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Title: Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors

Abstract

Layered halide hybrid organic–inorganic perovskites (HOP) have been the subject of intense investigation before the rise of three-dimensional (3D) HOP and their impressive performance in solar cells. Recently, layered HOP have also been proposed as attractive alternatives for photostable solar cells and revisited for light-emitting devices. Here, we combine classical solid-state physics concepts with simulation tools based on density functional theory to overview the main features of the optoelectronic properties of layered HOP. A detailed comparison between layered and 3D HOP is performed to highlight differences and similarities. In the same way as the cubic phase was established for 3D HOP, here we introduce the tetragonal phase with D4h symmetry as the reference phase for 2D monolayered HOP. It allows for detailed analysis of the spin–orbit coupling effects and structural transitions with corresponding electronic band folding. We further investigate the effects of octahedral tilting on the band gap, loss of inversion symmetry and possible Rashba effect, quantum confinement, and dielectric confinement related to the organic barrier, up to excitonic properties. Altogether, this paper aims to provide an interpretive and predictive framework for 3D and 2D layered HOP optoelectronic properties.

Authors:
 [1];  [2];  [2];  [3];  [4];  [4];  [5];  [5];  [5];  [5]; ORCiD logo [5]; ORCiD logo [5];  [2];  [1];  [2]
+ Show Author Affiliations
  1. National Inst. of Applied Sciences of Rennes (INSA), CNRS/UMR 6082, Rennes (France). Optical Functions for Information Technologies (FOTON)
  2. Univ. of Rennes, CNRS/UMR 6226, Rennes (France). Inst. of Chemical Sciences of Rennes (ICRH)
  3. The Barcelona Institute of Science and Technology (BIST), CSIC, Barcelona (Spain). Catalan Inst. of Nanoscience and Nanotechnology (ICN2)
  4. Univ. of Groningen (Netherlands). Zernike Inst. for Advanced Materials
  5. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; USDOE Laboratory Directed Research and Development (LDRD) Program; National Research Agency (ANR) (France); BPO Foundation (France); European Research Council (ERC); Netherlands Organization for Scientific Research (NWO); Ministry of Economy and Enterprise (MINECO) (Spain); European Union (EU)
OSTI Identifier:
1459816
Report Number(s):
LA-UR-16-26260
Journal ID: ISSN 1936-0851
Grant/Contract Number:  
AC52-06NA25396; 2016-c2012096724; PEROPHOT 2015; 306983; SEV-2013-0295; 687008
Resource Type:
Accepted Manuscript
Journal Name:
ACS Nano
Additional Journal Information:
Journal Volume: 10; Journal Issue: 11; Journal ID: ISSN 1936-0851
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY; 36 MATERIALS SCIENCE; Bethe−Salpeter equation; density functional theory; dielectric confinement; exciton; halide perovskites; k·p; layered materials; quantum confinement; Rashba

