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Title: [Ru II(tpy)(bpy)Cl] +-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

Abstract

13 C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO 2 reduction reaction catalyzed by a ruthenium complex.

Authors:
 [1];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Univ. of Connecticut, Storrs, CT (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1460826
Alternate Identifier(s):
OSTI ID: 1460466
Report Number(s):
BNL-207858-2018-JAAM
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 61; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Schneider, T. W., Hren, M. T., Ertem, M. Z., and Angeles-Boza, Alfredo M. [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects. United States: N. p., 2018. Web. doi:10.1039/C8CC03009J.
Schneider, T. W., Hren, M. T., Ertem, M. Z., & Angeles-Boza, Alfredo M. [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects. United States. doi:10.1039/C8CC03009J.
Schneider, T. W., Hren, M. T., Ertem, M. Z., and Angeles-Boza, Alfredo M. Sat . "[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects". United States. doi:10.1039/C8CC03009J. https://www.osti.gov/servlets/purl/1460826.
@article{osti_1460826,
title = {[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects},
author = {Schneider, T. W. and Hren, M. T. and Ertem, M. Z. and Angeles-Boza, Alfredo M.},
abstractNote = {13 C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO 2 reduction reaction catalyzed by a ruthenium complex.},
doi = {10.1039/C8CC03009J},
journal = {ChemComm},
number = 61,
volume = 54,
place = {United States},
year = {2018},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Figures / Tables:

Figure 1 Figure 1: Schematic representations of [RuII(tpy)(bpy)Cl]+ (1) and [RuII(tpy)(bpy)H]+ (2)

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Works referenced in this record:

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