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Title: Surface modification of carbon black nanoparticles enhances photothermal separation and release of CO2

Abstract

Here, carbon black nanoparticles (CB) were covalently modified to improve the photothermal regeneration of a CO2 capture nanofluid through decarboxylation. The photothermal release of CO2 addresses high energy costs associated with regenerating capture fluids. By incorporating sulfonamides on the surface of CB, we enhance the photothermal separation of CO2 from MEA by approximately 70% more than the unmodified CB. In contrast, with an anionic sulfonate on the surface, the total CO2 released fell by approximately 60%. We verified the chemical composition and structure of surface modification using complementary techniques including FT-IR, TGA, XPS, and Raman spectroscopy.

Authors:
ORCiD logo [1];  [2];  [1]
  1. Univ. of California, Irvine, CA (United States). Dept. of Chemistry
  2. Univ. of California, Irvine, CA (United States). Dept. of Physics and Astronomy; Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); US Dept. of Education (DoED); USDOD: US Air Force Office of Scientific Research (AFOSR); 3M Company, Maplewood, MN (United States); American Chemical Society (ACS) Petroleum Research Fund (PRF); National Science Foundation (NSF)
Contributing Org.:
Cabot Corp., Boston, MA (United States)
OSTI Identifier:
1459137
Report Number(s):
LLNL-JRNL-748226
Journal ID: ISSN 0008-6223; 932400
Grant/Contract Number:  
AC52-07NA27344; FA9550-12-1-0352; CHE-1338173
Resource Type:
Accepted Manuscript
Journal Name:
Carbon
Additional Journal Information:
Journal Volume: 105; Journal Issue: C; Journal ID: ISSN 0008-6223
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Goetz, Samantha A., Nguyen, Du T., and Esser-Kahn, Aaron P. Surface modification of carbon black nanoparticles enhances photothermal separation and release of CO2. United States: N. p., 2016. Web. doi:10.1016/j.carbon.2016.03.053.
Goetz, Samantha A., Nguyen, Du T., & Esser-Kahn, Aaron P. Surface modification of carbon black nanoparticles enhances photothermal separation and release of CO2. United States. doi:10.1016/j.carbon.2016.03.053.
Goetz, Samantha A., Nguyen, Du T., and Esser-Kahn, Aaron P. Mon . "Surface modification of carbon black nanoparticles enhances photothermal separation and release of CO2". United States. doi:10.1016/j.carbon.2016.03.053. https://www.osti.gov/servlets/purl/1459137.
@article{osti_1459137,
title = {Surface modification of carbon black nanoparticles enhances photothermal separation and release of CO2},
author = {Goetz, Samantha A. and Nguyen, Du T. and Esser-Kahn, Aaron P.},
abstractNote = {Here, carbon black nanoparticles (CB) were covalently modified to improve the photothermal regeneration of a CO2 capture nanofluid through decarboxylation. The photothermal release of CO2 addresses high energy costs associated with regenerating capture fluids. By incorporating sulfonamides on the surface of CB, we enhance the photothermal separation of CO2 from MEA by approximately 70% more than the unmodified CB. In contrast, with an anionic sulfonate on the surface, the total CO2 released fell by approximately 60%. We verified the chemical composition and structure of surface modification using complementary techniques including FT-IR, TGA, XPS, and Raman spectroscopy.},
doi = {10.1016/j.carbon.2016.03.053},
journal = {Carbon},
number = C,
volume = 105,
place = {United States},
year = {2016},
month = {4}
}

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Cited by: 4 works
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