Citation Formats

Pedesseau, Laurent, Sapori, Daniel, Traore, Boubacar, Robles, Roberto, Fang, Hong-Hua, Loi, Maria Antonietta, Tsai, Hsinhan, Nie, Wanyi, Blancon, Jean-Christophe, Neukirch, Amanda, Tretiak, Sergei, Mohite, Aditya D., Katan, Claudine, Even, Jacky, and Kepenekian, Mikael. Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors. United States: N. p., 2016. Web. doi:10.1021/acsnano.6b05944.
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Pedesseau, Laurent, Sapori, Daniel, Traore, Boubacar, Robles, Roberto, Fang, Hong-Hua, Loi, Maria Antonietta, Tsai, Hsinhan, Nie, Wanyi, Blancon, Jean-Christophe, Neukirch, Amanda, Tretiak, Sergei, Mohite, Aditya D., Katan, Claudine, Even, Jacky, & Kepenekian, Mikael. Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors. United States. https://doi.org/10.1021/acsnano.6b05944
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Pedesseau, Laurent, Sapori, Daniel, Traore, Boubacar, Robles, Roberto, Fang, Hong-Hua, Loi, Maria Antonietta, Tsai, Hsinhan, Nie, Wanyi, Blancon, Jean-Christophe, Neukirch, Amanda, Tretiak, Sergei, Mohite, Aditya D., Katan, Claudine, Even, Jacky, and Kepenekian, Mikael. Wed . "Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors". United States. https://doi.org/10.1021/acsnano.6b05944. https://www.osti.gov/servlets/purl/1459816.
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@article{osti_1459816,
title = {Advances and Promises of Layered Halide Hybrid Perovskite Semiconductors},
author = {Pedesseau, Laurent and Sapori, Daniel and Traore, Boubacar and Robles, Roberto and Fang, Hong-Hua and Loi, Maria Antonietta and Tsai, Hsinhan and Nie, Wanyi and Blancon, Jean-Christophe and Neukirch, Amanda and Tretiak, Sergei and Mohite, Aditya D. and Katan, Claudine and Even, Jacky and Kepenekian, Mikael},
abstractNote = {Layered halide hybrid organic–inorganic perovskites (HOP) have been the subject of intense investigation before the rise of three-dimensional (3D) HOP and their impressive performance in solar cells. Recently, layered HOP have also been proposed as attractive alternatives for photostable solar cells and revisited for light-emitting devices. Here, we combine classical solid-state physics concepts with simulation tools based on density functional theory to overview the main features of the optoelectronic properties of layered HOP. A detailed comparison between layered and 3D HOP is performed to highlight differences and similarities. In the same way as the cubic phase was established for 3D HOP, here we introduce the tetragonal phase with D4h symmetry as the reference phase for 2D monolayered HOP. It allows for detailed analysis of the spin–orbit coupling effects and structural transitions with corresponding electronic band folding. We further investigate the effects of octahedral tilting on the band gap, loss of inversion symmetry and possible Rashba effect, quantum confinement, and dielectric confinement related to the organic barrier, up to excitonic properties. Altogether, this paper aims to provide an interpretive and predictive framework for 3D and 2D layered HOP optoelectronic properties.},
doi = {10.1021/acsnano.6b05944},
journal = {ACS Nano},
number = 11,
volume = 10,
place = {United States},
year = {2016},
month = {10}
}
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https://doi.org/10.1021/acsnano.6b05944
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Works referenced in this record:

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012

Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012

  • Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00591

Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013

  • Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
  • Nature, Vol. 499, Issue 7458, p. 316-319
  • DOI: 10.1038/nature12340

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015

Photophysics of Organic-Inorganic Hybrid Lead Iodide Perovskite Single Crystals
journal, February 2015

  • Fang, Hong-Hua; Raissa, Raissa; Abdu-Aguye, Mustapha
  • Advanced Functional Materials, Vol. 25, Issue 16
  • DOI: 10.1002/adfm.201404421

Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites
journal, June 2015

  • Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina
  • Nature Physics, Vol. 11, Issue 7
  • DOI: 10.1038/nphys3357

Efficient luminescent solar cells based on tailored mixed-cation perovskites
journal, January 2016

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency
journal, January 2016

  • Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03874J

Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers
journal, October 2015

A vacuum flash–assisted solution process for high-efficiency large-area perovskite solar cells
journal, June 2016

Perovskite solar cells and large area modules (100 cm 2 ) based on an air flow-assisted PbI 2 blade coating deposition process
journal, March 2015

Toxicity of organometal halide perovskite solar cells
journal, February 2016

  • Babayigit, Aslihan; Ethirajan, Anitha; Muller, Marc
  • Nature Materials, Vol. 15, Issue 3
  • DOI: 10.1038/nmat4572

Environmentally responsible fabrication of efficient perovskite solar cells from recycled car batteries
journal, January 2014

  • Chen, Po-Yen; Qi, Jifa; Klug, Matthew T.
  • Energy Environ. Sci., Vol. 7, Issue 11
  • DOI: 10.1039/C4EE00965G

Evolution of Chemical Composition, Morphology, and Photovoltaic Efficiency of CH 3 NH 3 PbI 3 Perovskite under Ambient Conditions
journal, December 2015

Light-activated photocurrent degradation and self-healing in perovskite solar cells
journal, May 2016

  • Nie, Wanyi; Blancon, Jean-Christophe; Neukirch, Amanda J.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11574

Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets
journal, March 1995

Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors
journal, October 1999

Optical properties due to electronic transitions in two-dimensional semiconductors ( C n H 2 n + 1 NH 3 ) 2 PbI 4
journal, December 1990

Structurally Tailored Organic−Inorganic Perovskites:  Optical Properties and Solution-Processed Channel Materials for Thin-Film Transistors
journal, October 2001

  • Mitzi, David B.; Dimitrakopoulos, Christos D.; Kosbar, Laura L.
  • Chemistry of Materials, Vol. 13, Issue 10
  • DOI: 10.1021/cm010105g

