A Combined Experimental and Theoretical Study on the Activity and Selectivity of the Electrocatalytic Hydrogenation of Aldehydes

Cantu, David C.; Padmaperuma, Asanga B.; Nguyen, Manh-Thuong; Akhade, Sneha A.; Yoon, Yeohoon; Wang, Yang-Gang; Lee, Mal-Soon; Glezakou, Vassiliki-Alexandra; Rousseau, Roger; Lilga, Michael A.

doi:10.1021/ACSCATAL.8B00858

Title: A Combined Experimental and Theoretical Study on the Activity and Selectivity of the Electrocatalytic Hydrogenation of Aldehydes

Journal Article · 29 June 2018 · ACS Catalysis

DOI: https://doi.org/10.1021/ACSCATAL.8B00858 · OSTI ID:1460961

Cantu, David C. ^[1]; Padmaperuma, Asanga B. ^[2]; Nguyen, Manh-Thuong ^[1]; Akhade, Sneha A. ^[1]; Yoon, Yeohoon ^[1]; Wang, Yang-Gang ^[1]; Lee, Mal-Soon ^[1]; Glezakou, Vassiliki-Alexandra ^[1]; Rousseau, Roger ^[1]; Lilga, Michael A. ^[2]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Inst. for Integrated Catalysis
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate,

A detailed mechanistic study of the electrochemical hydrogenation of aldehydes is presented toward the goal of identifying how organic molecules in solution behave at the interface with charged surfaces and what is the best manner to convert them. Specifically, this study focuses on designing an electrocatalytic route for ambient temperature post-pyrolysis treatment of bio-oil. Aldehyde reductions are needed to convert biomass into fuels or chemicals. A combined experimental and computational approach is taken toward catalyst design to provide testable hypotheses regarding catalyst composition, activity, and selectivity. Electrochemical hydrogenation mechanisms for benzaldehyde and pentanal reduction are found to proceed by a coupled proton-electron transfer process. Initial results show that Au, Ag, Cu, and C catalysts exhibit the highest conversion to alcohol products. These catalysts are suitable because they show high cathodic onset potentials for H₂ formation and low cathodic onset potentials for organic reduction. Conversion of aromatic aldehydes is found to be appreciably higher than aliphatic ones. Classical molecular dynamics simulations of solvent and substrate mixtures in an electrolytic cell were performed to assess how species concentrations vary at the solid/liquid interface and in the bulk as a function of applied voltage. Results show that an increase in voltage in the electrolytic cell decreases organic and increases water mole fractions at the solid/liquid interface. In this current study, charged cathodic surfaces result in carbonyl orientations at the surface that do not favor electron transfer. Repulsion of organic substrates to the bulk must be compensated by strong adhesion to the electrode surface. In conclusion, implications on catalyst choice and process design are discussed.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1460961

Report Number(s):: PNNL-SA--132938

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 8 Vol. 8; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Structural principles to steer the selectivity of the electrocatalytic reduction of aliphatic ketones on platinum Bondue, Christoph J.; Calle-Vallejo, Federico; Figueiredo, Marta C. Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0229-3	journal	March 2019
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