Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe2 (dobdc) Analogues
Abstract
Here, metal–organic frameworks are a new class of heterogeneous catalysts in which molecular-level control over both the immediate and long-range chemical environment surrounding a catalytic center can be readily achieved. Here, the oxidation of cyclohexane to cyclohexanol and cyclohexanone is used as a model reaction to investigate the effect of a hydrophobic pore environment on product selectivity and catalyst stability in a series of iron-based frameworks. Specifically, expanded analogues of Fe2(dobdc) (dobdc4– = 2,5-dioxido-1,4-benzenedicarboxylate) were synthesized and evaluated, including the biphenyl derivative Fe2(dobpdc) (H4dobpdc = 4,4¢-dihydroxy-[1,1¢-biphenyl]-3,3¢-dicarboxylic acid), the terphenyl derivative Fe2(dotpdc) (H4dotpdc = 4,4¢¢-dihydroxy-[1,1¢:4¢,1¢¢-terphenyl]-3,3¢¢-dicarboxylic acid), and three modified terphenyl derivatives in which the central ring is replaced with tetrafluoro-, tetramethyl-, or di-tert-butylaryl groups. Within these five materials, a remarkable three-fold enhancement of the alcohol:ketone (A:K) ratio and an order of magnitude increase in turnover number is achieved by simply altering the framework pore diameter and installing nonpolar functional groups near the iron site. Mössbauer spectroscopy, kinetic isotope effect, and gas adsorption measurements reveal that variations in the A:K selectivities arise from differences in the cyclohexane adsorption enthalpies of these frameworks, which become more favorable as the number of hydrophobic residues and thus van der Waals interactions increases.
- Authors:
-
- Univ. of California, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Univ. of Minnesota, Minneapolis, MN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1458984
- Grant/Contract Number:
- FG02-12ER16362; SC0008688
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 138; Journal Issue: 43; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Xiao, Dianne J., Oktawiec, Julia, Milner, Phillip J., and Long, Jeffrey R. Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe2 (dobdc) Analogues. United States: N. p., 2016.
Web. doi:10.1021/jacs.6b08417.
Xiao, Dianne J., Oktawiec, Julia, Milner, Phillip J., & Long, Jeffrey R. Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe2 (dobdc) Analogues. United States. https://doi.org/10.1021/jacs.6b08417
Xiao, Dianne J., Oktawiec, Julia, Milner, Phillip J., and Long, Jeffrey R. Wed .
"Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe2 (dobdc) Analogues". United States. https://doi.org/10.1021/jacs.6b08417. https://www.osti.gov/servlets/purl/1458984.
@article{osti_1458984,
title = {Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe2 (dobdc) Analogues},
author = {Xiao, Dianne J. and Oktawiec, Julia and Milner, Phillip J. and Long, Jeffrey R.},
abstractNote = {Here, metal–organic frameworks are a new class of heterogeneous catalysts in which molecular-level control over both the immediate and long-range chemical environment surrounding a catalytic center can be readily achieved. Here, the oxidation of cyclohexane to cyclohexanol and cyclohexanone is used as a model reaction to investigate the effect of a hydrophobic pore environment on product selectivity and catalyst stability in a series of iron-based frameworks. Specifically, expanded analogues of Fe2(dobdc) (dobdc4– = 2,5-dioxido-1,4-benzenedicarboxylate) were synthesized and evaluated, including the biphenyl derivative Fe2(dobpdc) (H4dobpdc = 4,4¢-dihydroxy-[1,1¢-biphenyl]-3,3¢-dicarboxylic acid), the terphenyl derivative Fe2(dotpdc) (H4dotpdc = 4,4¢¢-dihydroxy-[1,1¢:4¢,1¢¢-terphenyl]-3,3¢¢-dicarboxylic acid), and three modified terphenyl derivatives in which the central ring is replaced with tetrafluoro-, tetramethyl-, or di-tert-butylaryl groups. Within these five materials, a remarkable three-fold enhancement of the alcohol:ketone (A:K) ratio and an order of magnitude increase in turnover number is achieved by simply altering the framework pore diameter and installing nonpolar functional groups near the iron site. Mössbauer spectroscopy, kinetic isotope effect, and gas adsorption measurements reveal that variations in the A:K selectivities arise from differences in the cyclohexane adsorption enthalpies of these frameworks, which become more favorable as the number of hydrophobic residues and thus van der Waals interactions increases.},
