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Title: Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction

Abstract

High-performance electrocatalytic CO2reduction to CO using Ni single-atom catalyst in an anion membrane electrode assembly.

Authors:
ORCiD logo [1];  [2];  [3];  [4];  [5];  [5];  [3];  [4]; ORCiD logo [1];  [5];  [5]; ORCiD logo [1]
  1. Harvard Univ., Cambridge, MA (United States)
  2. Stanford Univ., Stanford, CA (United States)
  3. Harvard Univ., Cambridge, MA (United States); Univ. of Science and Technology of China, Hefei (China)
  4. Univ. of Saskatchewan; Saskatoon (Canada)
  5. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1460822
Report Number(s):
BNL-207853-2018-JAAM
Journal ID: ISSN 1754-5692; EESNBY
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 11; Journal Issue: 4; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Jiang, Kun, Siahrostami, Samira, Zheng, Tingting, Hu, Yongfeng, Hwang, Sooyeon, Stavitski, Eli, Peng, Yande, Dynes, James, Gangisetty, Mehash, Su, Dong, Attenkofer, Klaus, and Wang, Haotian. Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction. United States: N. p., 2018. Web. https://doi.org/10.1039/C7EE03245E.
Jiang, Kun, Siahrostami, Samira, Zheng, Tingting, Hu, Yongfeng, Hwang, Sooyeon, Stavitski, Eli, Peng, Yande, Dynes, James, Gangisetty, Mehash, Su, Dong, Attenkofer, Klaus, & Wang, Haotian. Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction. United States. https://doi.org/10.1039/C7EE03245E
Jiang, Kun, Siahrostami, Samira, Zheng, Tingting, Hu, Yongfeng, Hwang, Sooyeon, Stavitski, Eli, Peng, Yande, Dynes, James, Gangisetty, Mehash, Su, Dong, Attenkofer, Klaus, and Wang, Haotian. Thu . "Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction". United States. https://doi.org/10.1039/C7EE03245E. https://www.osti.gov/servlets/purl/1460822.
@article{osti_1460822,
title = {Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction},
author = {Jiang, Kun and Siahrostami, Samira and Zheng, Tingting and Hu, Yongfeng and Hwang, Sooyeon and Stavitski, Eli and Peng, Yande and Dynes, James and Gangisetty, Mehash and Su, Dong and Attenkofer, Klaus and Wang, Haotian},
abstractNote = {High-performance electrocatalytic CO2reduction to CO using Ni single-atom catalyst in an anion membrane electrode assembly.},
doi = {10.1039/C7EE03245E},
journal = {Energy & Environmental Science},
number = 4,
volume = 11,
place = {United States},
year = {2018},
month = {2}
}

Journal Article:
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Cited by: 65 works
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Figures / Tables:

Fig. 1 Fig. 1: Morphology and composition characterization of Ni–NG. (A) TEM image of a Ni–NG nanosheet. No Ni NPs were observed. (B) Aberrationcorrected HAADF-STEM image of a Ni–NG nanosheet. The uniformly distributed bright dots represent Ni atoms due to the high mass compared to C or N. (C) A zoom-in STEMmore » image of Ni–NG. Isolated Ni single atoms (brighter dots) were observed, and a few representatives were indicated by red circles. (D) Elemental mapping of a Ni–NG nanosheet confirming the co-existence of C, N, and Ni atoms.« less

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    journal, January 2019

    • Yang, Fan; Wang, Minjian; Liu, Wei
    • Green Chemistry, Vol. 21, Issue 3
    • DOI: 10.1039/c8gc03664k

    Recent progress in single-atom electrocatalysts: concept, synthesis, and applications in clean energy conversion
    journal, January 2018

    • Su, Jianwei; Ge, Ruixiang; Dong, Yan
    • Journal of Materials Chemistry A, Vol. 6, Issue 29
    • DOI: 10.1039/c8ta04064h

    Tuning the activity of N-doped carbon for CO 2 reduction via in situ encapsulation of nickel nanoparticles into nano-hybrid carbon substrates
    journal, January 2019

    • Yuan, Cheng-Zong; Li, Hong-Bao; Jiang, Yi-Fan
    • Journal of Materials Chemistry A, Vol. 7, Issue 12
    • DOI: 10.1039/c8ta11500a

