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This content will become publicly available on July 7, 2019

Title: [Ru II(tpy)(bpy)Cl] +-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

13 C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO 2 reduction reaction catalyzed by a ruthenium complex.
Authors:
 [1] ;  [1] ; ORCiD logo [2] ; ORCiD logo [1]
  1. Univ. of Connecticut, Storrs, CT (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Report Number(s):
BNL-207858-2018-JAAM
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:
SC0012704
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1460826
Alternate Identifier(s):
OSTI ID: 1460466