doi = {10.1021/jacs.6b08417},
journal = {Journal of the American Chemical Society},
number = 43,
volume = 138,
place = {United States},
year = {Wed Oct 05 00:00:00 EDT 2016},
month = {Wed Oct 05 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 120 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Figure 1.: Portions of the crystal structures of Fe2(dobdc), Fe2(dobpdc), Fe2(dotpdc) and their corresponding ligands. (a) View of the one-dimensional hexagonal pores of Fe2(dobdc), with an inset showing the local coordination environment around each coordinatively unsaturated iron(II) site. The pore sizes indicated here were calculated from experimental 77-K N2 adsorptionmore »
All figures and tables
(10 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Insights into metalloenzyme microenvironments: biomimetic metal complexes with a functional second coordination sphere
journal, January 2013
- Zhao, Meng; Wang, Hai-Bo; Ji, Liang-Nian
- Chemical Society Reviews, Vol. 42, Issue 21
Supramolecular catalysis. Part 2: artificial enzyme mimics
journal, January 2014
- Raynal, Matthieu; Ballester, Pablo; Vidal-Ferran, Anton
- Chem. Soc. Rev., Vol. 43, Issue 5
Molecular Designs for Controlling the Local Environments around Metal Ions
journal, July 2015
- Cook, Sarah A.; Borovik, A. S.
- Accounts of Chemical Research, Vol. 48, Issue 8
Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen
journal, January 2005
- Borovik, A. S.
- Accounts of Chemical Research, Vol. 38, Issue 1
Artificial Enzymes
journal, January 1996
- Murakami, Yukito; Kikuchi, Jun-ichi; Hisaeda, Yoshio
- Chemical Reviews, Vol. 96, Issue 2
Biomimetic Reactions Catalyzed by Cyclodextrins and Their Derivatives
journal, July 1998
- Breslow, Ronald; Dong, Steven D.
- Chemical Reviews, Vol. 98, Issue 5
The Use of Calixarenes in Metal-Based Catalysis
journal, December 2008
- Homden, Damien M.; Redshaw, Carl
- Chemical Reviews, Vol. 108, Issue 12
Selective Molecular Recognition, C−H Bond Activation, and Catalysis in Nanoscale Reaction Vessels
journal, April 2005
- Fiedler, Dorothea; Leung, Dennis H.; Bergman, Robert G.
- Accounts of Chemical Research, Vol. 38, Issue 4
Zeolites as solid solvents1Paper presented at the International Symposium `Organic Chemistry and Catalysis' on the occasion of the 65th birthday of Prof. H. van Bekkum, Delft, Netherlands, 2–3 October 1997.1
journal, September 1998
- Derouane, Eric G.
- Journal of Molecular Catalysis A: Chemical, Vol. 134, Issue 1-3
Small-Molecule H-Bond Donors in Asymmetric Catalysis
journal, December 2007
- Doyle, Abigail G.; Jacobsen, Eric N.
- Chemical Reviews, Vol. 107, Issue 12
Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation
journal, April 2010
- Shook, Ryan L.; Borovik, A. S.
- Inorganic Chemistry, Vol. 49, Issue 8
The roles of the first and second coordination spheres in the design of molecular catalysts for H 2 production and oxidation
journal, January 2009
- Rakowski DuBois, M.; DuBois, Daniel L.
- Chem. Soc. Rev., Vol. 38, Issue 1
Catalysis of the electrochemical reduction of carbon dioxide
journal, January 2013
- Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel
- Chem. Soc. Rev., Vol. 42, Issue 6
Zeolites as catalysts in oil refining
journal, January 2014
- Primo, Ana; Garcia, Hermenegildo
- Chem. Soc. Rev., Vol. 43, Issue 22
Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions
journal, January 2016
- Dyson, Paul J.; Jessop, Philip G.
