Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

doi:10.1149/2.0431810jes

Title: Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Authors:

; Qin, Yan ; Liu, Yuzi ; Liu, Qi ; Ren, Yang ; ;

Publication Date:: 2018-07-10

Grant/Contract Number:: AC02-06CH11357

Type:: Published Article

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Name: Journal of the Electrochemical Society Journal Volume: 165 Journal Issue: 10; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Sponsoring Org:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Country of Publication:: United States

Language:: English

OSTI Identifier:: 1459694


                    Zhang, Linghong, Qin, Yan, Liu, Yuzi, Liu, Qi, Ren, Yang, Jansen, Andrew N., and Lu, Wenquan. Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries.  United States: N. p.,  
        Web.  doi:10.1149/2.0431810jes.

Copy to clipboard


                    Zhang, Linghong, Qin, Yan, Liu, Yuzi, Liu, Qi, Ren, Yang, Jansen, Andrew N., & Lu, Wenquan. Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries.  United States.  doi:10.1149/2.0431810jes.

Copy to clipboard


                    Zhang, Linghong, Qin, Yan, Liu, Yuzi, Liu, Qi, Ren, Yang, Jansen, Andrew N., and Lu, Wenquan. 2018.  
        "Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries".  United States.  
        doi:10.1149/2.0431810jes.

Copy to clipboard


                    
@article{osti_1459694,

  title        = {Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries},

  author       = {Zhang, Linghong and Qin, Yan and Liu, Yuzi and Liu, Qi and Ren, Yang and Jansen, Andrew N. and Lu, Wenquan},

  abstractNote = {},

  doi          = {10.1149/2.0431810jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 10,

  volume       = 165,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

Copy to clipboard

Free Publicly Accessible Full Text
Publisher's Version of Record at 10.1149/2.0431810jes

Works referenced in this record:

Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries
journal, January 2007

Miyachi, Mariko; Yamamoto, Hironori; Kawai, Hidemasa
Journal of The Electrochemical Society, Vol. 154, Issue 4, p. A376-A380
DOI: 10.1149/1.2455963

Similar Records

Similar records in DOE PAGES and OSTI.GOV collections:

Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Journal Article - in OSTI.gov collection Zhang, Linghong ; Qin, Yan ; Liu, Yuzi ; ... January 2018 - Journal of the Electrochemical Society

In this study, we first investigate the major causes of capacity fading in silicon monoxide (SiO) anodes. Major capacity loss occurs in the early cycles followed by less capacity fading during the following cycles. Close examination of the electrochemical test results shows that similar to silicon, the major capacity loss of the SiO anode at the early cycles occurs at the earlier stages of lithiation (>0.27 V vs Li/Li+), suggesting the phenomenon of incomplete delithiation due to electrode volume expansion/contraction. Unlike silicon which shows continuous capacity loss toward lower voltages, the capacity retention of SiO stabilizes after the initial fastmore »« less
Full Text Available
SiO ₂ -Enhanced Structural Stability and Strong Adhesion with a New Binder of Konjac Glucomannan Enables Stable Cycling of Silicon Anodes for Lithium-Ion Batteries

Journal Article Guo, Songtao ; Li, Heng ; Li, Yaqian ; ... June 2018 - Advanced Energy Materials
High capacity and good cycling stability of multi-walled carbon nanotube/SnO{sub 2} core-shell structures as anode materials of lithium-ion batteries

Journal Article - in OSTI.gov collection Zhu, Chun-Ling ; Zhang, Mi-lin ; Qiao, Ying-Jie ; ... April 2010 - Materials Research Bulletin

The multi-walled carbon nanotube/SnO{sub 2} core-shell structures were fabricated by a wet chemical route. The electrochemical performance of the core-shell structures as anode materials of lithium-ion batteries was investigated. The initial discharge capacity and reversible capacity are up to 1472.7 and 1020.5 mAh g{sup -1}, respectively. Moreover, the reversible capacity still remains above 720 mAh g{sup -1} over 35 cycles, and the capacity fading is only 0.8% per cycle. Such high capacities and good cyclability are attributed to SnO{sub 2} network structures, excellent mechanical property and good electrical conductivity of the multi-walled carbon nanotubes.
Full Text Available
Capacity Fading Mechanism of the Commercial 18650 LiFePO ₄-Based Lithium-Ion Batteries: An in Situ Time-Resolved High-Energy Synchrotron XRD Study

Journal Article Liu, Qi ; Liu, Yadong ; Yang, Fan ; ... January 2018 - ACS Applied Materials and Interfaces

In this paper, in situ high-energy synchrotron XRD studies were carried out on commercial 18650 LiFePO ₄ cells at different cycles to track and investigate the dynamic, chemical, and structural changes in the course of long-term cycling to elucidate the capacity fading mechanism. The results indicate that the crystalline structural deterioration of the LiFePO ₄ cathode and the graphite anode is unlikely to happen before capacity fades below 80% of the initial capacity. Rather, the loss of the active lithium source is the primary cause for the capacity fade, which leads to the appearance of inactive FePO ₄ that ismore »« less
Cited by 1
One-pot synthesis of a metal–organic framework as an anode for Li-ion batteries with improved capacity and cycling stability

Journal Article - in OSTI.gov collection Gou, Lei, E-mail: Leigou@chd.edu.cn ; Hao, Li-Min ; Shi, Yong-Xin ; ... February 2014 - Journal of Solid State Chemistry

Metal–organic framework is a kind of novel electrode materials for lithium ion batteries. Here, a 3D metal–organic framework Co{sub 2}(OH){sub 2}BDC (BDC=1,4-benzenedicarboxylate) was synthesized for the first time by the reaction of Co{sup 2+} with a bio-inspired renewable organic ligand 1,4-benzenedicarboxylic acid through a solvothermal method. As an anode material for lithium ion batteries, this material exhibited an excellent cyclic stability as well as a large reversible capacity of ca. 650 mA h g{sup −1} at a current density of 50 mA g{sup −1} after 100 cycles within the voltage range of 0.02–3.0 V, higher than that of other BDCmore »« less
Full Text Available

Access journal articles and accepted manuscripts resulting from DOE research funding

Title: Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Access journal articles and accepted manuscripts
resulting from DOE research funding