote = {The isostructural, two-dimensional metal–organic frameworks (H2NMe2)2M2(Cl2dhbq)3 (M = Ti, V; Cl2dhbqn- = deprotonated 2,5-dichloro-3,6-dihydroxybenzoquinone) and (H2NMe2)1.5Cr2(dhbq)3 (dhbqn- = deprotonated 2,5-dihydroxybenzoquinone) are synthesized and investigated by spectroscopic, magnetic, and electrochemical methods. The three frameworks exhibit substantial differences in their electronic structures, and the bulk electronic conductivities of these phases correlate with the extent of delocalization observed via UV–vis–NIR and IR spectroscopies. Notably, substantial metal–ligand covalency in the vanadium phase results in the quenching of ligand-based spins, the observation of simultaneous metal- and ligand-based redox processes, and a high electronic conductivity of 0.45 S/cm. In conclusion, a molecular orbital analysis of these materials and a previously reported iron congener suggests that the differences in conductivity can be explained by correlating the metal–ligand energy alignment with the energy of intervalence charge transfer transitions, which should determine the barrier to charge hopping in the mixed-valence frameworks.},
doi = {10.1021/jacs.7b13510},
journal = {Journal of the American Chemical Society},
number = 8,
volume = 140,
place = {United States},
year = {2018},
month = {2}
}
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https://doi.org/10.1021/jacs.7b13510
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Figures / Tables:

Scheme 1 Scheme 1: The redox states of the linker 2,5‐dihyroxybenzoquinone that have been observed in metal–organic complexes and materials.
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Works referenced in this record:

The pervasive chemistry of metal–organic frameworks
journal, January 2009

  • Long, Jeffrey R.; Yaghi, Omar M.
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1213-1214
  • DOI: 10.1039/b903811f

Metal–Organic Frameworks (MOFs)
journal, January 2014

  • Zhou, Hong-Cai “Joe”; Kitagawa, Susumu
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS90059F

Emerging Multifunctional Metal-Organic Framework Materials
journal, July 2016

Conductive metal–organic frameworks and networks: fact or fantasy?
journal, January 2012

  • Hendon, Christopher H.; Tiana, Davide; Walsh, Aron
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 38, p. 13120-13132
  • DOI: 10.1039/c2cp41099k

Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties
journal, April 2007

  • Férey, Gérard; Millange, Franck; Morcrette, Mathieu
  • Angewandte Chemie International Edition, Vol. 46, Issue 18
  • DOI: 10.1002/anie.200605163

Microporous magnets
journal, January 2011

  • Dechambenoit, Pierre; Long, Jeffrey R.
  • Chemical Society Reviews, Vol. 40, Issue 6
  • DOI: 10.1039/c0cs00167h

Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity
journal, April 2015

  • Erickson, Kristopher J.; Léonard, François; Stavila, Vitalie
  • Advanced Materials, Vol. 27, Issue 22
  • DOI: 10.1002/adma.201501078

Cu 3 (hexaiminotriphenylene) 2 : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing
journal, February 2015

  • Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F.
  • Angewandte Chemie International Edition, Vol. 54, Issue 14
  • DOI: 10.1002/anie.201411854

Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks
journal, October 2015

  • Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M.
  • Journal of the American Chemical Society, Vol. 137, Issue 43
  • DOI: 10.1021/jacs.5b09600

Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016

  • Sun, Lei; Campbell, Michael G.; Dincă, Mircea
  • Angewandte Chemie International Edition, Vol. 55, Issue 11
  • DOI: 10.1002/anie.201506219

High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012

  • Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 134, Issue 31
  • DOI: 10.1021/ja3059827

New Porous Crystals of Extended Metal-Catecholates
journal, August 2012

  • Hmadeh, Mohamad; Lu, Zheng; Liu, Zheng
  • Chemistry of Materials, Vol. 24, Issue 18, p. 3511-3513
  • DOI: 10.1021/cm301194a

Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) ∞ Chains and High Intrinsic Charge Mobility
journal, May 2013

