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Title: Exploration of the Na x MoO 2 phase diagram for low sodium contents ( x ≤ 0.5)


Phase diagram in the Na x MoO 2 system ( x ≤ 0.5) determined using electrochemistry and in situ X-ray powder diffraction.

 [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. CNRS, Univ. Bordeaux, Bordeaux INP, F-33600 Pessac, France
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Sponsoring Org.:
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Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry A Journal Volume: 6 Journal Issue: 30; Journal ID: ISSN 2050-7488
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom

Citation Formats

Vitoux, Laura, Guignard, Marie, Darriet, Jacques, and Delmas, Claude. Exploration of the Na x MoO 2 phase diagram for low sodium contents ( x ≤ 0.5). United Kingdom: N. p., 2018. Web. doi:10.1039/C8TA04224A.
Vitoux, Laura, Guignard, Marie, Darriet, Jacques, & Delmas, Claude. Exploration of the Na x MoO 2 phase diagram for low sodium contents ( x ≤ 0.5). United Kingdom. doi:10.1039/C8TA04224A.
Vitoux, Laura, Guignard, Marie, Darriet, Jacques, and Delmas, Claude. Mon . "Exploration of the Na x MoO 2 phase diagram for low sodium contents ( x ≤ 0.5)". United Kingdom. doi:10.1039/C8TA04224A.
title = {Exploration of the Na x MoO 2 phase diagram for low sodium contents ( x ≤ 0.5)},
author = {Vitoux, Laura and Guignard, Marie and Darriet, Jacques and Delmas, Claude},
abstractNote = {Phase diagram in the Na x MoO 2 system ( x ≤ 0.5) determined using electrochemistry and in situ X-ray powder diffraction.},
doi = {10.1039/C8TA04224A},
journal = {Journal of Materials Chemistry A},
number = 30,
volume = 6,
place = {United Kingdom},
year = {2018},
month = {1}

Journal Article:
Free Publicly Available Full Text
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DOI: 10.1039/C8TA04224A

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Works referenced in this record:

Vacancy Ordering in O 3 -Type Layered Metal Oxide Sodium-Ion Battery Cathodes
journal, December 2015

Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015

  • Kubota, Kei; Komaba, Shinichi
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0151514jes

Electrochemical Na-Deintercalation from NaVO2
journal, January 2011

  • Didier, C.; Guignard, M.; Denage, C.
  • Electrochemical and Solid-State Letters, Vol. 14, Issue 5
  • DOI: 10.1149/1.3555102

Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010

  • Berthelot, R.; Carlier, D.; Delmas, C.
  • Nature Materials, Vol. 10, Issue 1
  • DOI: 10.1038/nmat2920

Sodium and Sodium-Ion Batteries: 50 Years of Research
journal, February 2018

P2-NaxVO2 system as electrodes for batteries and electron-correlated materials
journal, November 2012

  • Guignard, Marie; Didier, Christophe; Darriet, Jacques
  • Nature Materials, Vol. 12, Issue 1
  • DOI: 10.1038/nmat3478

Sodium deintercalation from sodium iron oxide
journal, June 1994

The Na x MoO 2 Phase Diagram ( 1 / 2x < 1): An Electrochemical Devil’s Staircase
journal, August 2017

Structural characterisation of the highly deintercalated LixNi1.02O2 phases (with x ≤ 0.30)
journal, January 2001

  • Croguennec, L.; Pouillerie, C.; Mansour, A. N.
  • Journal of Materials Chemistry, Vol. 11, Issue 1
  • DOI: 10.1039/b003377o

Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides
journal, January 1982

Sodium intercalation into the layer oxides NaxMo2O4
journal, December 1986

Structural study of NiO2 and CoO2 as end members of the lithiated compounds by in situ high resolution X-ray powder diffraction
journal, September 1999

�ber Alkalimanganate(III) bis (V)
journal, October 1969

  • Scholder, R.; Protzer, U.
  • Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 369, Issue 3-6
  • DOI: 10.1002/zaac.19693690321

NaxVO2 as possible electrode for Na-ion batteries
journal, September 2011

Alkali Metal-Nickel Oxides of the Type MNiO 2
journal, March 1954

  • Dyer, Lawrence D.; Borie, Bernard S.; Smith, G. Pedro
  • Journal of the American Chemical Society, Vol. 76, Issue 6
  • DOI: 10.1021/ja01635a012

Electrochemical intercalation of sodium in NaxCoO2 bronzes
journal, August 1981

PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013

P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries
journal, April 2015

  • Wang, Yuesheng; Xiao, Ruijuan; Hu, Yong-Sheng
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7954