Reduced Band Gap Hybrid Perovskites Resulting from Combined Hydrogen and Halogen Bonding at the Organic−Inorganic Interface
journal, February 2007

  • Sourisseau, Sebastien; Louvain, Nicolas; Bi, Wenhua
  • Chemistry of Materials, Vol. 19, Issue 3
  • DOI: 10.1021/cm062380e

Understanding Quantum Confinement of Charge Carriers in Layered 2D Hybrid Perovskites
journal, September 2014

  • Even, Jacky; Pedesseau, Laurent; Katan, Claudine
  • ChemPhysChem, Vol. 15, Issue 17
  • DOI: 10.1002/cphc.201402428

Electronic properties of 2D and 3D hybrid organic/inorganic perovskites for optoelectronic and photovoltaic applications
journal, November 2013

  • Pedesseau, Laurent; Jancu, Jean-Marc; Rolland, Alain
  • Optical and Quantum Electronics, Vol. 46, Issue 10
  • DOI: 10.1007/s11082-013-9823-9

Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
journal, March 2016

A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014

  • Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
  • Angewandte Chemie International Edition, Vol. 53, Issue 42
  • DOI: 10.1002/anie.201406466

2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
journal, June 2015

  • Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K.
  • Journal of the American Chemical Society, Vol. 137, Issue 24
  • DOI: 10.1021/jacs.5b03796

Atomically thin two-dimensional organic-inorganic hybrid perovskites
journal, September 2015

Excitons in ultrathin organic-inorganic perovskite crystals
journal, July 2015

Colloidal Organohalide Perovskite Nanoplatelets Exhibiting Quantum Confinement
journal, May 2015

  • Tyagi, Pooja; Arveson, Sarah M.; Tisdale, William A.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 10
  • DOI: 10.1021/acs.jpclett.5b00664

Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015

  • Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.
  • Nano Letters, Vol. 15, Issue 6
  • DOI: 10.1021/nl5048779

Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016

  • Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
  • Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
  • DOI: 10.1021/acs.chemmater.6b00847

High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016

  • Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
  • Nature, Vol. 536, Issue 7616
  • DOI: 10.1038/nature18306

Importance of Spin–Orbit Coupling in Hybrid Organic/Inorganic Perovskites for Photovoltaic Applications
journal, August 2013

  • Even, Jacky; Pedesseau, Laurent; Jancu, Jean-Marc
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 17
  • DOI: 10.1021/jz401532q

First-Principles Modeling of Mixed Halide Organometal Perovskites for Photovoltaic Applications
journal, July 2013

  • Mosconi, Edoardo; Amat, Anna; Nazeeruddin, Md. K.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 27
  • DOI: 10.1021/jp4048659

Structural and electronic properties of hybrid perovskites for high-efficiency thin-film photovoltaics from first-principles
journal, October 2013

  • Brivio, Federico; Walker, Alison B.; Walsh, Aron
  • APL Materials, Vol. 1, Issue 4
  • DOI: 10.1063/1.4824147

Small Photocarrier Effective Masses Featuring Ambipolar Transport in Methylammonium Lead Iodide Perovskite: A Density Functional Analysis
journal, November 2013

  • Giorgi, Giacomo; Fujisawa, Jun-Ichi; Segawa, Hiroshi
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 24
  • DOI: 10.1021/jz4023865

Inhomogeneous Electron Gas
journal, November 1964

Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965

Analysis of Multivalley and Multibandgap Absorption and Enhancement of Free Carriers Related to Exciton Screening in Hybrid Perovskites
journal, May 2014

  • Even, Jacky; Pedesseau, Laurent; Katan, Claudine
  • The Journal of Physical Chemistry C, Vol. 118, Issue 22
  • DOI: 10.1021/jp503337a

Interplay of spin–orbit coupling and lattice distortion in metal substituted 3D tri-chloride hybrid perovskites
journal, January 2015

  • Katan, C.; Pedesseau, L.; Kepenekian, M.
  • Journal of Materials Chemistry A, Vol. 3, Issue 17
  • DOI: 10.1039/C4TA06418F

Solid-State Physics Perspective on Hybrid Perovskite Semiconductors
journal, April 2015

  • Even, Jacky; Pedesseau, Laurent; Katan, Claudine
  • The Journal of Physical Chemistry C, Vol. 119, Issue 19
  • DOI: 10.1021/acs.jpcc.5b00695

