Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power

Brethome, Flavien M.; Williams, Neil J.; A Seipp, Charles; Kidder, Michelle; Custelcean, Radu

doi:10.1038/s41560-018-0150-z

Title: Direct air capture of CO₂ via aqueous-phase absorption and crystalline-phase release using concentrated solar power

Abstract

Using negative emissions technologies for the net removal of greenhouse gases from the atmosphere could provide a pathway to limit global temperature rises. Direct air capture of carbon dioxide offers the prospect of permanently lowering the atmospheric CO₂ concentration, providing that economical and energy-efficient technologies can be developed and deployed on a large scale. Here in this paper, we report an approach to direct air capture, at the laboratory scale, using mostly off-the-shelf materials and equipment. First, CO₂ absorption is achieved with readily available and environmentally friendly aqueous amino acid solutions (glycine and sarcosine) using a household humidifier. The CO₂-loaded solutions are then reacted with a simple guanidine compound, which crystallizes as a very insoluble carbonate salt and regenerates the amino acid sorbent. Finally, effective CO₂ release and near-quantitative regeneration of the guanidine compound are achieved by relatively mild heating of the carbonate crystals using concentrated solar power.

Authors:

Brethome, Flavien M. ^[1];

^[1]; A Seipp, Charles ^[1];

^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Publication Date:: Mon May 07 00:00:00 EDT 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1460227

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Nature Energy

Additional Journal Information:: Journal Volume: 3; Journal Issue: 7; Journal ID: ISSN 2058-7546

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 14 SOLAR ENERGY; 54 ENVIRONMENTAL SCIENCES

Citation Formats


                    Brethome, Flavien M., Williams, Neil J., A Seipp, Charles, Kidder, Michelle, and Custelcean, Radu. Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power.  United States: N. p., 2018. 
Web.  doi:10.1038/s41560-018-0150-z.

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                    Brethome, Flavien M., Williams, Neil J., A Seipp, Charles, Kidder, Michelle, & Custelcean, Radu. Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power.  United States.  https://doi.org/10.1038/s41560-018-0150-z

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                    Brethome, Flavien M., Williams, Neil J., A Seipp, Charles, Kidder, Michelle, and Custelcean, Radu. Mon .  
"Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power".  United States.  https://doi.org/10.1038/s41560-018-0150-z.  https://www.osti.gov/servlets/purl/1460227.

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@article{osti_1460227,

  title        = {Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power},

  author       = {Brethome, Flavien M. and Williams, Neil J. and A Seipp, Charles and Kidder, Michelle and Custelcean, Radu},

  abstractNote = {Using negative emissions technologies for the net removal of greenhouse gases from the atmosphere could provide a pathway to limit global temperature rises. Direct air capture of carbon dioxide offers the prospect of permanently lowering the atmospheric CO2 concentration, providing that economical and energy-efficient technologies can be developed and deployed on a large scale. Here in this paper, we report an approach to direct air capture, at the laboratory scale, using mostly off-the-shelf materials and equipment. First, CO2 absorption is achieved with readily available and environmentally friendly aqueous amino acid solutions (glycine and sarcosine) using a household humidifier. The CO2-loaded solutions are then reacted with a simple guanidine compound, which crystallizes as a very insoluble carbonate salt and regenerates the amino acid sorbent. Finally, effective CO2 release and near-quantitative regeneration of the guanidine compound are achieved by relatively mild heating of the carbonate crystals using concentrated solar power.},

  doi          = {10.1038/s41560-018-0150-z},

  journal      = {Nature Energy},

  number       = 7,

  volume       = 3,

  place        = {United States},

  year         = {Mon May 07 00:00:00 EDT 2018},

  month        = {Mon May 07 00:00:00 EDT 2018}

}

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Works referencing / citing this record:

Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO ₂ Reduction
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Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO ₂ Reduction
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Simulation of carbon dioxide absorption by amino acids in two-phase batch and bubble column reactors
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Gabitto, Jorge; Custelcean, Radu; Tsouris, Costas
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Direct air capture of CO ₂ – topological analysis of the experimental electron density (QTAIM) of the highly insoluble carbonate salt of a 2,6-pyridine-bis(iminoguanidine), (PyBIGH ₂ )(CO ₃ )(H ₂ O) ₄
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Li, Chengcheng; Wang, Tuo; Liu, Bin
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Recent advances in self-assembled amidinium and guanidinium frameworks
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Title: Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power

