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Title: Paradigm Shift for Radical S -Adenosyl- l -methionine Reactions: The Organometallic Intermediate Ω Is Central to Catalysis

Authors:
 [1] ;  [2] ;  [1] ;  [2] ;  [1] ;  [1] ;  [1] ;  [1] ;  [3] ;  [3] ;  [1] ;  [1] ;  [4] ;  [4] ;  [5] ; ORCiD logo [5] ;  [1] ; ORCiD logo [2] ; ORCiD logo [1]
  1. Department of Chemistry &, Biochemistry, Montana State University, Bozeman, Montana 59717, United States
  2. Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States
  3. Institute of Microbiology, Eidgenössische Technische Hochschule Zürich, Vladimir-Prelog-Weg 4, Zürich 8093, Switzerland
  4. Cassia, LLC, 3030 Bunker Hill Street, Ste. 214, San Diego, California 92109, United States
  5. Department of Biochemistry, Duke University Medical Center, Durham, North Carolina 27710, United States
Publication Date:
Grant/Contract Number:
SC0005404
Type:
Published Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 140; Journal Issue: 28; Related Information: CHORUS Timestamp: 2018-07-18 17:27:18; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
OSTI Identifier:
1459248