[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects
Abstract
13 C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO 2 reduction reaction catalyzed by a ruthenium complex.
- Authors:
-
- Univ. of Connecticut, Storrs, CT (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1460826
- Alternate Identifier(s):
- OSTI ID: 1460466
- Report Number(s):
- BNL-207858-2018-JAAM
Journal ID: ISSN 1359-7345
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 61; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Citation Formats
Schneider, T. W., Hren, M. T., Ertem, M. Z., and Angeles-Boza, Alfredo M. [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects. United States: N. p., 2018.
Web. doi:10.1039/C8CC03009J.
Schneider, T. W., Hren, M. T., Ertem, M. Z., & Angeles-Boza, Alfredo M. [RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects. United States. https://doi.org/10.1039/C8CC03009J
Schneider, T. W., Hren, M. T., Ertem, M. Z., and Angeles-Boza, Alfredo M. Sat .
"[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects". United States. https://doi.org/10.1039/C8CC03009J. https://www.osti.gov/servlets/purl/1460826.
@article{osti_1460826,
title = {[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects},
author = {Schneider, T. W. and Hren, M. T. and Ertem, M. Z. and Angeles-Boza, Alfredo M.},
abstractNote = {13 C kinetic isotope effect determinations combined with DFT calculations provide insight on the CO 2 reduction reaction catalyzed by a ruthenium complex.},
doi = {10.1039/C8CC03009J},
journal = {ChemComm},
number = 61,
volume = 54,
place = {United States},
year = {Sat Jul 07 00:00:00 EDT 2018},
month = {Sat Jul 07 00:00:00 EDT 2018}
}
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Cited by: 10 works
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Figures / Tables:
Figure 1: Schematic representations of [RuII(tpy)(bpy)Cl]+ (1) and [RuII(tpy)(bpy)H]+ (2)
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Works referencing / citing this record:
Efficient labeling of organic molecules using 13 C elemental carbon: universal access to 13 C 2 -labeled synthetic building blocks, polymers and pharmaceuticals
journal, January 2020
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- Organic Chemistry Frontiers, Vol. 7, Issue 4
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.