  • Sun, Lei; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 135, Issue 22
  • DOI: 10.1021/ja4037516

π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet
journal, February 2013

  • Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken
  • Journal of the American Chemical Society, Vol. 135, Issue 7
  • DOI: 10.1021/ja312380b

High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013

  • Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
  • Science, Vol. 343, Issue 6166, p. 66-69
  • DOI: 10.1126/science.1246738

Million-Fold Electrical Conductivity Enhancement in Fe 2 (DEBDC) versus Mn 2 (DEBDC) (E = S, O)
journal, May 2015

  • Sun, Lei; Hendon, Christopher H.; Minier, Mikael A.
  • Journal of the American Chemical Society, Vol. 137, Issue 19
  • DOI: 10.1021/jacs.5b02897

A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
journal, June 2015

  • Huang, Xing; Sheng, Peng; Tu, Zeyi
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8408

Electrical conductivity and electroluminescence of a new anthracene-based metal–organic framework with π-conjugated zigzag chains
journal, January 2016

  • Chen, Dashu; Xing, Hongzhu; Su, Zhongmin
  • Chemical Communications, Vol. 52, Issue 10
  • DOI: 10.1039/C5CC09065B

Electroconductive Porous Coordination Polymer Cu[Cu(pdt) 2 ] Composed of Donor and Acceptor Building Units
journal, October 2009

  • Takaishi, Shinya; Hosoda, Miyuki; Kajiwara, Takashi
  • Inorganic Chemistry, Vol. 48, Issue 19
  • DOI: 10.1021/ic802117q

Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
journal, July 2010

  • Kobayashi, Yoji; Jacobs, Benjamin; Allendorf, Mark D.
  • Chemistry of Materials, Vol. 22, Issue 14
  • DOI: 10.1021/cm101238m

Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012

  • Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K.
  • Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601
  • DOI: 10.1002/chem.201103433

Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator
journal, October 2014

  • Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro
  • Journal of the American Chemical Society, Vol. 136, Issue 41
  • DOI: 10.1021/ja507619d

A Dual−Ion Battery Cathode via Oxidative Insertion of Anions in a Metal–Organic Framework
journal, October 2015

  • Aubrey, Michael L.; Long, Jeffrey R.
  • Journal of the American Chemical Society, Vol. 137, Issue 42
  • DOI: 10.1021/jacs.5b08022

Is iron unique in promoting electrical conductivity in MOFs?
journal, January 2017

  • Sun, Lei; Hendon, Christopher H.; Park, Sarah S.
  • Chemical Science, Vol. 8, Issue 6
  • DOI: 10.1039/C7SC00647K

Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015

  • Park, Sarah S.; Hontz, Eric R.; Sun, Lei
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja512437u

Electrical switching and memory phenomena in Cu‐TCNQ thin films
journal, March 1979

  • Potember, R. S.; Poehler, T. O.; Cowan, D. O.
  • Applied Physics Letters, Vol. 34, Issue 6
  • DOI: 10.1063/1.90814

Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane:  M(TCNQ) 2 (M = Mn, Fe, Co, Ni) †
journal, May 2003

  • Clérac, Rodolphe; O'Kane, Shannon; Cowen, Jerry
  • Chemistry of Materials, Vol. 15, Issue 9
  • DOI: 10.1021/cm021053d

Transition metal complexes of o-benzoquinone, o-semiquinone, and catecholate ligands
journal, August 1981

Noninnocence in Metal Complexes: A Dithiolene Dawn
journal, October 2011

  • Eisenberg, Richard; Gray, Harry B.
  • Inorganic Chemistry, Vol. 50, Issue 20
  • DOI: 10.1021/ic2011748

Superexchange metal-metal coupling in dinuclear pentaammineruthenium complexes incorporating a 1,4-dicyanamidobenzene dianion bridging ligand
journal, June 1992

  • Aquino, M. A. S.; Lee, F. L.; Gabe, E. J.
  • Journal of the American Chemical Society, Vol. 114, Issue 13
  • DOI: 10.1021/ja00039a026

