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This content will become publicly available on June 29, 2019

Title: Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium

Combined structural/electrochemical/computational studies of ceric Ce[OSi(O t Bu) 3 ] 4 and cerous [Ce{OSi(O t Bu) 3 } 4 ][K(2.2.2-crypt)] suggest a redox-modulated coordination switch of a tris( tert -butoxy)siloxy ligand.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [1]
  1. Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, 72076 Tübingen, Germany
  2. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, USA
Publication Date:
Grant/Contract Number:
SC0017259
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Related Information: CHORUS Timestamp: 2018-07-12 06:02:03; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1460011