    A nickel–iridium alloy as an efficient heterogeneous catalyst for hydrogenation of olefins
    journal, January 2019

    • Bai, Jia-qi; Tamura, Masazumi; Nakagawa, Yoshinao
    • Chemical Communications, Vol. 55, Issue 71
    • DOI: 10.1039/c9cc04822g

    Transition metal embedded C 3 N monolayers as promising catalysts for the hydrogen evolution reaction
    journal, January 2019

    • Zhao, Yameng; Ma, Dongwei; Zhang, Jing
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 36
    • DOI: 10.1039/c9cp04267a

    Surface strategies for catalytic CO 2 reduction: from two-dimensional materials to nanoclusters to single atoms
    journal, January 2019

    • Wang, Liming; Chen, Wenlong; Zhang, Doudou
    • Chemical Society Reviews, Vol. 48, Issue 21
    • DOI: 10.1039/c9cs00163h

    A general route via formamide condensation to prepare atomically dispersed metal–nitrogen–carbon electrocatalysts for energy technologies
    journal, January 2019

    • Zhang, Guoxin; Jia, Yin; Zhang, Cong
    • Energy & Environmental Science, Vol. 12, Issue 4
    • DOI: 10.1039/c9ee00162j

    An alkaline polymer electrolyte CO 2 electrolyzer operated with pure water
    journal, January 2019

    • Yin, Zhenglei; Peng, Hanqing; Wei, Xing
    • Energy & Environmental Science, Vol. 12, Issue 8
    • DOI: 10.1039/c9ee01204d

    FeNC catalysts for CO 2 electroreduction to CO: effect of nanostructured carbon supports
    journal, January 2019

    • Karapinar, Dilan; Tran, Ngoc-Huan; Giaume, Domitille
    • Sustainable Energy & Fuels, Vol. 3, Issue 7
    • DOI: 10.1039/c9se00214f

    Electrochemical CO 2 reduction: from nanoclusters to single atom catalysts
    journal, January 2020

    • Lü, Fang; Bao, Haihong; Mi, Yuying
    • Sustainable Energy & Fuels, Vol. 4, Issue 3
    • DOI: 10.1039/c9se00776h

    Nickel-containing N-doped carbon as effective electrocatalysts for the reduction of CO 2 to CO in a continuous-flow electrolyzer
    journal, January 2020

    • Daems, Nick; De Mot, Bert; Choukroun, Daniel
    • Sustainable Energy & Fuels, Vol. 4, Issue 3
    • DOI: 10.1039/c9se00814d

    Achieving highly efficient CO 2 to CO electroreduction exceeding 300 mA cm −2 with single-atom nickel electrocatalysts
    journal, January 2019

    • Jeong, Hui-Yun; Balamurugan, Mani; Choutipalli, Venkata Surya Kumar
    • Journal of Materials Chemistry A, Vol. 7, Issue 17
    • DOI: 10.1039/c9ta02405k

    A mechanistic study of B 36 -supported atomic Au promoted CO 2 electroreduction to formic acid
    journal, January 2019

    • Li, Wen-Ying; Zhao, Xiang; Dang, Jing-Shuang
    • Journal of Materials Chemistry A, Vol. 7, Issue 23
    • DOI: 10.1039/c9ta03983j

    Emerging nanostructured carbon-based non-precious metal electrocatalysts for selective electrochemical CO 2 reduction to CO
    journal, January 2019

    • Wang, Xinyue; Zhao, Qidong; Yang, Bin
    • Journal of Materials Chemistry A, Vol. 7, Issue 44
    • DOI: 10.1039/c9ta09681g

    Hydrogen peroxide electrochemical synthesis on hybrid double-atom (Pd–Cu) doped N vacancy g-C 3 N 4 : a novel design strategy for electrocatalyst screening
    journal, January 2020

    • Cao, Yongyong; Zhao, Chenxia; Fang, Qiaojun
    • Journal of Materials Chemistry A, Vol. 8, Issue 5
    • DOI: 10.1039/c9ta12468c

    Steering CO 2 electroreduction toward ethanol production by a surface-bound Ru polypyridyl carbene catalyst on N-doped porous carbon
    journal, December 2019

    • Liu, Yanming; Fan, Xinfei; Nayak, Animesh
    • Proceedings of the National Academy of Sciences, Vol. 116, Issue 52
    • DOI: 10.1073/pnas.1907740116

      Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.