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Title: Acceleration of CO 2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics

Kinetic studies of CO 2 insertion into transition metal hydrides provide evidence about the nature of the rate-determining transition state.
Authors:
 [1] ; ORCiD logo [2] ; ORCiD logo [1] ; ORCiD logo [1]
  1. Department of Chemistry, Yale University, New Haven, USA
  2. Department of Chemistry, University of Missouri, Columbia, USA
Publication Date:
Grant/Contract Number:
SC0018222; SC0001059
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 9 Journal Issue: 32; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1460464

Heimann, Jessica E., Bernskoetter, Wesley H., Hazari, Nilay, and Mayer, James M.. Acceleration of CO 2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics. United Kingdom: N. p., Web. doi:10.1039/C8SC02535E.
Heimann, Jessica E., Bernskoetter, Wesley H., Hazari, Nilay, & Mayer, James M.. Acceleration of CO 2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics. United Kingdom. doi:10.1039/C8SC02535E.
Heimann, Jessica E., Bernskoetter, Wesley H., Hazari, Nilay, and Mayer, James M.. 2018. "Acceleration of CO 2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics". United Kingdom. doi:10.1039/C8SC02535E.
@article{osti_1460464,
title = {Acceleration of CO 2 insertion into metal hydrides: ligand, Lewis acid, and solvent effects on reaction kinetics},
author = {Heimann, Jessica E. and Bernskoetter, Wesley H. and Hazari, Nilay and Mayer, James M.},
abstractNote = {Kinetic studies of CO 2 insertion into transition metal hydrides provide evidence about the nature of the rate-determining transition state.},
doi = {10.1039/C8SC02535E},
journal = {Chemical Science},
number = 32,
volume = 9,
place = {United Kingdom},
year = {2018},
month = {1}
}