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Title: Oxidatively stable ferrocenyl-π-bridge-titanocene D–π-A complexes: an electrochemical and spectroscopic investigation of the mixed-valent states

Coordination of Cu I into R Cp 2 Ti(C 2 Fc) 2 compounds results in well-separated Fe III/II couples and mixed-valent states with distinct spectroscopic signatures.
Authors:
ORCiD logo [1] ;  [1] ;  [2] ; ORCiD logo [1] ; ORCiD logo [3] ;  [1] ;  [2] ; ORCiD logo [1]
  1. Department of Chemistry, Furman University, Greenville, USA
  2. Department of Chemistry, The University of North Carolina at Chapel Hill, Chapel Hill, USA
  3. Department of Chemistry, Clemson University, Clemson, USA
Publication Date:
Grant/Contract Number:
SC0013461; SC0001011
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 32; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1460884

Pienkos, Jared A., Webster, Alexander B., Piechota, Eric J., Agakidou, A. Danai, McMillen, Colin D., Pritchett, David Y., Meyer, Gerald J., and Wagenknecht, Paul S.. Oxidatively stable ferrocenyl-π-bridge-titanocene D–π-A complexes: an electrochemical and spectroscopic investigation of the mixed-valent states. United Kingdom: N. p., Web. doi:10.1039/C8DT01853G.
Pienkos, Jared A., Webster, Alexander B., Piechota, Eric J., Agakidou, A. Danai, McMillen, Colin D., Pritchett, David Y., Meyer, Gerald J., & Wagenknecht, Paul S.. Oxidatively stable ferrocenyl-π-bridge-titanocene D–π-A complexes: an electrochemical and spectroscopic investigation of the mixed-valent states. United Kingdom. doi:10.1039/C8DT01853G.
Pienkos, Jared A., Webster, Alexander B., Piechota, Eric J., Agakidou, A. Danai, McMillen, Colin D., Pritchett, David Y., Meyer, Gerald J., and Wagenknecht, Paul S.. 2018. "Oxidatively stable ferrocenyl-π-bridge-titanocene D–π-A complexes: an electrochemical and spectroscopic investigation of the mixed-valent states". United Kingdom. doi:10.1039/C8DT01853G.
@article{osti_1460884,
title = {Oxidatively stable ferrocenyl-π-bridge-titanocene D–π-A complexes: an electrochemical and spectroscopic investigation of the mixed-valent states},
author = {Pienkos, Jared A. and Webster, Alexander B. and Piechota, Eric J. and Agakidou, A. Danai and McMillen, Colin D. and Pritchett, David Y. and Meyer, Gerald J. and Wagenknecht, Paul S.},
abstractNote = {Coordination of Cu I into R Cp 2 Ti(C 2 Fc) 2 compounds results in well-separated Fe III/II couples and mixed-valent states with distinct spectroscopic signatures.},
doi = {10.1039/C8DT01853G},
journal = {Dalton Transactions},
number = 32,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}