Automated Separation of Uranium and Plutonium from Environmental Swipe Samples for Multiple Collector Inductively Coupled Plasma Mass Spectrometry
Abstract
A fully automated method for the separation of low-concentration uranium from plutonium in environmental swipe samples has been developed. The offline chromatography system features renewable 1 mL Eichrom TEVA and UTEVA column generation from bulk resin slurry. Discrete fractions of the separated actinides are delivered into user defined vials for future analysis. Clean room background levels were achieved outside of a cleanroom environment with this method. Purification of uranium and plutonium from various sample matrixes and at various concentrations was successful. Major and minor isotope ratios for both elements were measured via multiple collector inductively coupled plasma mass spectrometry and were in good agreement with certified reference values. Lastly, validation of the separation method was conducted on archived environmental samples and agreed with values previously reported using standard column chemistry.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1460201
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Analytical Chemistry
- Additional Journal Information:
- Journal Volume: 90; Journal Issue: 15; Journal ID: ISSN 0003-2700
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Automated Separations; TEVA; UTEVA; Uranium; Plutonium; ICP–MS; Environmental Samples
Citation Formats
Metzger, Shalina C., Ticknor, Brian W., Rogers, Kayron T., Bostick, Debra A., McBay, Eddy H., and Hexel, Cole R. Automated Separation of Uranium and Plutonium from Environmental Swipe Samples for Multiple Collector Inductively Coupled Plasma Mass Spectrometry. United States: N. p., 2018.
Web. doi:10.1021/acs.analchem.8b02095.
Metzger, Shalina C., Ticknor, Brian W., Rogers, Kayron T., Bostick, Debra A., McBay, Eddy H., & Hexel, Cole R. Automated Separation of Uranium and Plutonium from Environmental Swipe Samples for Multiple Collector Inductively Coupled Plasma Mass Spectrometry. United States. https://doi.org/10.1021/acs.analchem.8b02095
Metzger, Shalina C., Ticknor, Brian W., Rogers, Kayron T., Bostick, Debra A., McBay, Eddy H., and Hexel, Cole R. Sun .
"Automated Separation of Uranium and Plutonium from Environmental Swipe Samples for Multiple Collector Inductively Coupled Plasma Mass Spectrometry". United States. https://doi.org/10.1021/acs.analchem.8b02095. https://www.osti.gov/servlets/purl/1460201.
@article{osti_1460201,
title = {Automated Separation of Uranium and Plutonium from Environmental Swipe Samples for Multiple Collector Inductively Coupled Plasma Mass Spectrometry},
author = {Metzger, Shalina C. and Ticknor, Brian W. and Rogers, Kayron T. and Bostick, Debra A. and McBay, Eddy H. and Hexel, Cole R.},
abstractNote = {A fully automated method for the separation of low-concentration uranium from plutonium in environmental swipe samples has been developed. The offline chromatography system features renewable 1 mL Eichrom TEVA and UTEVA column generation from bulk resin slurry. Discrete fractions of the separated actinides are delivered into user defined vials for future analysis. Clean room background levels were achieved outside of a cleanroom environment with this method. Purification of uranium and plutonium from various sample matrixes and at various concentrations was successful. Major and minor isotope ratios for both elements were measured via multiple collector inductively coupled plasma mass spectrometry and were in good agreement with certified reference values. Lastly, validation of the separation method was conducted on archived environmental samples and agreed with values previously reported using standard column chemistry.},
doi = {10.1021/acs.analchem.8b02095},
journal = {Analytical Chemistry},
number = 15,
volume = 90,
place = {United States},
year = {Sun Jul 29 00:00:00 EDT 2018},
month = {Sun Jul 29 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Strengthening IAEA safeguards through environmental sampling and analysis
journal, June 1998
- Donohue, D. L.
- Journal of Alloys and Compounds, Vol. 271-273
Mass spectrometric analysis for nuclear safeguards
journal, January 2015
- Boulyga, Sergei; Konegger-Kappel, Stefanie; Richter, Stephan
- Journal of Analytical Atomic Spectrometry, Vol. 30, Issue 7
Uranium isotope analysis by MC-ICP-MS in sub-ng sized samples
journal, January 2016
- Boulyga, Sergei F.; Koepf, Andreas; Konegger-Kappel, Stefanie
- Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 11
Radionuclide determination in environmental samples by inductively coupled plasma mass spectrometry
journal, August 2006
- Lariviere, Dominic; Taylor, Vivien F.; Evans, R. Douglas
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 61, Issue 8
Separation of actinides from spent nuclear fuel: A review
journal, November 2016
- Veliscek-Carolan, Jessica
- Journal of Hazardous Materials, Vol. 318
A review on solid phase extraction of actinides and lanthanides with amide based extractants
journal, May 2017
- Ansari, Seraj A.; Mohapatra, Prasanta K.