- Catalysis Science & Technology, Vol. 6, Issue 10
Shape-Selective Catalysis in Zeolites
book, January 1999
- Weitkamp, Jens; Ernst, Stefan; Puppe, Lothar
- Catalysis and Zeolites
State of the art and future challenges of zeolites as catalysts
journal, May 2003
- Corma, Avelino
- Journal of Catalysis, Vol. 216, Issue 1-2
From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis
journal, October 1997
- Corma, Avelino
- Chemical Reviews, Vol. 97, Issue 6, p. 2373-2420
Design and Preparation of Organic−Inorganic Hybrid Catalysts
journal, October 2002
- Wight, A. P.; Davis, M. E.
- Chemical Reviews, Vol. 102, Issue 10
Ordered mesoporous materials in catalysis
journal, January 2005
- Taguchi, Akira; Schüth, Ferdi
- Microporous and Mesoporous Materials, Vol. 77, Issue 1
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
journal, August 2010
- Chen, Banglin; Xiang, Shengchang; Qian, Guodong
- Accounts of Chemical Research, Vol. 43, Issue 8
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010
- Deng, H.; Doonan, C. J.; Furukawa, H.
- Science, Vol. 327, Issue 5967, p. 846-850
Mapping of Functional Groups in Metal-Organic Frameworks
journal, July 2013
- Kong, X.; Deng, H.; Yan, F.
- Science, Vol. 341, Issue 6148, p. 882-885
Programmed Pore Architectures in Modular Quaternary Metal–Organic Frameworks
journal, November 2013
- Liu, Lujia; Konstas, Kristina; Hill, Matthew R.
- Journal of the American Chemical Society, Vol. 135, Issue 47
Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs
journal, July 2016
- Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng
- Journal of the American Chemical Society, Vol. 138, Issue 28
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009
- Ma, Liqing; Abney, Carter; Lin, Wenbin
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis
journal, January 2014
- Liu, Jiewei; Chen, Lianfen; Cui, Hao
- Chemical Society Reviews, Vol. 43, Issue 16, p. 6011-6061
Toward “metalloMOFzymes”: Metal–Organic Frameworks with Single-Site Metal Catalysts for Small-Molecule Transformations
journal, May 2016
- Cohen, Seth M.; Zhang, Zhenjie; Boissonnault, Jake A.
- Inorganic Chemistry, Vol. 55, Issue 15
Isoreticular Chiral Metal−Organic Frameworks for Asymmetric Alkene Epoxidation: Tuning Catalytic Activity by Controlling Framework Catenation and Varying Open Channel Sizes
journal, November 2010
- Song, Feijie; Wang, Cheng; Falkowski, Joseph M.
- Journal of the American Chemical Society, Vol. 132, Issue 43
Urea Metal–Organic Frameworks as Effective and Size-Selective Hydrogen-Bond Catalysts
journal, February 2012
- Roberts, John M.; Fini, Branden M.; Sarjeant, Amy A.
- Journal of the American Chemical Society, Vol. 134, Issue 7
Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation
journal, February 2012
- Lu, Guang; Li, Shaozhou; Guo, Zhen
- Nature Chemistry, Vol. 4, Issue 4, p. 310-316
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst
journal, February 2016
- Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J.
- ACS Central Science, Vol. 2, Issue 3
Capturing snapshots of post-synthetic metallation chemistry in metal–organic frameworks
journal, September 2014
- Bloch, Witold M.; Burgun, Alexandre; Coghlan, Campbell J.
- Nature Chemistry, Vol. 6, Issue 10
Single-Crystal-to-Single-Crystal Metalation of a Metal–Organic Framework: A Route toward Structurally Well-Defined Catalysts
journal, February 2015
- Gonzalez, Miguel I.; Bloch, Eric D.; Mason, Jarad A.
- Inorganic Chemistry, Vol. 54, Issue 6
Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
journal, February 2004
- Costas, Miquel; Mehn, Mark P.; Jensen, Michael P.
