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Title: Lithium-Iron (III) Fluoride Battery with Double Surface Protection

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [5];  [6];  [7];  [5];  [5];  [5]
  1. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta GA 30332 USA
  2. Electrochemistry Branch, Sensor and Electron Devices Directorate, Power and Energy Division, U.S. Army Research Laboratory, Adelphi MD 20783 USA
  3. School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta GA 30318 USA
  4. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta GA 30326 USA, Engineering Laboratory for the Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 P. R. China
  5. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta GA 30326 USA
  6. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta GA 30326 USA, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 China
  7. School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta GA 30326 USA, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1460889
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials Journal Volume: 8 Journal Issue: 26; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Zhao, Enbo, Borodin, Oleg, Gao, Xiaosi, Lei, Danni, Xiao, Yiran, Ren, Xiaolei, Fu, Wenbin, Magasinski, Alexandre, Turcheniuk, Kostiantyn, and Yushin, Gleb. Lithium-Iron (III) Fluoride Battery with Double Surface Protection. Germany: N. p., 2018. Web. doi:10.1002/aenm.201800721.
Zhao, Enbo, Borodin, Oleg, Gao, Xiaosi, Lei, Danni, Xiao, Yiran, Ren, Xiaolei, Fu, Wenbin, Magasinski, Alexandre, Turcheniuk, Kostiantyn, & Yushin, Gleb. Lithium-Iron (III) Fluoride Battery with Double Surface Protection. Germany. doi:10.1002/aenm.201800721.
Zhao, Enbo, Borodin, Oleg, Gao, Xiaosi, Lei, Danni, Xiao, Yiran, Ren, Xiaolei, Fu, Wenbin, Magasinski, Alexandre, Turcheniuk, Kostiantyn, and Yushin, Gleb. Wed . "Lithium-Iron (III) Fluoride Battery with Double Surface Protection". Germany. doi:10.1002/aenm.201800721.
@article{osti_1460889,
title = {Lithium-Iron (III) Fluoride Battery with Double Surface Protection},
author = {Zhao, Enbo and Borodin, Oleg and Gao, Xiaosi and Lei, Danni and Xiao, Yiran and Ren, Xiaolei and Fu, Wenbin and Magasinski, Alexandre and Turcheniuk, Kostiantyn and Yushin, Gleb},
abstractNote = {},
doi = {10.1002/aenm.201800721},
journal = {Advanced Energy Materials},
number = 26,
volume = 8,
place = {Germany},
year = {2018},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/aenm.201800721

Citation Metrics:
Cited by: 5 works
Citation information provided by
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Works referenced in this record:

Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF 6 , LiBF 4 , LiDFOB, LiBOB, and LiTFSI
journal, January 2018

  • Parimalam, Bharathy S.; Lucht, Brett L.
  • Journal of The Electrochemical Society, Vol. 165, Issue 2
  • DOI: 10.1149/2.0901802jes

Hierarchical Fabric Decorated with Carbon Nanowire/Metal Oxide Nanocomposites for 1.6 V Wearable Aqueous Supercapacitors
journal, February 2018

  • Fu, Wenbin; Zhao, Enbo; Ren, Xiaolei
  • Advanced Energy Materials, Vol. 8, Issue 18
  • DOI: 10.1002/aenm.201703454

Generation of Cathode Passivation Films via Oxidation of Lithium Bis(oxalato) Borate on High Voltage Spinel (LiNi 0.5 Mn 1.5 O 4 )
journal, March 2014

  • Xu, Mengqing; Tsiouvaras, Nikolaos; Garsuch, Arnd
  • The Journal of Physical Chemistry C, Vol. 118, Issue 14
  • DOI: 10.1021/jp501970j

A High-Capacity Cathode for Lithium Batteries Consisting of Porous Microspheres of Highly Amorphized Iron Fluoride Densified from Its Open Parent Phase
journal, August 2012

  • Li, Chilin; Mu, Xiaoke; van Aken, Peter A.
  • Advanced Energy Materials, Vol. 3, Issue 1
  • DOI: 10.1002/aenm.201200209