Abstract

Citation Formats

State of the Climate in 2016 journal, August 2017

Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent journal, December 2011

Comprehensive Study of the Hydration and Dehydration Reactions of Carbon Dioxide in Aqueous Solution journal, December 2009

Why Capture CO2 from the Atmosphere? journal, September 2009

Negative emissions physically needed to keep global warming below 2 °C journal, August 2015

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Moisture-swing sorption for carbon dioxide capture from ambient air: a thermodynamic analysis journal, January 2013

Young people's burden: requirement of negative CO 2 emissions journal, January 2017

Protonation Constants and Thermodynamic Properties of Amino Acid Salts for CO 2 Capture at High Temperatures journal, July 2014

The urgency of the development of CO2 capture from ambient air journal, July 2012

Slicing the pie: how big could carbon dioxide removal be?: Slicing the pie journal, July 2017

Amine–Oxide Hybrid Materials for CO 2 Capture from Ambient Air journal, September 2015

Conceptual Design of a Novel CO 2 Capture Process Based on Precipitating Amino Acid Solvents journal, August 2013

A calorimetric study of carbamate formation journal, May 2011

Amino Acids as Carbon Capture Solvents: Chemical Kinetics and Mechanism of the Glycine + CO 2 Reaction journal, June 2013

Energy and Material Balance of CO 2 Capture from Ambient Air journal, November 2007

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc) journal, April 2012

CO 2 Capture from Ambient Air by Crystallization with a Guanidine Sorbent journal, December 2016

Aqueous Sulfate Separation by Sequestration of [(SO 4 ) 2 (H 2 O) 4 ] 4− Clusters within Highly Insoluble Imine-Linked Bis-Guanidinium Crystals journal, December 2015

Moisture Swing Sorbent for Carbon Dioxide Capture from Ambient Air journal, August 2011

CO2 Capture Using Phase-Changing Sorbents journal, March 2012

Amine-Based Nanofibrillated Cellulose As Adsorbent for CO 2 Capture from Air journal, October 2011

The urgency of the development of CO2 capture from ambient air text, January 2012

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Carbon Dioxide Capture from Air Using Amine-Grafted Porous Polymer Networks journal, February 2013

Characterization of kinetic limitations to atmospheric CO 2 capture by solid sorbent : Characterization of kinetic limitations to atmospheric CO2 capture by solid sorbent journal, September 2015

CO2 capture from atmospheric air via consecutive CaO-carbonation and CaCO3-calcination cycles in a fluidized-bed solar reactor journal, February 2009

Direct Capture of CO2 from Ambient Air journal, August 2016

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Kinetics of the Reversible Reaction of CO 2 (aq) and HCO 3 – with Sarcosine Salt in Aqueous Solution journal, October 2012

A CALORIMETRIC STUDY OF THE HEAT OF IONIZATION OF WATER AT 25° 1a journal, December 1963

The Solubility of Carbon Dioxide in Water at Low Pressure journal, November 1991

Committed warming inferred from observations journal, July 2017

Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO 2 Reduction journal, November 2019

Fundamentals and applications of photocatalytic CO2 methanation journal, July 2019

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Direct air capture of CO 2 – topological analysis of the experimental electron density (QTAIM) of the highly insoluble carbonate salt of a 2,6-pyridine-bis(iminoguanidine), (PyBIGH 2 )(CO 3 )(H 2 O) 4 journal, January 2019

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Title: Direct air capture of CO₂ via aqueous-phase absorption and crystalline-phase release using concentrated solar power

State of the Climate in 2016
journal, August 2017

Carbon Dioxide Capture from the Air Using a Polyamine Based Regenerable Solid Adsorbent
journal, December 2011

Comprehensive Study of the Hydration and Dehydration Reactions of Carbon Dioxide in Aqueous Solution
journal, December 2009