- Chemical Reviews, Vol. 104, Issue 2
From simple to supramolecular cytochrome P450 mimics
journal, January 2000
- Feiters, Martinus C.; Rowan, Alan E.; Nolte, Roeland J. M.
- Chemical Society Reviews, Vol. 29, Issue 6
Liquid-Phase Adsorption of Aromatics over a Metal–Organic Framework and Activated Carbon: Effects of Hydrophobicity/Hydrophilicity of Adsorbents and Solvent Polarity
journal, November 2015
- Bhadra, Biswa Nath; Cho, Kyung Ho; Khan, Nazmul Abedin
- The Journal of Physical Chemistry C, Vol. 119, Issue 47
Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
journal, September 2011
- Bloch, Eric D.; Murray, Leslie J.; Queen, Wendy L.
- Journal of the American Chemical Society, Vol. 133, Issue 37
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
journal, March 2012
- Bloch, E. D.; Queen, W. L.; Krishna, R.
- Science, Vol. 335, Issue 6076, p. 1606-1610
Reversible CO Binding Enables Tunable CO/H 2 and CO/N 2 Separations in Metal–Organic Frameworks with Exposed Divalent Metal Cations
journal, July 2014
- Bloch, Eric D.; Hudson, Matthew R.; Mason, Jarad A.
- Journal of the American Chemical Society, Vol. 136, Issue 30
Gradual Release of Strongly Bound Nitric Oxide from Fe 2 (NO) 2 (dobdc)
journal, March 2015
- Bloch, Eric D.; Queen, Wendy L.; Chavan, Sachin
- Journal of the American Chemical Society, Vol. 137, Issue 10
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
journal, May 2014
- Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A.
- Nature Chemistry, Vol. 6, Issue 7
Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes
journal, July 2015
- Puri, Mayank; Que, Lawrence
- Accounts of Chemical Research, Vol. 48, Issue 8
Mechanism of Oxidation of Ethane to Ethanol at Iron(IV)–Oxo Sites in Magnesium-Diluted Fe 2 (dobdc)
journal, April 2015
- Verma, Pragya; Vogiatzis, Konstantinos D.; Planas, Nora
- Journal of the American Chemical Society, Vol. 137, Issue 17
Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012
- Deng, H.; Grunder, S.; Cordova, K. E.
- Science, Vol. 336, Issue 6084, p. 1018-1023
Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal–Organic Framework Crystals
journal, June 2016
- Fracaroli, Alejandro M.; Siman, Peter; Nagib, David A.
- Journal of the American Chemical Society, Vol. 138, Issue 27
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015
- McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
- Nature, Vol. 519, Issue 7543
Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M 2 (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)
journal, February 2016
- Gygi, David; Bloch, Eric D.; Mason, Jarad A.
- Chemistry of Materials, Vol. 28, Issue 4
Fast Calculation of van der Waals Volume as a Sum of Atomic and Bond Contributions and Its Application to Drug Compounds
journal, September 2003
- Zhao, Yuan H.; Abraham, Michael H.; Zissimos, Andreas M.
- The Journal of Organic Chemistry, Vol. 68, Issue 19
To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes
journal, January 2016
- Cho, Kyung-Bin; Hirao, Hajime; Shaik, Sason
- Chemical Society Reviews, Vol. 45, Issue 5
Nonheme Fe IV O Complexes That Can Oxidize the C−H Bonds of Cyclohexane at Room Temperature
journal, January 2004
- Kaizer, József; Klinker, Eric J.; Oh, Na Young
- Journal of the American Chemical Society, Vol. 126, Issue 2
Modeling TauD- J : A High-Spin Nonheme Oxoiron(IV) Complex with High Reactivity toward C–H Bonds
journal, February 2015
- Biswas, Achintesh N.; Puri, Mayank; Meier, Katlyn K.