In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes
journal, December 2014

  • Kim, Hyea; Wu, Feixiang; Lee, Jung Tae
  • Advanced Energy Materials, Vol. 5, Issue 6
  • DOI: 10.1002/aenm.201401792

Fabrication of FeF3 Nanoflowers on CNT Branches and Their Application to High Power Lithium Rechargeable Batteries
journal, October 2010

  • Kim, Sung-Wook; Seo, Dong-Hwa; Gwon, Hyeokjo
  • Advanced Materials, Vol. 22, Issue 46
  • DOI: 10.1002/adma.201002879

Three-dimensionally ordered macroporous FeF3 and its in situ homogenous polymerization coating for high energy and power density lithium ion batteries
journal, January 2012

  • Ma, De-long; Cao, Zhan-yi; Wang, Heng-guo
  • Energy & Environmental Science, Vol. 5, Issue 9
  • DOI: 10.1039/c2ee22568a

Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017


Thermal Decomposition of NF 3 with Various Oxides
journal, January 1996

  • Vileno, Elizabeth; LeClair, Michael K.; Suib, Steven L.
  • Chemistry of Materials, Vol. 8, Issue 6
  • DOI: 10.1021/cm9504955

Conversion cathodes for rechargeable lithium and lithium-ion batteries
journal, January 2017

  • Wu, Feixiang; Yushin, Gleb
  • Energy & Environmental Science, Vol. 10, Issue 2
  • DOI: 10.1039/C6EE02326F

Performance Enhancement and Side Reactions in Rechargeable Nickel–Iron Batteries with Nanostructured Electrodes
journal, January 2016

  • Lei, Danni; Lee, Dong-Chan; Magasinski, Alexandre
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 3
  • DOI: 10.1021/acsami.5b10547

Lithium Titanate Confined in Carbon Nanopores for Asymmetric Supercapacitors
journal, March 2016


Plasma-Enhanced Atomic Layer Deposition of Ultrathin Oxide Coatings for Stabilized Lithium-Sulfur Batteries
journal, June 2013

  • Kim, Hyea; Lee, Jung Tae; Lee, Dong-Chan
  • Advanced Energy Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aenm.201300253

Polysulfide Anchoring Mechanism Revealed by Atomic Layer Deposition of V 2 O 5 and Sulfur-Filled Carbon Nanotubes for Lithium–Sulfur Batteries
journal, February 2017

  • Carter, Rachel; Oakes, Landon; Muralidharan, Nitin
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 8
  • DOI: 10.1021/acsami.6b16155

Oxidative Stability and Initial Decomposition Reactions of Carbonate, Sulfone, and Alkyl Phosphate-Based Electrolytes
journal, April 2013

  • Borodin, Oleg; Behl, Wishvender; Jow, T. Richard
  • The Journal of Physical Chemistry C, Vol. 117, Issue 17
  • DOI: 10.1021/jp400527c

Recent Achievements on Inorganic Electrode Materials for Lithium-Ion Batteries
journal, February 2015

  • Croguennec, Laurence; Palacin, M. Rosa
  • Journal of the American Chemical Society, Vol. 137, Issue 9
  • DOI: 10.1021/ja507828x

In situ surface protection for enhancing stability and performance of conversion-type cathodes
journal, January 2017

  • Wu, Feixiang; Borodin, Oleg; Yushin, Gleb
  • MRS Energy & Sustainability, Vol. 4
  • DOI: 10.1557/mre.2017.11

Pulsed laser deposited iron fluoride thin films for lithium-ion batteries
journal, April 2006


Toward in-situ protected sulfur cathodes by using lithium bromide and pre-charge
journal, October 2017


Impact of Lithium Bis(oxalate)borate Electrolyte Additive on the Performance of High-Voltage Spinel/Graphite Li-Ion Batteries
journal, October 2013

  • Pieczonka, Nicholas P. W.; Yang, Li; Balogh, Michael P.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 44
  • DOI: 10.1021/jp408717x

An FeF 3 ·0.5H 2 O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries
journal, July 2013

  • Li, Chilin; Yin, Congling; Gu, Lin
  • Journal of the American Chemical Society, Vol. 135, Issue 31
  • DOI: 10.1021/ja402061q

Infiltrated Porous Polymer Sheets as Free-Standing Flexible Lithium-Sulfur Battery Electrodes
journal, May 2016