Oxygen Vacancies and Intermediate Spin Trivalent Cobalt Ions in Lithium-Overstoichiometric LiCoO 2
journal, January 2003

  • Levasseur, Stéphane; Ménétrier, Michel; Shao-Horn, Yang
  • Chemistry of Materials, Vol. 15, Issue 1
  • DOI: 10.1021/cm021279g

Crystal Structures and Electrode Performance of Alpha-NaFeO2 for Rechargeable Sodium Batteries
journal, January 2012

Structural evolution and electrochemistry of monoclinic NaNiO2 upon the first cycling process
journal, July 2014

Patterning of sodium ions and the control of electrons in sodium cobaltate
journal, February 2007

  • Roger, M.; Morris, D. J. P.; Tennant, D. A.
  • Nature, Vol. 445, Issue 7128
  • DOI: 10.1038/nature05531

Sur quelques nouvelles phases de formule NaxMnO2 (x ⩽ 1)
journal, February 1971

  • Parant, Jean-Paul; Olazcuaga, Roger; Devalette, Michel
  • Journal of Solid State Chemistry, Vol. 3, Issue 1
  • DOI: 10.1016/0022-4596(71)90001-6

In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2]
journal, January 2001

  • Lu, Zhonghua; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 148, Issue 11
  • DOI: 10.1149/1.1407247

O3–Na x Mn 1/3 Fe 2/3 O 2 as a positive electrode material for Na-ion batteries: structural evolutions and redox mechanisms upon Na + (de)intercalation
journal, January 2015

  • Mortemard de Boisse, B.; Cheng, J. -H.; Carlier, D.
  • Journal of Materials Chemistry A, Vol. 3, Issue 20
  • DOI: 10.1039/C4TA06688J

Using a Battery to Synthesize New Vanadium Oxides
journal, July 2017

CoO2, The End Member of the LixCoO2 Solid Solution
journal, January 1996

  • Amatucci, G. G.; Tarascon, J. M.; Klein, L. C.
  • Journal of The Electrochemical Society, Vol. 143, Issue 3, p. 1114-1123
  • DOI: 10.1149/1.1836594

The LixNi1−yMgyO2 (y=0.05, 0.10) system: structural modifications observed upon cycling
journal, July 2000

Electrochemical intercalation and deintercalation of NaxMnO2 bronzes
journal, May 1985

A study of the Na x TiO2 system by electrochemical deintercalation
journal, January 1983

  • Maazaz, A.; Delmas, C.; Hagenmuller, P.
  • Journal of Inclusion Phenomena, Vol. 1, Issue 1
  • DOI: 10.1007/BF00658014

Sodium-ion batteries: present and future
journal, January 2017

  • Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook
  • Chemical Society Reviews, Vol. 46, Issue 12
  • DOI: 10.1039/C6CS00776G

O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries
journal, December 2014

Sur de nouveaux bronzes oxygénés de formule NaχCoO2 (χ1). Le système cobalt-oxygène-sodium
journal, April 1973

P2-Na x Mn 1/2 Fe 1/2 O 2 Phase Used as Positive Electrode in Na Batteries: Structural Changes Induced by the Electrochemical (De)intercalation Process
journal, September 2014

  • Mortemard de Boisse, Benoit; Carlier, Dany; Guignard, Marie
  • Inorganic Chemistry, Vol. 53, Issue 20
  • DOI: 10.1021/ic5017802

Crystallographic Computing System JANA2006: General features
journal, January 2014

  • Petříček, Václav; Dušek, Michal; Palatinus, Lukáš
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 229, Issue 5
  • DOI: 10.1515/zkri-2014-1737

Electrochemically Reversible Sodium Intercalation of Layered NaNi0.5Mn0.5O2 and NaCrO2
conference, January 2009

  • Komaba, Shinichi; Nakayama, Tetsuri; Ogata, Atsushi
  • 214th ECS Meeting, ECS Transactions
  • DOI: 10.1149/1.3112727

Electrochemical Properties of Monoclinic NaNiO 2
journal, November 2012

  • Vassilaras, Plousia; Ma, Xiaohua; Li, Xin
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.023302jes

Etude par desintercalation electrochimique des systemes NaxCrO2 et NaxNiO2
journal, August 1982

New extended clusters in ternary molybdenum oxides
journal, March 1985

Layered alkali rhodium oxides AxRhO2: Topotactic solvation, exchange, and redox reactions
journal, November 1987