- Journal of the American Chemical Society, Vol. 137, Issue 7
Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme Fe IV O Complexes
journal, December 2012
- Cho, Kyung-Bin; Wu, Xiujuan; Lee, Yong-Min
- Journal of the American Chemical Society, Vol. 134, Issue 50
Mononuclear Nonheme High-Spin ( S =2) versus Intermediate-Spin ( S =1) Iron(IV)-Oxo Complexes in Oxidation Reactions
journal, June 2016
- Bae, Seong Hee; Seo, Mi Sook; Lee, Yong-Min
- Angewandte Chemie International Edition, Vol. 55, Issue 28
The Road to Non-Heme Oxoferryls and Beyond †
journal, July 2007
- Que, Lawrence
- Accounts of Chemical Research, Vol. 40, Issue 7
The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol
journal, April 2009
- Vermeulen, Nicolaas A.; Chen, Mark S.; Christina White, M.
- Tetrahedron, Vol. 65, Issue 16
The Crystal Structure of a High-Spin Oxoiron(IV) Complex and Characterization of Its Self-Decay Pathway
journal, June 2010
- England, Jason; Guo, Yisong; Farquhar, Erik R.
- Journal of the American Chemical Society, Vol. 132, Issue 25
Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes
journal, July 2012
- Talsi, Evgenii P.; Bryliakov, Konstantin P.
- Coordination Chemistry Reviews, Vol. 256, Issue 13-14
Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions
journal, January 2015
- Lindhorst, A. C.; Haslinger, S.; Kühn, Fritz E.
- Chemical Communications, Vol. 51, Issue 97
Oxidations of cycloalkanes and benzene by hydrogen peroxide catalyzed by an {FeIIIN2S2} centre
journal, January 2009
- Fernandes, Ricardo R.; Kirillova, Marina V.; da Silva, José A. L.
- Applied Catalysis A: General, Vol. 353, Issue 1
Synthesis and structural characterization of iron complexes with 2,2,2-tris(1-pyrazolyl)ethanol ligands: Application in the peroxidative oxidation of cyclohexane under mild conditions
journal, March 2011
- Silva, Telma F. S.; Guedes da Silva, M. Fátima; Mishra, Gopal S.
- Journal of Organometallic Chemistry, Vol. 696, Issue 6
Atmospheric‐Pressure, Liquid‐Phase, Selective Aerobic Oxidation of Alkanes Catalysed by Metal–Organic Frameworks
journal, April 2011
- Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes; Garcia, Hermenegildo
- Chemistry – A European Journal, Vol. 17, Issue 22
Cyclohexane selective oxidation over metal–organic frameworks of MIL-101 family: superior catalytic activity and selectivity
journal, January 2012
- Maksimchuk, Nataliya V.; Kovalenko, Konstantin A.; Fedin, Vladimir P.
- Chemical Communications, Vol. 48, Issue 54
Superior Performance of Fe(BTC) With Respect to Other Metal-Containing Solids in the N -Hydroxyphthalimide-Promoted Heterogeneous Aerobic Oxidation of Cycloalkanes
journal, March 2013
- Mikami, Yusuke; Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes
- ChemCatChem, Vol. 5, Issue 7
Liquid phase oxidation of n-octane to C8 oxygenates over modified Fe-MOF-5 catalysts
journal, December 2014
- Cele, Mduduzi N.; Friedrich, Holger B.; Bala, Muhammad D.
- Catalysis Communications, Vol. 57
Kinetic Isotope Effect is a Sensitive Probe of Spin State Reactivity in C−H Hydroxylation of N , N -Dimethylaniline by Cytochrome P450
journal, January 2006
- Li, Chunsen; Wu, Wei; Kumar, Devesh
- Journal of the American Chemical Society, Vol. 128, Issue 2
A Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes
journal, January 2009
- Klinker, Eric J.; Shaik, Sason; Hirao, Hajime
- Angewandte Chemie International Edition, Vol. 48, Issue 7
Reactivity of High-Valent Iron–Oxo Species in Enzymes and Synthetic Reagents: A Tale of Many States
journal, July 2007
- Shaik, Sason; Hirao, Hajime; Kumar, Devesh
- Accounts of Chemical Research, Vol. 40, Issue 7
Evidence for Hydrogen Abstraction from C1 of Taurine by the High-Spin Fe(IV) Intermediate Detected during Oxygen Activation by Taurine:α-Ketoglutarate Dioxygenase (TauD)
journal, October 2003
- Price, John C.; Barr, Eric W.; Glass, Timothy E.