Pedestrian Guide to Symmetry Properties of the Reference Cubic Structure of 3D All-Inorganic and Hybrid Perovskites
journal, June 2015

Molecular disorder and translation/rotation coupling in the plastic crystal phase of hybrid perovskites
journal, January 2016

A Relativistic Equation for Bound-State Problems
journal, December 1951

Structure and optical properties of lead iodide based two-dimensional perovskite compounds containing fluorophenethylamines
journal, November 2004

Strong exciton-photon coupling in microcavities containing new fluorophenethylamine based perovskite compounds
journal, January 2012

Synthesis, characterization and phase transitions in the inorganic–organic layered perovskite-type hybrids [(C n H 2 n  + 1 NH 3 ) 2 PbI 4 ], n = 4, 5 and 6
journal, September 2007

  • Billing, David G.; Lemmerer, Andreas
  • Acta Crystallographica Section B Structural Science, Vol. 63, Issue 5
  • DOI: 10.1107/S0108768107031758

Tunable Charge Transport in Soluble Organic–Inorganic Hybrid Semiconductors
journal, December 2007

  • Takahashi, Yukari; Obara, Rena; Nakagawa, Kohei
  • Chemistry of Materials, Vol. 19, Issue 25
  • DOI: 10.1021/cm702405c

Synthesis, Crystal Structure, and Optical and Thermal Properties of (C4H9NH3)2MI4 (M = Ge, Sn, Pb)
journal, January 1996

  • Mitzi, David B.
  • Chemistry of Materials, Vol. 8, Issue 3, p. 791-800
  • DOI: 10.1021/cm9505097

Confinement Effects in Low-Dimensional Lead Iodide Perovskite Hybrids
journal, June 2016

Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating
journal, June 2005

  • Knutson, Jeremy L.; Martin, James D.; Mitzi, David B.
  • Inorganic Chemistry, Vol. 44, Issue 13
  • DOI: 10.1021/ic050244q

Steric engineering of metal-halide perovskites with tunable optical band gaps
journal, December 2014

  • Filip, Marina R.; Eperon, Giles E.; Snaith, Henry J.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6757

DFT and k · p modelling of the phase transitions of lead and tin halide perovskites for photovoltaic cells : DFT and
journal, October 2013

  • Even, Jacky; Pedesseau, Laurent; Jancu, Jean-Marc
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 8, Issue 1
  • DOI: 10.1002/pssr.201308183

Switchable S = 1/2 and J = 1/2 Rashba bands in ferroelectric halide perovskites
journal, April 2014

  • Kim, M.; Im, J.; Freeman, A. J.
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 19
  • DOI: 10.1073/pnas.1405780111

Relativistic quasiparticle self-consistent electronic structure of hybrid halide perovskite photovoltaic absorbers
journal, April 2014

Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin–Orbit Coupling and Octahedra Tilting
journal, May 2014

  • Amat, Anna; Mosconi, Edoardo; Ronca, Enrico
  • Nano Letters, Vol. 14, Issue 6
  • DOI: 10.1021/nl5012992

Tunable ferroelectric polarization and its interplay with spin–orbit coupling in tin iodide perovskites
journal, December 2014

  • Stroppa, Alessandro; Di Sante, Domenico; Barone, Paolo
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6900

Rashba and Dresselhaus Effects in Hybrid Organic–Inorganic Perovskites: From Basics to Devices
journal, September 2015

Crystal structure of bis(benzylammonium) lead tetrachloride, (C7H7NH3)2PbCl4
journal, September 1999

  • Braun, M.; Frey, W.
  • Zeitschrift für Kristallographie - New Crystal Structures, Vol. 214, Issue 3
  • DOI: 10.1515/ncrs-1999-0318

A lead-halide perovskite molecular ferroelectric semiconductor
journal, May 2015

  • Liao, Wei-Qiang; Zhang, Yi; Hu, Chun-Li
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8338

Synthesis, Single-Crystal Structure and Characterization of (CH 3 NH 3 ) 2 Pb(SCN) 2 I 2
journal, September 2015

  • Daub, Michael; Hillebrecht, Harald
  • Angewandte Chemie International Edition, Vol. 54, Issue 38
  • DOI: 10.1002/anie.201506449

(CH 3 NH 3 ) 2 Pb(SCN) 2 I 2 : A More Stable Structural Motif for Hybrid Halide Photovoltaics?
journal, October 2015

