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Title: Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction

Abstract

High-performance electrocatalytic CO2reduction to CO using Ni single-atom catalyst in an anion membrane electrode assembly.

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [5];  [5];  [3];  [4]; ORCiD logo [1];  [5];  [5]; ORCiD logo [1]
  1. Harvard Univ., Cambridge, MA (United States)
  2. Stanford Univ., Stanford, CA (United States)
  3. Harvard Univ., Cambridge, MA (United States); Univ. of Science and Technology of China, Hefei (China)
  4. Univ. of Saskatchewan; Saskatoon (Canada)
  5. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1460822
Report Number(s):
BNL-207853-2018-JAAM
Journal ID: ISSN 1754-5692; EESNBY
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 11; Journal Issue: 4; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Jiang, Kun, Siahrostami, Samira, Zheng, Tingting, Hu, Yongfeng, Hwang, Sooyeon, Stavitski, Eli, Peng, Yande, Dynes, James, Gangisetty, Mehash, Su, Dong, Attenkofer, Klaus, and Wang, Haotian. Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction. United States: N. p., 2018. Web. doi:10.1039/C7EE03245E.
Jiang, Kun, Siahrostami, Samira, Zheng, Tingting, Hu, Yongfeng, Hwang, Sooyeon, Stavitski, Eli, Peng, Yande, Dynes, James, Gangisetty, Mehash, Su, Dong, Attenkofer, Klaus, & Wang, Haotian. Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction. United States. doi:10.1039/C7EE03245E.
Jiang, Kun, Siahrostami, Samira, Zheng, Tingting, Hu, Yongfeng, Hwang, Sooyeon, Stavitski, Eli, Peng, Yande, Dynes, James, Gangisetty, Mehash, Su, Dong, Attenkofer, Klaus, and Wang, Haotian. Thu . "Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction". United States. doi:10.1039/C7EE03245E. https://www.osti.gov/servlets/purl/1460822.
@article{osti_1460822,
title = {Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction},
author = {Jiang, Kun and Siahrostami, Samira and Zheng, Tingting and Hu, Yongfeng and Hwang, Sooyeon and Stavitski, Eli and Peng, Yande and Dynes, James and Gangisetty, Mehash and Su, Dong and Attenkofer, Klaus and Wang, Haotian},
abstractNote = {High-performance electrocatalytic CO2reduction to CO using Ni single-atom catalyst in an anion membrane electrode assembly.},
doi = {10.1039/C7EE03245E},
journal = {Energy & Environmental Science},
number = 4,
volume = 11,
place = {United States},
year = {2018},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
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Citation Metrics:
Cited by: 65 works
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Figures / Tables:

Fig. 1 Fig. 1: Morphology and composition characterization of Ni–NG. (A) TEM image of a Ni–NG nanosheet. No Ni NPs were observed. (B) Aberrationcorrected HAADF-STEM image of a Ni–NG nanosheet. The uniformly distributed bright dots represent Ni atoms due to the high mass compared to C or N. (C) A zoom-in STEMmore » image of Ni–NG. Isolated Ni single atoms (brighter dots) were observed, and a few representatives were indicated by red circles. (D) Elemental mapping of a Ni–NG nanosheet confirming the co-existence of C, N, and Ni atoms.« less

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