Carbon-Metal Fluoride Nanocomposites: Structure and Electrochemistry of FeF3 : C
journal, January 2003

  • Badway, F.; Pereira, N.; Cosandey, F.
  • Journal of The Electrochemical Society, Vol. 150, Issue 9, p. A1209-A1218
  • DOI: 10.1149/1.1596162

Graphene–Li 2 S–Carbon Nanocomposite for Lithium–Sulfur Batteries
journal, December 2015


Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes
journal, November 2011

  • Wang, Feng; Robert, Rosa; Chernova, Natasha A.
  • Journal of the American Chemical Society, Vol. 133, Issue 46
  • DOI: 10.1021/ja206268a

Lithium Iodide as a Promising Electrolyte Additive for Lithium-Sulfur Batteries: Mechanisms of Performance Enhancement
journal, November 2014


Examining the Solid Electrolyte Interphase on Binder-Free Graphite Electrodes
journal, January 2009

  • Xiao, Ang; Yang, Li; Lucht, Brett L.
  • Journal of The Electrochemical Society, Vol. 156, Issue 4
  • DOI: 10.1149/1.3078020

Li-ion battery materials: present and future
journal, June 2015


LiBOB as Additive in LiPF[sub 6]-Based Lithium Ion Electrolytes
journal, January 2005

  • Xu, Kang; Zhang, Shengshui; Jow, T. Richard
  • Electrochemical and Solid-State Letters, Vol. 8, Issue 7
  • DOI: 10.1149/1.1924930

A Mesoporous Iron-Based Fluoride Cathode of Tunnel Structure for Rechargeable Lithium Batteries
journal, March 2011

  • Li, Chilin; Gu, Lin; Tong, Jianwei
  • Advanced Functional Materials, Vol. 21, Issue 8
  • DOI: 10.1002/adfm.201002213

Tailoring Electrolyte Composition for LiBOB
journal, January 2008

  • Xu, Kang
  • Journal of The Electrochemical Society, Vol. 155, Issue 10
  • DOI: 10.1149/1.2961055

Pomegranate-Structured Conversion-Reaction Cathode with a Built-in Li Source for High-Energy Li-Ion Batteries
journal, May 2016


High-Capacity Lithium-Ion Battery Conversion Cathodes Based on Iron Fluoride Nanowires and Insights into the Conversion Mechanism
journal, October 2012

  • Li, Linsen; Meng, Fei; Jin, Song
  • Nano Letters, Vol. 12, Issue 11, p. 6030-6037
  • DOI: 10.1021/nl303630p

Lithium-Iron Fluoride Battery with In Situ Surface Protection
journal, February 2016

  • Gu, Wentian; Borodin, Oleg; Zdyrko, Bogdan
  • Advanced Functional Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adfm.201504848

Metal Fluorides Nanoconfined in Carbon Nanopores as Reversible High Capacity Cathodes for Li and Li-Ion Rechargeable Batteries: FeF 2 as an Example
journal, February 2015

  • Gu, Wentian; Magasinski, Alexandre; Zdyrko, Bogdan
  • Advanced Energy Materials, Vol. 5, Issue 4
  • DOI: 10.1002/aenm.201500243

Ternary metal fluorides as high-energy cathodes with low cycling hysteresis
journal, March 2015

  • Wang, Feng; Kim, Sung-Wook; Seo, Dong-Hwa
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7668

LiBOB: Is it an alternative salt for lithium ion chemistry?
journal, August 2005


Molecular Dynamics Simulations and Experimental Study of Lithium Ion Transport in Dilithium Ethylene Dicarbonate
journal, April 2013

  • Borodin, Oleg; Zhuang, Guorong V.; Ross, Philip N.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 15
  • DOI: 10.1021/jp4000494

Thermal Decomposition of NF3 by Ti, Si, and Sn Powders
journal, April 1995

  • Vileno, Elizabeth; LeClair, Michael K.; Suib, Steven L.
  • Chemistry of Materials, Vol. 7, Issue 4, p. 683-687
  • DOI: 10.1021/cm00052a012

NF3 decomposition over some metal oxides in the absence of water
journal, September 2010