  • Ganose, Alex M.; Savory, Christopher N.; Scanlon, David O.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
  • DOI: 10.1021/acs.jpclett.5b02177

Photovoltaic Properties of Two-Dimensional (CH 3 NH 3 ) 2 Pb(SCN) 2 I 2 Perovskite: A Combined Experimental and Density Functional Theory Study
journal, March 2016

  • Xiao, Zewen; Meng, Weiwei; Saparov, Bayrammurad
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 7
  • DOI: 10.1021/acs.jpclett.6b00248

Intrinsic White-Light Emission from Layered Hybrid Perovskites
journal, September 2014

  • Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R.
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja507086b

Strong exciton–photon coupling at room temperature in microcavities containing two-dimensional layered perovskite compounds
journal, June 2008

Excitonic and nonlinear-optical properties of dielectric quantum-well structures
journal, December 1989

Excitons in self-organized semiconductor/insulator superlattices: PbI-based perovskite compounds
journal, May 1995

Dielectric properties of ultrathin SiO2 slabs
journal, December 2005

  • Shi, N.; Ramprasad, R.
  • Applied Physics Letters, Vol. 87, Issue 26
  • DOI: 10.1063/1.2150584

Electronic surface states and dielectric self-energy profiles in colloidal nanoscale platelets of CdSe
journal, January 2014

  • Even, Jacky; Pedesseau, Laurent; Kepenekian, Mikaël
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 45
  • DOI: 10.1039/C4CP03267E

Tight-binding calculations of image-charge effects in colloidal nanoscale platelets of CdSe
journal, January 2014

Quantum confinement and dielectric profiles of colloidal nanoplatelets of halide inorganic and hybrid organic–inorganic perovskites
journal, January 2016

  • Sapori, Daniel; Kepenekian, Mikaël; Pedesseau, Laurent
  • Nanoscale, Vol. 8, Issue 12
  • DOI: 10.1039/C5NR07175E

The Dielectric Constants of Typical Aliphatic and Aromatic Hydrocarbons, Cyclohexane, Cyclohexanone, and Cyclohexanol.
journal, December 1919

  • Richards, T. W.; Shipley, J. W.
  • Journal of the American Chemical Society, Vol. 41, Issue 12
  • DOI: 10.1021/ja02233a017

Role of Polar Phonons in the Photo Excited State of Metal Halide Perovskites
journal, June 2016

  • Bokdam, Menno; Sander, Tobias; Stroppa, Alessandro
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep28618

Ab initio modeling of 2D layered organohalide lead perovskites
journal, April 2016

  • Fraccarollo, Alberto; Cantatore, Valentina; Boschetto, Gabriele
  • The Journal of Chemical Physics, Vol. 144, Issue 16
  • DOI: 10.1063/1.4947305

Exciton Green’s-function approach to optical absorption in a quantum well with an applied electric field
journal, January 1991

  • Chuang, Shun-Lien; Schmitt-Rink, Stefan; Miller, David A. B.
  • Physical Review B, Vol. 43, Issue 2
  • DOI: 10.1103/PhysRevB.43.1500
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    Simple fabrication of layered halide perovskite platelets and enhanced photoluminescence from mechanically exfoliated flakes
    journal, January 2019

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    • Nanoscale, Vol. 11, Issue 17
    • DOI: 10.1039/c9nr00638a

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    journal, March 2019

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    journal, January 2019

    • Ju, Ming-Gang; Dai, Jun; Ma, Liang
    • Journal of Materials Chemistry A, Vol. 7, Issue 28
    • DOI: 10.1039/c9ta04486h

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    journal, November 2019

    • Duim, Herman; Adjokatse, Sampson; Kahmann, Simon
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    • DOI: 10.1002/adfm.201907505

    Steady-state microwave conductivity reveals mobility-lifetime product in methylammonium lead iodide
    journal, October 2018

    • Labram, John G.; Perry, Erin E.; Venkatesan, Naveen R.
    • Applied Physics Letters, Vol. 113, Issue 15
    • DOI: 10.1063/1.5041959

    Influence of π -conjugated cations and halogen substitution on the optoelectronic and excitonic properties of layered hybrid perovskites
    journal, October 2018

    Unveiling the operation mechanism of layered perovskite solar cells
    journal, March 2019

    Two‐Dimensional Halide Perovskites in Solar Cells: 2D or not 2D?
    journal, March 2019