Why Capture CO2 from the Atmosphere?
journal, September 2009

Negative emissions physically needed to keep global warming below 2 °C
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An air–liquid contactor for large-scale capture of CO ₂ from air
journal, September 2012

Moisture-swing sorption for carbon dioxide capture from ambient air: a thermodynamic analysis
journal, January 2013

Young people's burden: requirement of negative CO ₂ emissions
journal, January 2017

Protonation Constants and Thermodynamic Properties of Amino Acid Salts for CO ₂ Capture at High Temperatures
journal, July 2014

The urgency of the development of CO2 capture from ambient air
journal, July 2012

Slicing the pie: how big could carbon dioxide removal be?: Slicing the pie
journal, July 2017

Amine–Oxide Hybrid Materials for CO ₂ Capture from Ambient Air
journal, September 2015

Conceptual Design of a Novel CO ₂ Capture Process Based on Precipitating Amino Acid Solvents
journal, August 2013

A calorimetric study of carbamate formation
journal, May 2011

Amino Acids as Carbon Capture Solvents: Chemical Kinetics and Mechanism of the Glycine + CO ₂ Reaction
journal, June 2013

Energy and Material Balance of CO ₂ Capture from Ambient Air
journal, November 2007

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg₂(dobpdc)
journal, April 2012

CO ₂ Capture from Ambient Air by Crystallization with a Guanidine Sorbent
journal, December 2016

Aqueous Sulfate Separation by Sequestration of [(SO ₄ ) ₂ (H ₂ O) ₄ ] ⁴⁻ Clusters within Highly Insoluble Imine-Linked Bis-Guanidinium Crystals
journal, December 2015

Moisture Swing Sorbent for Carbon Dioxide Capture from Ambient Air
journal, August 2011

CO₂ Capture Using Phase-Changing Sorbents
journal, March 2012

Amine-Based Nanofibrillated Cellulose As Adsorbent for CO ₂ Capture from Air
journal, October 2011

The urgency of the development of CO2 capture from ambient air
text, January 2012

Carbon Dioxide Capture from Atmospheric Air Using Sodium Hydroxide Spray
journal, April 2008

Carbon Dioxide Capture from Air Using Amine-Grafted Porous Polymer Networks
journal, February 2013

Characterization of kinetic limitations to atmospheric CO ₂ capture by solid sorbent : Characterization of kinetic limitations to atmospheric CO2 capture by solid sorbent
journal, September 2015

CO2 capture from atmospheric air via consecutive CaO-carbonation and CaCO3-calcination cycles in a fluidized-bed solar reactor
journal, February 2009

Direct Capture of CO₂ from Ambient Air
journal, August 2016

Process design and energy requirements for the capture of carbon dioxide from air
journal, December 2006

Kinetics of the Reversible Reaction of CO ₂ (aq) and HCO ₃ ^– with Sarcosine Salt in Aqueous Solution
journal, October 2012

A CALORIMETRIC STUDY OF THE HEAT OF IONIZATION OF WATER AT 25° ^1a
journal, December 1963

The Solubility of Carbon Dioxide in Water at Low Pressure
journal, November 1991

Committed warming inferred from observations
journal, July 2017

Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO ₂ Reduction
journal, November 2019

Fundamentals and applications of photocatalytic CO2 methanation
journal, July 2019

Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO ₂ Reduction
journal, November 2019

CO 2 absorption from simulated flue gas in a bubble column
journal, February 2019

Simulation of carbon dioxide absorption by amino acids in two-phase batch and bubble column reactors
journal, February 2019

Direct air capture of CO ₂ – topological analysis of the experimental electron density (QTAIM) of the highly insoluble carbonate salt of a 2,6-pyridine-bis(iminoguanidine), (PyBIGH ₂ )(CO ₃ )(H ₂ O) ₄
journal, January 2019

Photoelectrochemical CO ₂ reduction to adjustable syngas on grain-boundary-mediated a-Si/TiO ₂ /Au photocathodes with low onset potentials
journal, January 2019

Fundamentals and applications of photocatalytic CO2 methanation
journal, July 2019

Recent advances in self-assembled amidinium and guanidinium frameworks
journal, January 2019