Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates

Hossen, Md Mir; Bendickson, Lee; Palo, Pierre E.; Yao, Zhiqi; Nilsen-Hamilton, Marit; Hillier, Andrew C.

doi:10.1088/1361-6528/aacb16

Title: Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates

Abstract

Here, DNA origami can be used to create a variety of complex and geometrically unique nanostructures that can be further modified to produce building blocks for applications such as in optical metamaterials. We describe a method for creating metal-coated nanostructures using DNA origami templates and a photochemical metallization technique. Triangular DNA origami forms were fabricated and coated with a thin metal layer by photochemical silver reduction while in solution or supported on a surface. The DNA origami template serves as a localized photosensitizer to facilitate reduction of silver ions directly from solution onto the DNA surface. The metallizing process is shown to result in a conformal metal coating, which grows in height to a self-limiting value with increasing photoreduction steps. Although this coating process results in a slight decrease in the triangle dimensions, the overall template shape is retained. Notably, this coating method exhibits characteristics of self-limiting and defect-filling growth, which results in a metal nanostructure that maps the shape of the original DNA template with a continuous and uniform metal layer and stops growing once all available DNA sites are exhausted.

Authors:

Hossen, Md Mir ^[1]; Bendickson, Lee ^[1]; Palo, Pierre E. ^[1]; Yao, Zhiqi ^[1];

^[1];

^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)

Publication Date:: 2018-06-27

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1460379

Report Number(s):: IS-J-9702
Journal ID: ISSN 0957-4484

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Nanotechnology

Additional Journal Information:: Journal Volume: 29; Journal Issue: 35; Journal ID: ISSN 0957-4484

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

Subject:: 59 BASIC BIOLOGICAL SCIENCES; DNA; origami; metal nanostructures; metamaterials; photochemical; silver

Citation Formats


                    Hossen, Md Mir, Bendickson, Lee, Palo, Pierre E., Yao, Zhiqi, Nilsen-Hamilton, Marit, and Hillier, Andrew C. Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates.  United States: N. p., 2018. 
Web.  doi:10.1088/1361-6528/aacb16.

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                    Hossen, Md Mir, Bendickson, Lee, Palo, Pierre E., Yao, Zhiqi, Nilsen-Hamilton, Marit, & Hillier, Andrew C. Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates.  United States.  https://doi.org/10.1088/1361-6528/aacb16

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                    Hossen, Md Mir, Bendickson, Lee, Palo, Pierre E., Yao, Zhiqi, Nilsen-Hamilton, Marit, and Hillier, Andrew C. Wed .  
"Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates".  United States.  https://doi.org/10.1088/1361-6528/aacb16.  https://www.osti.gov/servlets/purl/1460379.

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@article{osti_1460379,

  title        = {Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates},

  author       = {Hossen, Md Mir and Bendickson, Lee and Palo, Pierre E. and Yao, Zhiqi and Nilsen-Hamilton, Marit and Hillier, Andrew C.},

  abstractNote = {Here, DNA origami can be used to create a variety of complex and geometrically unique nanostructures that can be further modified to produce building blocks for applications such as in optical metamaterials. We describe a method for creating metal-coated nanostructures using DNA origami templates and a photochemical metallization technique. Triangular DNA origami forms were fabricated and coated with a thin metal layer by photochemical silver reduction while in solution or supported on a surface. The DNA origami template serves as a localized photosensitizer to facilitate reduction of silver ions directly from solution onto the DNA surface. The metallizing process is shown to result in a conformal metal coating, which grows in height to a self-limiting value with increasing photoreduction steps. Although this coating process results in a slight decrease in the triangle dimensions, the overall template shape is retained. Notably, this coating method exhibits characteristics of self-limiting and defect-filling growth, which results in a metal nanostructure that maps the shape of the original DNA template with a continuous and uniform metal layer and stops growing once all available DNA sites are exhausted.},

  doi          = {10.1088/1361-6528/aacb16},

  journal      = {Nanotechnology},

  number       = 35,

  volume       = 29,

  place        = {United States},

  year         = {2018},

  month        = {6}

}

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Title: Creating metamaterial building blocks with directed photochemical metallization of silver onto DNA origami templates

