Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Zhang, Linghong; Qin, Yan; Liu, Yuzi; Liu, Qi; Ren, Yang; Jansen, Andrew N.; Lu, Wenquan

doi:10.1149/2.0431810jes

Title: Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Authors:

; Qin, Yan; Liu, Yuzi; Liu, Qi; Ren, Yang;

;

Publication Date:: 2018-07-10

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI Identifier:: 1459694

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Published Article

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Name: Journal of the Electrochemical Society Journal Volume: 165 Journal Issue: 10; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Zhang, Linghong, Qin, Yan, Liu, Yuzi, Liu, Qi, Ren, Yang, Jansen, Andrew N., and Lu, Wenquan. Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries.  United States: N. p., 2018. 
Web.  doi:10.1149/2.0431810jes.

Copy to clipboard


                    Zhang, Linghong, Qin, Yan, Liu, Yuzi, Liu, Qi, Ren, Yang, Jansen, Andrew N., & Lu, Wenquan. Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries.  United States.  https://doi.org/10.1149/2.0431810jes

Copy to clipboard


                    Zhang, Linghong, Qin, Yan, Liu, Yuzi, Liu, Qi, Ren, Yang, Jansen, Andrew N., and Lu, Wenquan. Tue .  
"Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries".  United States.  https://doi.org/10.1149/2.0431810jes.

Copy to clipboard


                    
@article{osti_1459694,

  title        = {Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries},

  author       = {Zhang, Linghong and Qin, Yan and Liu, Yuzi and Liu, Qi and Ren, Yang and Jansen, Andrew N. and Lu, Wenquan},

  abstractNote = {},

  doi          = {10.1149/2.0431810jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 10,

  volume       = 165,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Publisher's Version of Record
https://doi.org/10.1149/2.0431810jes

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Carbon-coated nano-Si dispersed oxides/graphite composites as anode material for lithium ion batteries
journal, May 2004

Lee, Heon-Young; Lee, Sung-Man
Electrochemistry Communications, Vol. 6, Issue 5
DOI: 10.1016/j.elecom.2004.03.005

Size-Dependent Fracture of Silicon Nanoparticles During Lithiation
journal, January 2012

Liu, Xiao Hua; Zhong, Li; Huang, Shan
ACS Nano, Vol. 6, Issue 2
DOI: 10.1021/nn204476h

Solid-State NMR and Electrochemical Dilatometry Study on Li[sup +] Uptake/Extraction Mechanism in SiO Electrode
journal, January 2007

Kim, Taeahn; Park, Sangjin; Oh, Seung M.
Journal of The Electrochemical Society, Vol. 154, Issue 12
DOI: 10.1149/1.2790282

Characterizations and electrochemical behaviors of disproportionated SiO and its composite for rechargeable Li-ion batteries
journal, January 2010

Park, Cheol-Min; Choi, Woongchul; Hwa, Yoon
Journal of Materials Chemistry, Vol. 20, Issue 23
DOI: 10.1039/b923926j

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Obrovac, M. N.; Chevrier, V. L.
Chemical Reviews, Vol. 114, Issue 23
DOI: 10.1021/cr500207g

Capacity Fading Mechanisms of Silicon Nanoparticle Negative Electrodes for Lithium Ion Batteries
journal, January 2015

Yoon, Taeho; Nguyen, Cao Cuong; Seo, Daniel M.
Journal of The Electrochemical Society, Vol. 162, Issue 12
DOI: 10.1149/2.0731512jes

Atomic-scale disproportionation in amorphous silicon monoxide
journal, May 2016

Hirata, Akihiko; Kohara, Shinji; Asada, Toshihiro
Nature Communications, Vol. 7, Issue 1
DOI: 10.1038/ncomms11591

Combinatorial Studies of Si _{1− x} O _x as a Potential Negative Electrode Material for Li-Ion Battery Applications
journal, January 2013

Al-Maghrabi, M. A.; Suzuki, Junji; Sanderson, R. J.
Journal of The Electrochemical Society, Vol. 160, Issue 9
DOI: 10.1149/2.115309jes

Critical roles of binders and formulation at multiscales of silicon-based composite electrodes
journal, April 2015

Mazouzi, D.; Karkar, Z.; Reale Hernandez, C.
Journal of Power Sources, Vol. 280
DOI: 10.1016/j.jpowsour.2015.01.140

Facile approach to SiOx/Si/C composite anode material from bulk SiO for lithium ion batteries
journal, January 2013

Feng, Xuejiao; Yang, Jun; Lu, Qingwen
Physical Chemistry Chemical Physics, Vol. 15, Issue 34
DOI: 10.1039/c3cp51799c

TEM investigation on the structure of amorphous silicon monoxide
journal, June 2003

