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Title: Investigation of the synthesis and characterization of platinum-DMSA nanoparticles using millifluidic chip reactor

Abstract

Here a continuous flow process for production of water-soluble Platinum-Dimercaptosuccinic acid (Pt(DMSA)) nanoparticles at ambient conditions using millifluidics is demonstrated. The process development was supported by in-situ synchrotron radiation-based X-ray absorption spectroscopy (XAS) investigations. The XAS revealed that the nucleation and growth of the Pt(DMSA) nanoparticles is extremely fast. Such a fast nucleation and growth process was also found to hinder coating of the channel walls, except at the zone 1 where the reactants first interact. The engineering of hitherto unreported Pt(DMSA) nanoparticles, well characterized using High-resolution transmission electron microscopy (HR-TEM), Scanning transmission electron microscopy (STEM), Scanning electron microscopy (SEM), Energy dispersive spectroscopy (EDS), Powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier transform infra-red spectroscopy (FT-IR), using continuous flow processes offers potential opportunities for scale-up.

Authors:
 [1];  [1];  [1];  [2];  [2];  [2];  [3];  [1];  [1];  [1]
+ Show Author Affiliations
  1. Louisiana State Univ., Baton Rouge, LA (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Indiana Univ., Bloomington, IN (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Atomic-Level Catalyst Design (CALCD)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1369707
Alternate Identifier(s):
OSTI ID: 1460452
Grant/Contract Number:  
SC0001058
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Engineering Journal
Additional Journal Information:
Journal Volume: 281; Journal Issue: C; Related Information: CALCD partners with Louisiana State University (lead); Clemson University; University of Florida; Georgia Institute of Technology; Grambling State University; Oak Ridge National Laboratory; Ohio State University; Pennsylvania State; Texas A&M University; Vienna University of Technology, Austria; University of Utrecht, Netherlands; Journal ID: ISSN 1385-8947
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Platinum-DMSA nanoparticles; In-situ XAS; Millifluidics

Citation Formats

Navin, Chelliah V., Krishna, Katla Sai, Bovenkamp-Langlois, G. Lisa, Miller, Jeffery T., Chattopadhyay, Soma, Shibata, Tomohiro, Losovyj, Yaroslav, Singh, Varshni, Theegala, Chandra, and Kumar, Challa S. S. R. Investigation of the synthesis and characterization of platinum-DMSA nanoparticles using millifluidic chip reactor. United States: N. p., 2015. Web. doi:10.1016/j.cej.2015.06.049.
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Navin, Chelliah V., Krishna, Katla Sai, Bovenkamp-Langlois, G. Lisa, Miller, Jeffery T., Chattopadhyay, Soma, Shibata, Tomohiro, Losovyj, Yaroslav, Singh, Varshni, Theegala, Chandra, & Kumar, Challa S. S. R. Investigation of the synthesis and characterization of platinum-DMSA nanoparticles using millifluidic chip reactor. United States. https://doi.org/10.1016/j.cej.2015.06.049
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Navin, Chelliah V., Krishna, Katla Sai, Bovenkamp-Langlois, G. Lisa, Miller, Jeffery T., Chattopadhyay, Soma, Shibata, Tomohiro, Losovyj, Yaroslav, Singh, Varshni, Theegala, Chandra, and Kumar, Challa S. S. R. Tue . "Investigation of the synthesis and characterization of platinum-DMSA nanoparticles using millifluidic chip reactor". United States. https://doi.org/10.1016/j.cej.2015.06.049. https://www.osti.gov/servlets/purl/1369707.
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@article{osti_1369707,
title = {Investigation of the synthesis and characterization of platinum-DMSA nanoparticles using millifluidic chip reactor},
author = {Navin, Chelliah V. and Krishna, Katla Sai and Bovenkamp-Langlois, G. Lisa and Miller, Jeffery T. and Chattopadhyay, Soma and Shibata, Tomohiro and Losovyj, Yaroslav and Singh, Varshni and Theegala, Chandra and Kumar, Challa S. S. R.},
abstractNote = {Here a continuous flow process for production of water-soluble Platinum-Dimercaptosuccinic acid (Pt(DMSA)) nanoparticles at ambient conditions using millifluidics is demonstrated. The process development was supported by in-situ synchrotron radiation-based X-ray absorption spectroscopy (XAS) investigations. The XAS revealed that the nucleation and growth of the Pt(DMSA) nanoparticles is extremely fast. Such a fast nucleation and growth process was also found to hinder coating of the channel walls, except at the zone 1 where the reactants first interact. The engineering of hitherto unreported Pt(DMSA) nanoparticles, well characterized using High-resolution transmission electron microscopy (HR-TEM), Scanning transmission electron microscopy (STEM), Scanning electron microscopy (SEM), Energy dispersive spectroscopy (EDS), Powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier transform infra-red spectroscopy (FT-IR), using continuous flow processes offers potential opportunities for scale-up.},
doi = {10.1016/j.cej.2015.06.049},
journal = {Chemical Engineering Journal},
number = C,
volume = 281,
place = {United States},
year = {Tue Jun 16 00:00:00 EDT 2015},
month = {Tue Jun 16 00:00:00 EDT 2015}
}
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https://doi.org/10.1016/j.cej.2015.06.049
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    Works referencing / citing this record:

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