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Title: Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium

Combined structural/electrochemical/computational studies of ceric Ce[OSi(O t Bu) 3 ] 4 and cerous [Ce{OSi(O t Bu) 3 } 4 ][K(2.2.2-crypt)] suggest a redox-modulated coordination switch of a tris( tert -butoxy)siloxy ligand.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [1]
  1. Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, 72076 Tübingen, Germany
  2. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, USA
Publication Date:
Grant/Contract Number:
SC0017259
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 30; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1460011

Friedrich, Jochen, Qiao, Yusen, Maichle-Mössmer, Cäcilia, Schelter, Eric J., and Anwander, Reiner. Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium. United Kingdom: N. p., Web. doi:10.1039/C8DT01878B.
Friedrich, Jochen, Qiao, Yusen, Maichle-Mössmer, Cäcilia, Schelter, Eric J., & Anwander, Reiner. Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium. United Kingdom. doi:10.1039/C8DT01878B.
Friedrich, Jochen, Qiao, Yusen, Maichle-Mössmer, Cäcilia, Schelter, Eric J., and Anwander, Reiner. 2018. "Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium". United Kingdom. doi:10.1039/C8DT01878B.
@article{osti_1460011,
title = {Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium},
author = {Friedrich, Jochen and Qiao, Yusen and Maichle-Mössmer, Cäcilia and Schelter, Eric J. and Anwander, Reiner},
abstractNote = {Combined structural/electrochemical/computational studies of ceric Ce[OSi(O t Bu) 3 ] 4 and cerous [Ce{OSi(O t Bu) 3 } 4 ][K(2.2.2-crypt)] suggest a redox-modulated coordination switch of a tris( tert -butoxy)siloxy ligand.},
doi = {10.1039/C8DT01878B},
journal = {Dalton Transactions},
number = 30,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {1}
}

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