Schulmeister, Klaus; Mader, Werner
Journal of Non-Crystalline Solids, Vol. 320, Issue 1-3
DOI: 10.1016/S0022-3093(03)00029-2

Modified SiO as a high performance anode for Li-ion batteries
journal, January 2013

Hwa, Yoon; Park, Cheol-Min; Sohn, Hun-Joon
Journal of Power Sources, Vol. 222
DOI: 10.1016/j.jpowsour.2012.08.060

Improvement in Cycle Performance and Clarification of Deterioration Mechanism of Lithium-Ion Full Cells Using SiO Anodes
journal, January 2013

Kajita, Tetsuya; Yuge, Ryota; Nakahara, Kentaro
Journal of The Electrochemical Society, Vol. 160, Issue 10
DOI: 10.1149/2.065310jes

Lithium trapping in alloy forming electrodes and current collectors for lithium based batteries
journal, January 2017

Rehnlund, David; Lindgren, Fredrik; Böhme, Solveig
Energy & Environmental Science, Vol. 10, Issue 6
DOI: 10.1039/C7EE00244K

Effect of Volume Expansion on SEI Covering Carbon-Coated Nano-Si/SiO Composite
journal, January 2013

Yuge, R.; Toda, A.; Fukatsu, K.
Journal of The Electrochemical Society, Vol. 160, Issue 10
DOI: 10.1149/2.075310jes

Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries
journal, January 2007

Miyachi, Mariko; Yamamoto, Hironori; Kawai, Hidemasa
Journal of The Electrochemical Society, Vol. 154, Issue 4, p. A376-A380
DOI: 10.1149/1.2455963

Similar Records in DOE PAGES and OSTI.GOV collections:

Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Journal Article Zhang, Linghong ; Qin, Yan ; Liu, Yuzi ; ... - Journal of the Electrochemical Society

In this study, we first investigate the major causes of capacity fading in silicon monoxide (SiO) anodes. Major capacity loss occurs in the early cycles followed by less capacity fading during the following cycles. Close examination of the electrochemical test results shows that similar to silicon, the major capacity loss of the SiO anode at the early cycles occurs at the earlier stages of lithiation (>0.27 V vs Li/Li+), suggesting the phenomenon of incomplete delithiation due to electrode volume expansion/contraction. Unlike silicon which shows continuous capacity loss toward lower voltages, the capacity retention of SiO stabilizes after the initial fastmore »« less
https://doi.org/10.1149/2.0431810jes
Investigation of SiO_x anode fading mechanism with limited capacity cycling

Journal Article Xiao, Haiqing ; Fang, Chen ; Zheng, Tianyue ; ... - APL Materials

Silicon suboxide (SiO_x) is one of the promising anode materials for the next-generation lithium-ion batteries. However, SiO_x has a severe capacity fading problem during cycling. It is thus desired to investigate the detailed fading mechanisms of SiO_x anode materials. In this study, limited capacity cycling was employed to examine the electrochemical behaviors of the SiO_x anode, and the lithiation/delithiation cycling was limited within a range of 10% theoretical capacity. This strategy minimizes the volume variation of SiO_x materials upon charging/discharging, which helps to reveal their decay factors other than volume fluctuation. It is demonstrated that the instability of the SiO_xmore »« less
https://doi.org/10.1063/5.0077036

Full Text Available
SiO₂-Enhanced Structural Stability and Strong Adhesion with a New Binder of Konjac Glucomannan Enables Stable Cycling of Silicon Anodes for Lithium-Ion Batteries

Journal Article Guo, Songtao ; Li, Heng ; Li, Yaqian ; ... - Advanced Energy Materials

Silicon-based anodes with high theoretical capacity have intriguing potential applications for next-generation high-energy lithium-ion batteries, but suffer from huge volumetric change that causes pulverization of electrodes. Rational design and construction of effective electrode structures combined with versatile binders remain a significant challenge. In this paper, a unique natural binder of konjac glucomannan (KGM) is developed and an amorphous protective layer of SiO₂ is fabricated on the surface of Si nanoparticles (Si@SiO₂) to enhance the adhesion. Benefiting from a plethora of hydroxyl groups, the KGM binder with inherently high adhesion and superior mechanical properties provides abundant contact sites to active materials.more »« less
Cited by 16
https://doi.org/10.1002/aenm.201800434

Full Text Available
Capacity Fading Mechanism of the Commercial 18650 LiFePO₄-Based Lithium-Ion Batteries: An in Situ Time-Resolved High-Energy Synchrotron XRD Study

Journal Article Liu, Qi ; Liu, Yadong ; Yang, Fan ; ... - ACS Applied Materials and Interfaces