Tetraoxolene radical stabilization by the interaction with transition-metal ions
journal, June 1991

  • Dei, Andrea.; Gatteschi, Dante.; Pardi, Luca.
  • Inorganic Chemistry, Vol. 30, Issue 12
  • DOI: 10.1021/ic00012a006

Variable Coordination Mode of Chloranilic Acid. Synthesis, Structure, and Electrochemical Properties of Some Osmium Complexes
journal, March 2005

  • Gupta, Parna; Das, Anindya; Basuli, Falguni
  • Inorganic Chemistry, Vol. 44, Issue 6
  • DOI: 10.1021/ic049149s

Monometallic Lanthanoid Assembly Showing Ferromagnetism with a Curie Temperature of 11 K
journal, September 2009

  • Nakabayashi, Koji; Ohkoshi, Shin-ichi
  • Inorganic Chemistry, Vol. 48, Issue 18
  • DOI: 10.1021/ic900625a

A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T c = 26 to 80 K
journal, December 2015

  • Jeon, Ie-Rang; Negru, Bogdan; Van Duyne, Richard P.
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10382

Multistep redox series of the tris(o-semiquinone)chromium(III) complexes
journal, July 1979

  • Downs, Hartley H.; Buchanan, Robert M.; Pierpont, Cortlandt G.
  • Inorganic Chemistry, Vol. 18, Issue 7
  • DOI: 10.1021/ic50197a003

Theoretical study of o-quinone complexes of chromium and vanadium
journal, August 1982

  • Gordon, Douglas J.; Fenske, Richard F.
  • Inorganic Chemistry, Vol. 21, Issue 8
  • DOI: 10.1021/ic00138a001

Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+)
journal, December 1986

  • Weiss, Armin; Riegler, Eugen; Robl, Christian
  • Zeitschrift für Naturforschung B, Vol. 41, Issue 12
  • DOI: 10.1515/znb-1986-1204

A Novel Hybrid Supramolecular Network Assembled from Perfect ??? Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer
journal, November 2004

  • Luo, Tzuoo-Tsair; Liu, Yen-Hsiang; Tsai, Hui-Lien
  • European Journal of Inorganic Chemistry, Vol. 2004, Issue 21
  • DOI: 10.1002/ejic.200400199

Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)- a Topology
journal, July 2011

  • Abrahams, Brendan F.; Hudson, Timothy A.; McCormick, Laura J.
  • Crystal Growth & Design, Vol. 11, Issue 7
  • DOI: 10.1021/cg2005908

A Family of Layered Chiral Porous Magnets Exhibiting Tunable Ordering Temperatures
journal, August 2013

  • Atzori, Matteo; Benmansour, Samia; Mínguez Espallargas, Guillermo
  • Inorganic Chemistry, Vol. 52, Issue 17
  • DOI: 10.1021/ic4013284

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework
journal, December 2015

  • Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui
  • Journal of the American Chemical Society, Vol. 137, Issue 50
  • DOI: 10.1021/jacs.5b10385

2D Conductive Iron-Quinoid Magnets Ordering up to T c = 105 K via Heterogenous Redox Chemistry
journal, March 2017

  • DeGayner, Jordan A.; Jeon, Ie-Rang; Sun, Lei
  • Journal of the American Chemical Society, Vol. 139, Issue 11
  • DOI: 10.1021/jacs.7b00705

Über Oxycarbonsäure-titanate, Polyphenol-titanate und einige analoge Verbindungen. (VII. Mitteilung: Über die Molekularverbindungen anorganischer Halogenide)
journal, June 1920

  • Rosenheim, Arthur; Sorge, Ottokar
  • Berichte der deutschen chemischen Gesellschaft (A and B Series), Vol. 53, Issue 6
  • DOI: 10.1002/cber.19200530609

Coordination isomers of biological iron transport compounds. V. The preparation and chirality of the chromium(III) enterobactin complex and model tris(catechol)chromium(III) analogues
journal, March 1976