    • Ortiz‐Cervantes, Carmen; Carmona‐Monroy, Paulina; Solis‐Ibarra, Diego
    • ChemSusChem, Vol. 12, Issue 8
    • DOI: 10.1002/cssc.201802992

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    journal, October 2019

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    journal, January 2017

    • Ahn, Jihoon; Lee, Eunsong; Tan, Jeiwan
    • Materials Horizons, Vol. 4, Issue 5
    • DOI: 10.1039/c7mh00197e

    Metal Halide Perovskite Light‐Emitting Devices: Promising Technology for Next‐Generation Displays
    journal, April 2019

    • Lu, Min; Zhang, Yu; Wang, Shixun
    • Advanced Functional Materials, Vol. 29, Issue 30
    • DOI: 10.1002/adfm.201902008

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    journal, January 2019

    • Venkatesan, Naveen R.; Mahdi, Ali; Barraza, Brian
    • Dalton Transactions, Vol. 48, Issue 37
    • DOI: 10.1039/c9dt03074c

    Exciton-enhanced infrared spectroscopy with organometallic perovskite nanoplatelets
    journal, January 2019

    • Wei, Xiao-Lan; Gao, Xiao-Li; Chen, Jia
    • New Journal of Chemistry, Vol. 43, Issue 7
    • DOI: 10.1039/c8nj06524a

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    journal, September 2018

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    journal, January 2018

    • Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe
    • Advanced Materials, Vol. 30, Issue 6
    • DOI: 10.1002/adma.201704217

    First principles study of 2D layered organohalide tin perovskites
    journal, June 2017

    • Fraccarollo, Alberto; Canti, Lorenzo; Marchese, Leonardo
    • The Journal of Chemical Physics, Vol. 146, Issue 23
    • DOI: 10.1063/1.4985054

    Dimensional tailoring of hybrid perovskites for photovoltaics
    journal, November 2018

    2D Ruddlesden-Popper Perovskites for Optoelectronics
    journal, October 2017

    Edge stabilization in reduced-dimensional perovskites
    journal, January 2020

    Band‐Edge Exciton Fine Structure and Exciton Recombination Dynamics in Single Crystals of Layered Hybrid Perovskites
    journal, December 2019

    • Fang, Hong‐Hua; Yang, Jie; Adjokatse, Sampson
    • Advanced Functional Materials, Vol. 30, Issue 6
    • DOI: 10.1002/adfm.201907979

    (C 3 H 9 NI) 4 AgBiI 8 : a direct-bandgap layered double perovskite based on a short-chain spacer cation for light absorption
    journal, January 2020

    • Yao, Yunpeng; Kou, Bo; Peng, Yu
    • Chemical Communications, Vol. 56, Issue 21
    • DOI: 10.1039/c9cc07796k

    Excited-state vibrational dynamics toward the polaron in methylammonium lead iodide perovskite
    journal, June 2018

    • Park, Myeongkee; Neukirch, Amanda J.; Reyes-Lillo, Sebastian E.
    • Nature Communications, Vol. 9, Issue 1
    • DOI: 10.1038/s41467-018-04946-7

    Aqueous acid-based synthesis of lead-free tin halide perovskites with near-unity photoluminescence quantum efficiency
    journal, January 2019

    • Wang, Aifei; Guo, Yanyan; Zhou, Zhaobo
    • Chemical Science, Vol. 10, Issue 17
    • DOI: 10.1039/c9sc00453j

    Recombination at high carrier density in methylammonium lead iodide studied using time-resolved microwave conductivity
    journal, August 2017

    • Labram, John G.; Chabinyc, Michael L.
    • Journal of Applied Physics, Vol. 122, Issue 6
    • DOI: 10.1063/1.4990802

    Searching for stability at lower dimensions: current trends and future prospects of layered perovskite solar cells
    journal, January 2019

    • Thrithamarassery Gangadharan, Deepak; Ma, Dongling
    • Energy & Environmental Science, Vol. 12, Issue 10
    • DOI: 10.1039/c9ee01591d

    Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites
    journal, November 2018

    • Cortecchia, D.; Neutzner, S.; Yin, J.
    • APL Materials, Vol. 6, Issue 11
    • DOI: 10.1063/1.5045782

    Exciton-band tuning induced by the width of the cation in 2D lead iodide perovskite hybrids
    journal, January 2020

    • Tremblay, Marie-Hélène; Bacsa, John; Barlow, Stephen
    • Materials Chemistry Frontiers
    • DOI: 10.1039/d0qm00118j

