H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity
Abstract
Abstract Aqueous rechargeable zinc ion batteries are considered a promising candidate for large‐scale energy storage owing to their low cost and high safety nature. A composite material comprised of H 2 V 3 O 8 nanowires (NWs) wrapped by graphene sheets and used as the cathode material for aqueous rechargeable zinc ion batteries is developed. Owing to the synergistic merits of desirable structural features of H 2 V 3 O 8 NWs and high conductivity of the graphene network, the H 2 V 3 O 8 NW/graphene composite exhibits superior zinc ion storage performance including high capacity of 394 mA h g −1 at 1/3 C, high rate capability of 270 mA h g −1 at 20 C and excellent cycling stability of up to 2000 cycles with a capacity retention of 87%. The battery offers a high energy density of 168 W h kg −1 at 1/3 C and a high power density of 2215 W kg −1 at 20 C (calculated based on the total weight of H 2 V 3 O 8 NW/graphene composite and the theoretically required amount of Zn). Systematic structural and elemental characterization confirm the reversible Zn 2+ and water cointercalation electrochemical reaction mechanism.more »
- Authors:
-
- Department of Materials Science and Engineering University of Wisconsin‐Madison Madison WI 53706 USA, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education) College of Physics Jilin University Changchun 130012 P. R. China
- Department of Materials Science and Engineering University of Wisconsin‐Madison Madison WI 53706 USA
- Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education) College of Physics Jilin University Changchun 130012 P. R. China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1459042
- Grant/Contract Number:
- #DE‐SC0008711; DE‐FG02‐08ER46547
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Name: Advanced Energy Materials Journal Volume: 8 Journal Issue: 19; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Pang, Qiang, Sun, Congli, Yu, Yanhao, Zhao, Kangning, Zhang, Ziyi, Voyles, Paul M., Chen, Gang, Wei, Yingjin, and Wang, Xudong. H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity. Germany: N. p., 2018.
Web. doi:10.1002/aenm.201800144.
Pang, Qiang, Sun, Congli, Yu, Yanhao, Zhao, Kangning, Zhang, Ziyi, Voyles, Paul M., Chen, Gang, Wei, Yingjin, & Wang, Xudong. H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity. Germany. https://doi.org/10.1002/aenm.201800144
Pang, Qiang, Sun, Congli, Yu, Yanhao, Zhao, Kangning, Zhang, Ziyi, Voyles, Paul M., Chen, Gang, Wei, Yingjin, and Wang, Xudong. Sun .
"H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity". Germany. https://doi.org/10.1002/aenm.201800144.
@article{osti_1459042,
title = {H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity},
author = {Pang, Qiang and Sun, Congli and Yu, Yanhao and Zhao, Kangning and Zhang, Ziyi and Voyles, Paul M. and Chen, Gang and Wei, Yingjin and Wang, Xudong},
abstractNote = {Abstract Aqueous rechargeable zinc ion batteries are considered a promising candidate for large‐scale energy storage owing to their low cost and high safety nature. A composite material comprised of H 2 V 3 O 8 nanowires (NWs) wrapped by graphene sheets and used as the cathode material for aqueous rechargeable zinc ion batteries is developed. Owing to the synergistic merits of desirable structural features of H 2 V 3 O 8 NWs and high conductivity of the graphene network, the H 2 V 3 O 8 NW/graphene composite exhibits superior zinc ion storage performance including high capacity of 394 mA h g −1 at 1/3 C, high rate capability of 270 mA h g −1 at 20 C and excellent cycling stability of up to 2000 cycles with a capacity retention of 87%. The battery offers a high energy density of 168 W h kg −1 at 1/3 C and a high power density of 2215 W kg −1 at 20 C (calculated based on the total weight of H 2 V 3 O 8 NW/graphene composite and the theoretically required amount of Zn). Systematic structural and elemental characterization confirm the reversible Zn 2+ and water cointercalation electrochemical reaction mechanism. This work brings a new prospect of designing high‐performance aqueous rechargeable zinc ion batteries for grid‐scale energy storage.},
doi = {10.1002/aenm.201800144},
journal = {Advanced Energy Materials},
number = 19,
volume = 8,
place = {Germany},
year = {Sun Mar 25 00:00:00 EDT 2018},
month = {Sun Mar 25 00:00:00 EDT 2018}
}
https://doi.org/10.1002/aenm.201800144
Web of Science
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