  • Isied, Stephan S.; Kuo, Gilbert; Raymond, Kenneth N.
  • Journal of the American Chemical Society, Vol. 98, Issue 7
  • DOI: 10.1021/ja00423a021

Synthetic, structural, and physical studies of bis(triethylammonium) tris(catecholato)vanadate(IV), potassium bis(catecholato)oxovanadate(IV), and potassium tris(catecholato)vanadate (III)
journal, September 1982

  • Cooper, Stephen R.; Koh, Yun Bai; Raymond, Kenneth N.
  • Journal of the American Chemical Society, Vol. 104, Issue 19
  • DOI: 10.1021/ja00383a016

Synthetic, structural, and physical studies of titanium complexes of catechol and 3,5-di-tert-butylcatechol
journal, April 1984

  • Borgias, Brandan A.; Cooper, Stephen R.; Koh, Yun Bai
  • Inorganic Chemistry, Vol. 23, Issue 8
  • DOI: 10.1021/ic00176a005

The quest for magnets composed of vanadium and 1,4-benzoquinones
journal, June 2007

Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal–Organic Frameworks
journal, July 2016

Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer
journal, July 2017

Characterization of the Chloranilate(•3−) π Radical as a Strong Spin-Coupling Bridging Ligand
journal, August 2006

  • Min, Kil Sik; Rheingold, Arnold L.; DiPasquale, Antonio
  • Inorganic Chemistry, Vol. 45, Issue 16
  • DOI: 10.1021/ic061076k

Spin Exchange Effects on the Physicochemical Properties of Tetraoxolene-Bridged Bimetallic Complexes
journal, April 2007

  • Guo, Dong; McCusker, James K.
  • Inorganic Chemistry, Vol. 46, Issue 8
  • DOI: 10.1021/ic070005y

Synthesis, crystal structure and electrochemistry of bis(N,N-dimethylammonium) tris(1,2-benzenedithiolato)titanate(IV)
journal, May 1994

Synthesis and Characterization of V V (3,6-DBSQ)(3,6-DBCat) 2 , a d 0 Metal Complex with Dioxygenase Catalytic Activity
journal, March 2009

  • Morris, Aimee M.; Pierpont, Cortlandt G.; Finke, Richard G.
  • Inorganic Chemistry, Vol. 48, Issue 8
  • DOI: 10.1021/ic802122q

Optical properties of the radical cation tetrathiafulvalenium (TT F + ) in its mixed-valence and monovalence halide salts
journal, January 1979

Role of NEt 4 + in Orienting and Locking Together [M 2 lig 3 ] 2– (6,3) Sheets (H 2 lig = Chloranilic or Fluoranilic Acid) to Generate Spacious Channels Perpendicular to the Sheets
journal, February 2017

  • Kingsbury, Christopher J.; Abrahams, Brendan F.; D’Alessandro, Deanna M.
  • Crystal Growth & Design, Vol. 17, Issue 4
  • DOI: 10.1021/acs.cgd.6b01886

Some electronic properties of the molybdenum bronzes
journal, January 1968

  • Dickens, P. G.; Neild, D. J.
  • Transactions of the Faraday Society, Vol. 64
  • DOI: 10.1039/tf9686400013

Charge storage in doped poly(thiophene): Optical and electrochemical studies
journal, July 1984

A Room-Temperature Molecular/Organic-Based Magnet
journal, June 1991

Spin liquids in frustrated magnets
journal, March 2010

Perturbation calculation from the charge-transfer spectrum data of intervalence site-transfer D.C. conductivity in Prussian Blue
journal, January 1980

  • England, Steven J.; Kathirgamanathan, Poopathy; Rosseinsky, David R.
  • Journal of the Chemical Society, Chemical Communications, Issue 17
  • DOI: 10.1039/c39800000840

Organic semiconductors: A theoretical characterization of the basic parameters governing charge transport
journal, April 2002

  • Bredas, J. L.; Calbert, J. P.; da Silva Filho, D. A.
  • Proceedings of the National Academy of Sciences, Vol. 99, Issue 9
  • DOI: 10.1073/pnas.092143399

Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium
journal, June 2006

  • D'Alessandro, Deanna M.; Keene, F. Richard
  • Chemical Reviews, Vol. 106, Issue 6
  • DOI: 10.1021/cr050010o

Optical and conductive properties of pyrazine-bridged iron, ruthenium and osmium octaethylporphyrin coordination polymers
journal, July 1986

Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework
journal, July 2017

  • Clough, Andrew J.; Skelton, Jonathan M.; Downes, Courtney A.
  • Journal of the American Chemical Society, Vol. 139, Issue 31
  • DOI: 10.1021/jacs.7b05742

Small polaron hopping in spinel manganates
journal, September 2005

Electron Hopping Conduction in the Soliton Model of Polyacetylene
journal, May 1981

Efros-Shklovskii variable-range hopping in reduced graphene oxide sheets of varying carbon s p 2 fraction
journal, December 2012

Study of LiFePO[sub 4] by Cyclic Voltammetry
journal, January 2007

  • Yu, Denis Y. W.; Fietzek, Christopher; Weydanz, Wolfgang
  • Journal of The Electrochemical Society, Vol. 154, Issue 4
  • DOI: 10.1149/1.2434687

Electrochemical Techniques for Intercalation Electrode Materials in Rechargeable Batteries
journal, February 2017

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013

  • Sathiya, M.; Rousse, G.; Ramesha, K.
  • Nature Materials, Vol. 12, Issue 9
  • DOI: 10.1038/nmat3699

Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3
journal, February 2017

  • Pearce, Paul E.; Perez, Arnaud J.; Rousse, Gwenaelle
  • Nature Materials, Vol. 16, Issue 5
  • DOI: 10.1038/nmat4864

Preface: Forum on Redox-Active Ligands
journal, October 2011

Intrinsically conducting metal–organic frameworks
journal, November 2016

  • Leong, Chanel F.; Usov, Pavel M.; D’Alessandro, Deanna M.
  • MRS Bulletin, Vol. 41, Issue 11
  • DOI: 10.1557/mrs.2016.241

Electrical conductivity, thermoelectric power, and ESR of a new family of molecular conductors, dicyanoquinonediimine-metal [(DCNQI ) 2 M] compounds
journal, September 1988

Discovery of a Neutral-to-Ionic Phase Transition in Organic Materials
journal, January 1981

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    Coordination‐driven self‐assembly of Cp*Rh‐Based Rectangles, Cages and Their Host−Guest Binding Study
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    journal, November 2019

    • Skorupskii, Grigorii; Trump, Benjamin A.; Kasel, Thomas W.
    • Nature Chemistry, Vol. 12, Issue 2
    • DOI: 10.1038/s41557-019-0372-0

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    journal, March 2019

    • Kingsbury, Christopher J.; Abrahams, Brendan F.; Auckett, Josie E.
    • Chemistry – A European Journal, Vol. 25, Issue 20
    • DOI: 10.1002/chem.201805600

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    journal, January 2019

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    • CrystEngComm, Vol. 21, Issue 15
    • DOI: 10.1039/c9ce00129h

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    journal, January 2019

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    • Journal of Materials Chemistry C, Vol. 7, Issue 19
    • DOI: 10.1039/c9tc01134j

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    journal, January 2019

    • Wang, Hai-Ning; Meng, Xing; Dong, Long-Zhang
    • Journal of Materials Chemistry A, Vol. 7, Issue 42
    • DOI: 10.1039/c9ta08253k

    Recent Development and Application of Conductive MOFs
    journal, August 2018

    Redox-active metal–organic frameworks for energy conversion and storage
    journal, January 2019

    • Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
    • Journal of Materials Chemistry A, Vol. 7, Issue 28
    • DOI: 10.1039/c9ta04680a

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    journal, January 2020

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    • DOI: 10.1039/d0sc01994a

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    • Australian Journal of Chemistry, Vol. 72, Issue 10
    • DOI: 10.1071/ch19193

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