Abstract

Citation Formats

Au-Nanoparticle Nanowires Based on DNA and Polylysine Templates journal, July 2002

Fabrication of optical negative-index metamaterials: Recent advances and outlook journal, May 2008

Connecting the Nanodots: Programmable Nanofabrication of Fused Metal Shapes on DNA Templates journal, August 2011

Metallization of DNA journal, February 2003

Building plasmonic nanostructures with DNA journal, April 2011

Plasmonic nanostructures through DNA-assisted lithography journal, February 2018

The self-assembling of DNA-templated Au nanoparticles into nanowires and their enhanced SERS and catalytic applications journal, January 2013

Metallic Nanostructures Based on DNA Nanoshapes journal, August 2016

Linear assemblies of nanoparticles electrostatically organized on DNA scaffolds journal, March 2003

The Evolution of Silicon Wafer Cleaning Technology journal, January 1990

DNA-Templated Photoinduced Silver Deposition journal, August 2005

Site-Specific Synthesis and In Situ Immobilization of Fluorescent Silver Nanoclusters on DNA Nanoscaffolds by Use of the Tollens Reaction journal, April 2011

UV-induced DNA damage and repair: a review journal, March 2002

Plasmonic staining of DNA molecules with photo-induced Ag nanoparticles monitored using dark-field microscopy journal, January 2013

Folding DNA to create nanoscale shapes and patterns journal, March 2006

Three-dimensional photonic metamaterials at optical frequencies journal, December 2007

Optimized Assembly and Covalent Coupling of Single-Molecule DNA Origami Nanoarrays journal, November 2014

Nanoscale Growth and Patterning of Inorganic Oxides Using DNA Nanostructure Templates journal, April 2013

Controlling Electromagnetic Fields journal, June 2006

DNA Origami with Complex Curvatures in Three-Dimensional Space journal, April 2011

Organization of 'nanocrystal molecules' using DNA journal, August 1996

DNA-based self-assembly of chiral plasmonic nanostructures with tailored optical response journal, March 2012

Casting inorganic structures with DNA molds journal, October 2014

DNA Origami-Templated Growth of Arbitrarily Shaped Metal Nanoparticles journal, May 2011

Controlled Nucleation of DNA Metallization journal, November 2008

Prescribed nanoparticle cluster architectures and low-dimensional arrays built using octahedral DNA origami frames journal, May 2015

Directed DNA Metallization journal, February 2006

Shape-Controlled Synthesis of Gold Nanostructures Using DNA Origami Molds journal, October 2014

Large-area spatially ordered arrays of gold nanoparticles directed by lithographically confined DNA origami journal, December 2009

Metamaterials: a new frontier of science and technology journal, January 2011

Metamaterial Electromagnetic Cloak at Microwave Frequencies journal, November 2006

Challenges in fabrication towards realization of practical metamaterials journal, September 2016

A DNA-based method for rationally assembling nanoparticles into macroscopic materials journal, August 1996

Custom-shaped metal nanostructures based on DNA origami silhouettes journal, January 2015

Anisotropic Electroless Deposition on DNA Origami Templates To Form Small Diameter Conductive Nanowires journal, January 2017

Photolytic Metallization of Au Nanoclusters and Electrically Conducting Micrometer Long Nanostructures on a DNA Scaffold journal, January 2008

Past achievements and future challenges in the development of three-dimensional photonic metamaterials journal, July 2011

Negative Refraction Makes a Perfect Lens journal, October 2000

Silver(I) Complexes with DNA and RNA Studied by Fourier Transform Infrared Spectroscopy and Capillary Electrophoresis journal, September 2001

Site-Specific Synthesis and In Situ Immobilization of Fluorescent Silver Nanoclusters on DNA Nanoscaffolds by Use of the Tollens Reaction journal, April 2011