- Journal of Chromatography A, Vol. 1499
Separation and preconcentration of uranium from acidic media by extraction chromatography
journal, August 1992
- Horwitz, E. Philip; Dietz, Mark L.; Chiarizia, Renato
- Analytica Chimica Acta, Vol. 266, Issue 1
Separation and preconcentration of actinides by extraction chromatography using a supported liquid anion exchanger: application to the characterization of high-level nuclear waste solutions
journal, June 1995
- Horwitz, E. Philip; Dietz, Mark L.; Chiarizia, Renato
- Analytica Chimica Acta, Vol. 310, Issue 1
Determination of plutonium concentration and its isotopic ratio in environmental materials by ICP-MS after separation using and extraction chromatography
journal, January 1999
- Muramatsu, Yasuyuki; Uchida, Shigeo; Tagami, Keiko
- Journal of Analytical Atomic Spectrometry, Vol. 14, Issue 5
Rapid isolation of plutonium in environmental solid samples using sequential injection anion exchange chromatography followed by detection with inductively coupled plasma mass spectrometry
journal, January 2011
- Qiao, Jixin; Hou, Xiaolin; Roos, Per
- Analytica Chimica Acta, Vol. 685, Issue 2
Sequential Injection Renewable Separation Column Instrument for Automated Sorbent Extraction Separations of Radionuclides
journal, December 1998
- Egorov, Oleg; O'Hara, Matthew J.; Grate, Jay W.
- Analytical Chemistry, Vol. 71, Issue 2
An automated chromatography procedure optimized for analysis of stable Cu isotopes from biological materials
journal, January 2016
- Enge, T. Gabriel; Field, M. Paul; Jolley, Dianne F.
- Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 10
Automated Analysis of Radionuclides in Nuclear Waste: Rapid Determination of 90 Sr by Sequential Injection Analysis
journal, January 1996
- Grate, Jay W.; Strebin, Robert; Janata, Jiri
- Analytical Chemistry, Vol. 68, Issue 2
Automated pressurized injection system for the separation of actinides by extraction chromatography
journal, August 2012
- Guérin, Nicolas; Nadeau, Kenny; Potvin, Sabrina
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 295, Issue 3
Automated solid phase extraction of theophylline by sequential injection on renewable column
journal, January 1998
- Dockendorff, Brian; Holman, David A.; Christian, Gary D.
- Analytical Communications, Vol. 35, Issue 11
Automated extraction chromatographic separations of actinides using separation-optimized sequential injection techniques
journal, January 1999
- Grate, Jay W.; Egorov, Oleg B.; Fiskum, Sandra K.
- The Analyst, Vol. 124, Issue 8
A rapid and efficient automated method for the sequential separation of plutonium and radiostrontium in seawater
journal, September 2014
- Kim, Hyuncheol; Chung, Kun Ho; Jung, Yoonhee
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 304, Issue 1
Design and performance of an automated radionuclide separator: Its application on the determination of 99Tc in groundwater
journal, November 2013
- Chung, Kun Ho; Choi, Sang Do; Choi, Geun Sik
- Applied Radiation and Isotopes, Vol. 81
Sequential Injection Method for Rapid and Simultaneous Determination of 236 U, 237 Np, and Pu Isotopes in Seawater
journal, November 2013
- Qiao, Jixin; Hou, Xiaolin; Steier, Peter
- Analytical Chemistry, Vol. 85, Issue 22
Bead Injection Extraction Chromatography Using High-Capacity Lab-on-Valve as a Front End to Inductively Coupled Plasma Mass Spectrometry for Urine Radiobioassay
journal, February 2013
- Qiao, Jixin; Hou, Xiaolin; Roos, Per
- Analytical Chemistry, Vol. 85, Issue 5
Peer Reviewed: From Flow Injection to Bead Injection.
journal, April 1999
- Ruzicka, Jaromir; Scampavia, Louis
- Analytical Chemistry, Vol. 71, Issue 7
Fully automated chromatographic purification of Sr and Ca for isotopic analysis
journal, January 2015
- Romaniello, S. J.; Field, M. P.; Smith, H. B.
- Journal of Analytical Atomic Spectrometry, Vol. 30, Issue 9
Round-robins in the area of uranium and plutonium bulk analysis of environmental samples
journal, August 2012
- Pointurier, Fabien; Williams, Ross W.; LaMont, Stephen P.
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 296, Issue 2
Spectral interferences in the determination of trace elements in environmental materials by inductively coupled plasma atomic emission spectrometry
journal, July 1999
- Daskalova, N.; Boevski, Iv.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 54, Issue 7
Works referencing / citing this record:
Evaluation and Specifications for In-Line Uranium Separations Using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) Detection for Trace Elemental Analysis
journal, March 2019
- Manard, Benjamin T.; Metzger, Shalina C.; Quarles, C. Derrick
- Applied Spectroscopy, Vol. 73, Issue 8
Development and comparison of two high accuracy methods for uranium concentration in nuclear fuel: ID-TIMS and K-edge densitometry
journal, July 2019
- Quemet, Alexandre; Ruas, Alexandre; Esbelin, Eric
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 321, Issue 3