skip to main content

DOE PAGESDOE PAGES

This content will become publicly available on June 25, 2019

Title: Hybrid Polymer/Metal–Organic Framework Films for Colorimetric Water Sensing over a Wide Concentration Range [Hybrid Polymer/MOF Films for Colorimetric Water Sensing over a Wide Concentration Range]

Because of their extraordinary surface areas and tailorable porosity, metal–organic frameworks (MOFs) have the potential to be excellent sensors of gas-phase analytes. MOFs with open metal sites are particularly attractive for detecting Lewis basic atmospheric analytes, such as water. Here, we demonstrate that thin films of the MOF HKUST-1 can be used to quantitatively determine the relative humidity (RH) of air using a colorimetric approach. HKUST-1 thin films are spin-coated onto rigid or flexible substrates and are shown to quantitatively determine the RH within the range of 0.1–5% RH by either visual observation or a straightforward optical reflectivity measurement. At high humidity (>10% RH), a polymer/MOF bilayer is used to slow the transport of H 2O to the MOF film, enabling quantitative determination of RH using time as the distinguishing metric. Lastly, the sensor is combined with an inexpensive light-emitting diode light source and Si photodiode detector to demonstrate a quantitative humidity detector for low humidity environments.
Authors:
 [1] ;  [1] ;  [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1]
  1. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Publication Date:
Report Number(s):
SAND-2018-5974J
Journal ID: ISSN 1944-8244; 664014
Grant/Contract Number:
AC04-94AL85000
Type:
Accepted Manuscript
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Volume: 10; Journal Issue: 28; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society (ACS)
Research Org:
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org:
USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; colorimetric sensing; HKUST-1; humidity detection; metal−organic framework; open metal site; polymer; thin film
OSTI Identifier:
1459992