    Two-dimensional halide perovskite nanomaterials and heterostructures
    journal, January 2018

    • Shi, Enzheng; Gao, Yao; Finkenauer, Blake P.
    • Chemical Society Reviews, Vol. 47, Issue 16
    • DOI: 10.1039/c7cs00886d

    Progress in Theoretical Study of Metal Halide Perovskite Solar Cell Materials
    journal, August 2017

    Scaling law for excitons in 2D perovskite quantum wells
    journal, June 2018

    Tuning the optical bandgap in layered hybrid perovskites through variation of alkyl chain length
    journal, April 2019

    • Sichert, Jasmina A.; Hemmerling, Annick; Cardenas-Daw, Carlos
    • APL Materials, Vol. 7, Issue 4
    • DOI: 10.1063/1.5087296

    Extremely reduced dielectric confinement in two-dimensional hybrid perovskites with large polar organics
    journal, November 2018

    Tailoring Organic Cation of 2D Air-Stable Organometal Halide Perovskites for Highly Efficient Planar Solar Cells
    journal, May 2017

    Dimensionality engineering of hybrid halide perovskite light absorbers
    journal, November 2018

    • Gao, Peng; Bin Mohd Yusoff, Abd Rashid; Nazeeruddin, Mohammad Khaja
    • Nature Communications, Vol. 9, Issue 1
    • DOI: 10.1038/s41467-018-07382-9

    Recent advances toward efficient and stable tin‐based perovskite solar cells
    journal, December 2019

    • Tai, Qidong; Cao, Jiupeng; Wang, Tianyue
    • EcoMat, Vol. 1, Issue 1
    • DOI: 10.1002/eom2.12004

    In-Plane Ferroelectricity in Thin Flakes of Van der Waals Hybrid Perovskite
    journal, October 2018

    Flexible Quasi‐2D Perovskite/IGZO Phototransistors for Ultrasensitive and Broadband Photodetection
    journal, December 2019

    Designing a new family of oxonium-cation based structurally diverse organic–inorganic hybrid iodoantimonate crystals
    journal, January 2019

    • Parmar, Swati; Pal, Shiv; Biswas, Abhijit
    • Chemical Communications, Vol. 55, Issue 52
    • DOI: 10.1039/c9cc03485d

    Enhanced Exciton and Photon Confinement in Ruddlesden-Popper Perovskite Microplatelets for Highly Stable Low-Threshold Polarized Lasing
    journal, April 2018

    Distinct conducting layer edge states in two-dimensional (2D) halide perovskite
    journal, July 2019

    Multiscale in modelling and validation for solar photovoltaics
    journal, January 2018

    Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides
    journal, July 2018

    • Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia
    • Angewandte Chemie, Vol. 130, Issue 35
    • DOI: 10.1002/ange.201806452

    Structural and thermodynamic limits of layer thickness in 2D halide perovskites
    journal, December 2018

    • Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha
    • Proceedings of the National Academy of Sciences, Vol. 116, Issue 1
    • DOI: 10.1073/pnas.1811006115

    Fabrication of single phase 2D homologous perovskite microplates by mechanical exfoliation
    journal, January 2018

    Controllable growth of two-dimensional perovskite microstructures
    journal, January 2018

    • Fang, Chen; Li, Junze; Wang, Jun
    • CrystEngComm, Vol. 20, Issue 41
    • DOI: 10.1039/c8ce01087k

    Growth mechanism of strongly emitting CH3NH3PbBr3 perovskite nanocrystals with a tunable bandgap
    journal, October 2017

    An overview on enhancing the stability of lead halide perovskite quantum dots and their applications in phosphor-converted LEDs
    journal, January 2019

    • Wei, Yi; Cheng, Ziyong; Lin, Jun
    • Chemical Society Reviews, Vol. 48, Issue 1
    • DOI: 10.1039/c8cs00740c

    Merits and Challenges of Ruddlesden-Popper Soft Halide Perovskites in Electro-Optics and Optoelectronics
    journal, October 2018

    Does Rashba splitting in CH 3 NH 3 PbBr 3 arise from 2 × 2 surface reconstruction?
    journal, January 2018

    • Che, Xiaoyang; Traore, Boubacar; Katan, Claudine
    • Physical Chemistry Chemical Physics, Vol. 20, Issue 14
    • DOI: 10.1039/c8cp00745d