Fabrication and temperature-dependent electrical characterization of a C-shape nanowire patterned by a DNA origami journal, January 2021

Imaging of Unstained DNA Origami Triangles with Electron Microscopy journal, August 2019

The remarkable UV light invulnerability of thymine GNA dinucleotides journal, January 2019

Au-Nanoparticle Nanowires Based on DNA and Polylysine Templates
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Fabrication of optical negative-index metamaterials: Recent advances and outlook
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Connecting the Nanodots: Programmable Nanofabrication of Fused Metal Shapes on DNA Templates
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Metallization of DNA
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Building plasmonic nanostructures with DNA
journal, April 2011

Plasmonic nanostructures through DNA-assisted lithography
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The self-assembling of DNA-templated Au nanoparticles into nanowires and their enhanced SERS and catalytic applications
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Metallic Nanostructures Based on DNA Nanoshapes
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Linear assemblies of nanoparticles electrostatically organized on DNA scaffolds
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The Evolution of Silicon Wafer Cleaning Technology
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DNA-Templated Photoinduced Silver Deposition
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Site-Specific Synthesis and In Situ Immobilization of Fluorescent Silver Nanoclusters on DNA Nanoscaffolds by Use of the Tollens Reaction
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UV-induced DNA damage and repair: a review
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Plasmonic staining of DNA molecules with photo-induced Ag nanoparticles monitored using dark-field microscopy
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Folding DNA to create nanoscale shapes and patterns
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Three-dimensional photonic metamaterials at optical frequencies
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Optimized Assembly and Covalent Coupling of Single-Molecule DNA Origami Nanoarrays
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Nanoscale Growth and Patterning of Inorganic Oxides Using DNA Nanostructure Templates
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Controlling Electromagnetic Fields
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DNA Origami with Complex Curvatures in Three-Dimensional Space
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Organization of 'nanocrystal molecules' using DNA
journal, August 1996

DNA-based self-assembly of chiral plasmonic nanostructures with tailored optical response
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Casting inorganic structures with DNA molds
journal, October 2014

DNA Origami-Templated Growth of Arbitrarily Shaped Metal Nanoparticles
journal, May 2011

Controlled Nucleation of DNA Metallization
journal, November 2008

Prescribed nanoparticle cluster architectures and low-dimensional arrays built using octahedral DNA origami frames
journal, May 2015

Directed DNA Metallization
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Shape-Controlled Synthesis of Gold Nanostructures Using DNA Origami Molds
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Large-area spatially ordered arrays of gold nanoparticles directed by lithographically confined DNA origami
journal, December 2009

Metamaterials: a new frontier of science and technology
journal, January 2011

Metamaterial Electromagnetic Cloak at Microwave Frequencies
journal, November 2006

Challenges in fabrication towards realization of practical metamaterials
journal, September 2016

A DNA-based method for rationally assembling nanoparticles into macroscopic materials
journal, August 1996

Custom-shaped metal nanostructures based on DNA origami silhouettes
journal, January 2015

Anisotropic Electroless Deposition on DNA Origami Templates To Form Small Diameter Conductive Nanowires
journal, January 2017

Photolytic Metallization of Au Nanoclusters and Electrically Conducting Micrometer Long Nanostructures on a DNA Scaffold
journal, January 2008

Past achievements and future challenges in the development of three-dimensional photonic metamaterials
journal, July 2011

Negative Refraction Makes a Perfect Lens
journal, October 2000

Silver(I) Complexes with DNA and RNA Studied by Fourier Transform Infrared Spectroscopy and Capillary Electrophoresis
journal, September 2001

Site-Specific Synthesis and In Situ Immobilization of Fluorescent Silver Nanoclusters on DNA Nanoscaffolds by Use of the Tollens Reaction
journal, April 2011

Fabrication and temperature-dependent electrical characterization of a C-shape nanowire patterned by a DNA origami
journal, January 2021

Imaging of Unstained DNA Origami Triangles with Electron Microscopy
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