Operando tribochemical formation of onion-like-carbon leads to macroscale superlubricity

Berman, Diana; Narayanan, Badri; Cherukara, Mathew J.; Sankaranarayanan, Subramanian K. R. S.; Erdemir, Ali; Zinovev, Alexander; Sumant, Anirudha V.

doi:10.1038/s41467-018-03549-6

Title: Operando tribochemical formation of onion-like-carbon leads to macroscale superlubricity

Journal Article · 20 March 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-03549-6 · OSTI ID:1460812

Berman, Diana ^[1]; Narayanan, Badri ^[2];

^[2]; Sankaranarayanan, Subramanian K. R. S. ^[2]; Erdemir, Ali ^[2]; Zinovev, Alexander ^[2]; Sumant, Anirudha V. ^[2]

Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of North Texas, Denton, TX (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

High contact pressure and shear during relative movement of the sliding interfaces are known to cause structural or chemical modification or complete phase transformation due to the stress induced chemical reaction. Such reactions can manifest either formation of tribofilm or induce enhanced wear at the tribological interface. The nature of these stress-induced reactions at the atomistic level and formation of byproducts at the tribological interface, however, remain poorly understood and pose uncertainties in predicting the tribological performance of the tribosystem. In this paper we demonstrate that, when pristine molybdenum disulfide layers in their two dimensional form are coupled with nanodiamonds, the catalytic interaction of sulfur with the nanodiamond through a stress-induced tribocatalytic reaction under high pressure and shear conditions induces amorphization of nanodiamond and eventually formation of onion like carbon structures (OLCs). This leads to near-zero friction, superlubricity, when sliding against diamond like carbon (DLC) ball in dry nitrogen environment at room temperature. Furthermore, the large size (20-30 nm in diameter) and stiffness of the resulting OLCS allow sustaining high contact pressures, while graphitic lattice provides an incommensurate contact with the DLC surface, thus allowing for successful demonstration of the superlubricity conditions.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1460812

Alternate ID(s):: OSTI ID: 1490201

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 9; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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