    Preface: Two dimensional (2D) hybrid organic-inorganic perovskites
    journal, November 2018

    • Li, Wei; Docampo, Pablo; Mohite, Aditya D.
    • APL Materials, Vol. 6, Issue 11
    • DOI: 10.1063/1.5079945

    Free-electron effects on the optical absorption of the hybrid perovskite CH 3 NH 3 PbI 3 from first principles
    journal, July 2019

    Perovskite‐Based Phototransistors and Hybrid Photodetectors
    journal, August 2019

    • Xie, Chao; Liu, Chun‐Ki; Loi, Hok‐Leung
    • Advanced Functional Materials, Vol. 30, Issue 20
    • DOI: 10.1002/adfm.201903907

    Stable biexcitons in two-dimensional metal-halide perovskites with strong dynamic lattice disorder
    journal, March 2018

    Two-dimensional hybrid perovskites sustaining strong polariton interactions at room temperature
    journal, May 2019

    Bright magnetic dipole radiation from two-dimensional lead-halide perovskites
    journal, February 2020

    • DeCrescent, Ryan A.; Venkatesan, Naveen R.; Dahlman, Clayton J.
    • Science Advances, Vol. 6, Issue 6
    • DOI: 10.1126/sciadv.aay4900

    Realization of “warm” white light via halide substitution in polar two-dimensional hybrid perovskites (2meptH 2 )PbCl x Br 4−x
    journal, January 2018

    • Wang, Sasa; Yao, Yunpeng; Wu, Zhenyue
    • Journal of Materials Chemistry C, Vol. 6, Issue 45
    • DOI: 10.1039/c8tc03167c

    Fluorination of Organic Spacer Impacts on the Structural and Optical Response of 2D Perovskites
    journal, January 2020

    • García-Benito, Inés; Quarti, Claudio; Queloz, Valentin I. E.
    • Frontiers in Chemistry, Vol. 7
    • DOI: 10.3389/fchem.2019.00946

    Multilayered 2D Cesium‐Based Hybrid Perovskite with Strong Polarization Sensitivity: Dimensional Reduction of CsPbBr 3
    journal, March 2020

    • Liu, Yi; Wang, Jiaqi; Han, Shiguo
    • Chemistry – A European Journal, Vol. 26, Issue 16
    • DOI: 10.1002/chem.201905531

    Lead-free hybrid perovskites for photovoltaics
    journal, January 2018

    First-principles characterization of two-dimensional (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) n−1 Ge n I 3n+1 perovskite
    journal, January 2018

    • Wu, Liyuan; Lu, Pengfei; Li, Yuheng
    • Journal of Materials Chemistry A, Vol. 6, Issue 47
    • DOI: 10.1039/c8ta10055a

    Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites
    journal, March 2017

    Unravelling Light-Induced Degradation of Layered Perovskite Crystals and Design of Efficient Encapsulation for Improved Photostability
    journal, April 2018

    • Fang, Hong-Hua; Yang, Jie; Tao, Shuxia
    • Advanced Functional Materials, Vol. 28, Issue 21
    • DOI: 10.1002/adfm.201800305

    Spintronics of Hybrid Organic–Inorganic Perovskites: Miraculous Basis of Integrated Optoelectronic Devices
    journal, June 2019

    • Liao, Kun; Hu, Xiaoyong; Cheng, Yinke
    • Advanced Optical Materials, Vol. 7, Issue 15
    • DOI: 10.1002/adom.201900350

    Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells
    journal, May 2018

    Surface Termination, Morphology, and Bright Photoluminescence of Cesium Lead Halide Perovskite Nanocrystals
    journal, November 2016

    Unveiling the operation mechanism of layered perovskite solar cells
    text, January 2019

    • M. M., Nahid,; S. J., Stuard,; J., Huang,
    • The University of North Carolina at Chapel Hill University Libraries
    • DOI: 10.17615/dstf-da41

    Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides
    journal, July 2018

    • Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia
    • Angewandte Chemie International Edition, Vol. 57, Issue 35
    • DOI: 10.1002/anie.201806452

    Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden-Popper Layered Perovskites
    conference, February 2018

    • Tsai, Hsinhan; Mohite, Aditya; Blancon, Jean-Christophe
    • Proceedings of the 3rd International Conference on Perovskite Thin Film Photovoltaics, Photonics and Optoelectronics
    • DOI: 10.29363/nanoge.abxpvperopto.2018.053
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