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Title: Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode

Abstract

Here, we report the development, testing, and demonstration of a setup for modulation excitation spectroscopy experiments at the Inner Shell Spectroscopy beamline of National Synchrotron Light Source - II. A computer algorithm and dedicated software were developed for asynchronous data processing and analysis. We demonstrate the reconstruction of X-ray absorption spectra for different time points within the modulation pulse using a model system. This setup and the software are intended for a broad range of functional materials which exhibit structural and/or electronic responses to the external stimulation, such as catalysts, energy and battery materials, and electromechanical devices.

Authors:
ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [2];  [1]; ORCiD logo [1];  [3];  [2]; ORCiD logo [1]
  1. Stony Brook Univ., Stony Brook, NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Weizmann Institute of Science, Rehovot (Israel)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1460821
Alternate Identifier(s):
OSTI ID: 1433575
Report Number(s):
[BNL-207845-2018-JAAM]
[Journal ID: ISSN 0034-6748; TRN: US1901923]
Grant/Contract Number:  
[SC0012704; AC02-98CH10886]
Resource Type:
Accepted Manuscript
Journal Name:
Review of Scientific Instruments
Additional Journal Information:
[ Journal Volume: 89; Journal Issue: 4]; Journal ID: ISSN 0034-6748
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Singh, H., Donetsky, D., Liu, J., Attenkofer, K., Cheng, B., Trelewicz, J. R., Lubomirsky, Igor, Stavitski, E., and Frenkel, A. I. Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode. United States: N. p., 2018. Web. doi:10.1063/1.5000679.
Singh, H., Donetsky, D., Liu, J., Attenkofer, K., Cheng, B., Trelewicz, J. R., Lubomirsky, Igor, Stavitski, E., & Frenkel, A. I. Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode. United States. doi:10.1063/1.5000679.
Singh, H., Donetsky, D., Liu, J., Attenkofer, K., Cheng, B., Trelewicz, J. R., Lubomirsky, Igor, Stavitski, E., and Frenkel, A. I. Wed . "Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode". United States. doi:10.1063/1.5000679. https://www.osti.gov/servlets/purl/1460821.
@article{osti_1460821,
title = {Investigation of periodically driven systems by x-ray absorption spectroscopy using asynchronous data collection mode},
author = {Singh, H. and Donetsky, D. and Liu, J. and Attenkofer, K. and Cheng, B. and Trelewicz, J. R. and Lubomirsky, Igor and Stavitski, E. and Frenkel, A. I.},
abstractNote = {Here, we report the development, testing, and demonstration of a setup for modulation excitation spectroscopy experiments at the Inner Shell Spectroscopy beamline of National Synchrotron Light Source - II. A computer algorithm and dedicated software were developed for asynchronous data processing and analysis. We demonstrate the reconstruction of X-ray absorption spectra for different time points within the modulation pulse using a model system. This setup and the software are intended for a broad range of functional materials which exhibit structural and/or electronic responses to the external stimulation, such as catalysts, energy and battery materials, and electromechanical devices.},
doi = {10.1063/1.5000679},
journal = {Review of Scientific Instruments},
number = [4],
volume = [89],
place = {United States},
year = {2018},
month = {4}
}

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Figures / Tables:

FIG. 1 FIG. 1: Schematic of an asynchronous detection mode showing a prototype time dependent XAFS data collection and their reconstruction. (a) Synchrotron energy profile as a function of time scanned near the Ni K-edge. (b) The corresponding absorption coefficient as a function of time, showing two representative scans µ1 and µ2.more » (c) The square wave of 1 Hz period was used to switch between the samples S1 and S2 (each sample was exposed to the beam for 0.5 s). (d) The enlarged pulses are shown to demonstrate the procedure of dividing the pulses in the same number (n) of intervals or bins. (e) Illustration of the data reconstruction procedure, where mn means n-th bin in the m-th pulse.« less

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