In this paper, in situ high-energy synchrotron XRD studies were carried out on commercial 18650 LiFePO₄ cells at different cycles to track and investigate the dynamic, chemical, and structural changes in the course of long-term cycling to elucidate the capacity fading mechanism. The results indicate that the crystalline structural deterioration of the LiFePO₄ cathode and the graphite anode is unlikely to happen before capacity fades below 80% of the initial capacity. Rather, the loss of the active lithium source is the primary cause for the capacity fade, which leads to the appearance of inactive FePO₄ that is proportional to themore »« less
Cited by 8
https://doi.org/10.1021/acsami.7b13060

Full Text Available
High capacity and good cycling stability of multi-walled carbon nanotube/SnO{sub 2} core-shell structures as anode materials of lithium-ion batteries

Journal Article Zhu, Chun-Ling ; Zhang, Mi-lin ; Qiao, Ying-Jie ; ... - Materials Research Bulletin

The multi-walled carbon nanotube/SnO{sub 2} core-shell structures were fabricated by a wet chemical route. The electrochemical performance of the core-shell structures as anode materials of lithium-ion batteries was investigated. The initial discharge capacity and reversible capacity are up to 1472.7 and 1020.5 mAh g{sup -1}, respectively. Moreover, the reversible capacity still remains above 720 mAh g{sup -1} over 35 cycles, and the capacity fading is only 0.8% per cycle. Such high capacities and good cyclability are attributed to SnO{sub 2} network structures, excellent mechanical property and good electrical conductivity of the multi-walled carbon nanotubes.
https://doi.org/10.1016/J.MATERRESBULL.2009.11.011

Similar Records

Title: Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries

Citation Formats

Carbon-coated nano-Si dispersed oxides/graphite composites as anode material for lithium ion batteries journal, May 2004

Size-Dependent Fracture of Silicon Nanoparticles During Lithiation journal, January 2012

Solid-State NMR and Electrochemical Dilatometry Study on Li[sup +] Uptake/Extraction Mechanism in SiO Electrode journal, January 2007

Characterizations and electrochemical behaviors of disproportionated SiO and its composite for rechargeable Li-ion batteries journal, January 2010

Alloy Negative Electrodes for Li-Ion Batteries journal, October 2014

Capacity Fading Mechanisms of Silicon Nanoparticle Negative Electrodes for Lithium Ion Batteries journal, January 2015

Atomic-scale disproportionation in amorphous silicon monoxide journal, May 2016

Combinatorial Studies of Si 1− x O x as a Potential Negative Electrode Material for Li-Ion Battery Applications journal, January 2013

Critical roles of binders and formulation at multiscales of silicon-based composite electrodes journal, April 2015

Facile approach to SiOx/Si/C composite anode material from bulk SiO for lithium ion batteries journal, January 2013

TEM investigation on the structure of amorphous silicon monoxide journal, June 2003

Modified SiO as a high performance anode for Li-ion batteries journal, January 2013

Improvement in Cycle Performance and Clarification of Deterioration Mechanism of Lithium-Ion Full Cells Using SiO Anodes journal, January 2013

Lithium trapping in alloy forming electrodes and current collectors for lithium based batteries journal, January 2017

Effect of Volume Expansion on SEI Covering Carbon-Coated Nano-Si/SiO Composite journal, January 2013

Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries journal, January 2007

Carbon-coated nano-Si dispersed oxides/graphite composites as anode material for lithium ion batteries
journal, May 2004

Size-Dependent Fracture of Silicon Nanoparticles During Lithiation
journal, January 2012

Solid-State NMR and Electrochemical Dilatometry Study on Li[sup +] Uptake/Extraction Mechanism in SiO Electrode
journal, January 2007

Characterizations and electrochemical behaviors of disproportionated SiO and its composite for rechargeable Li-ion batteries
journal, January 2010

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Capacity Fading Mechanisms of Silicon Nanoparticle Negative Electrodes for Lithium Ion Batteries
journal, January 2015

Atomic-scale disproportionation in amorphous silicon monoxide
journal, May 2016

Combinatorial Studies of Si _{1− x} O _x as a Potential Negative Electrode Material for Li-Ion Battery Applications
journal, January 2013

Critical roles of binders and formulation at multiscales of silicon-based composite electrodes
journal, April 2015

Facile approach to SiOx/Si/C composite anode material from bulk SiO for lithium ion batteries
journal, January 2013

TEM investigation on the structure of amorphous silicon monoxide
journal, June 2003

Modified SiO as a high performance anode for Li-ion batteries
journal, January 2013

Improvement in Cycle Performance and Clarification of Deterioration Mechanism of Lithium-Ion Full Cells Using SiO Anodes
journal, January 2013

Lithium trapping in alloy forming electrodes and current collectors for lithium based batteries
journal, January 2017

Effect of Volume Expansion on SEI Covering Carbon-Coated Nano-Si/SiO Composite
journal, January 2013

Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries
journal, January 2007