- Journal of the American Chemical Society, Vol. 125, Issue 43
A Synthetic High-Spin Oxoiron(IV) Complex: Generation, Spectroscopic Characterization, and Reactivity
journal, May 2009
- England, Jason; Martinho, Marlène; Farquhar, Erik R.
- Angewandte Chemie International Edition, Vol. 48, Issue 20
Low-coverage adsorption properties of the metal–organic framework MIL-47 studied by pulse chromatography and Monte Carlo simulations
journal, January 2009
- Finsy, Vincent; Calero, Sofia; García-Pérez, Elena
- Physical Chemistry Chemical Physics, Vol. 11, Issue 18
Microporous Metal-Organic Frameworks with High Gas Sorption and Separation Capacity
journal, April 2007
- Lee, J. Y.; Olson, D. H.; Pan, L.
- Advanced Functional Materials, Vol. 17, Issue 8
Henry's constants, isotherms and heats of adsorption of some hydrocarbons in zeolites of faujasite type with different content of sodium cations
journal, October 1984
- Dzhigit, O. M.; Kiselev, A. V.; Rachmanova, T. A.
- Zeolites, Vol. 4, Issue 4
Adsorption of volatile organic compounds onto carbon nanotubes, carbon nanofibers, and high-surface-area graphites
journal, January 2007
- Díaz, Eva; Ordóñez, Salvador; Vega, Aurelio
- Journal of Colloid and Interface Science, Vol. 305, Issue 1
Works referencing / citing this record:
A Bifunctional MOF Catalyst Containing Metal–Phosphine and Lewis Acidic Active Sites
journal, September 2018
- Prasad, Ram R. R.; Dawson, Daniel M.; Cox, Paul A.
- Chemistry – A European Journal, Vol. 24, Issue 57
HCl and O 2 co-activated bis(8-quinolinolato) oxovanadium( iv ) complexes as efficient photoactive species for visible light-driven oxidation of cyclohexane to KA oil
journal, January 2019
- She, Jialuo; Lin, Xiangfeng; Fu, Zaihui
- Catalysis Science & Technology, Vol. 9, Issue 2
Nature-mimic fabricated polydopamine/MIL-53(Fe): efficient visible-light responsive photocatalysts for the selective oxidation of alcohols
journal, January 2020
- Meng, Shuangyan; Zeng, Wei; Wang, Mingming
- New Journal of Chemistry, Vol. 44, Issue 5
Hydrophobic Modification of Microenvironment of Highly Dispersed Co 3 O 4 Nanoparticles for the Catalytic Selective Oxidation of Ethylbenzene
journal, November 2019
- Zhao, Li; Shi, Song; Liu, Meng
- ChemCatChem, Vol. 12, Issue 3
Fast Cyclohexane Oxidation Under Mild Reaction Conditions Through a Controlled Creation of Redox‐Active Fe(II/III) Sites in a Metal−Organic Framework
journal, October 2019
- Kim, Ah‐Reum; Ahn, Sol; Yoon, Tae‐Ung
- ChemCatChem, Vol. 11, Issue 22
Redox-active metal–organic frameworks for energy conversion and storage
journal, January 2019
- Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
- Journal of Materials Chemistry A, Vol. 7, Issue 28
Boosting selective oxidation of cyclohexane over a metal–organic framework by hydrophobicity engineering of pore walls
journal, January 2017
- Li, Luyan; Yang, Qihao; Chen, Si
- Chemical Communications, Vol. 53, Issue 72
Pseudo‐Gated Adsorption with Negligible Volume Change Evoked by Halogen‐Bond Interaction in the Nanospace of MOFs
journal, January 2020
- Kanoo, Prakash; Matsuda, Ryotaro; Sato, Hiroshi
- Chemistry – A European Journal, Vol. 26, Issue 10
Organic amines as templates: pore imprints with exactly matching sizes in a series of metal–organic frameworks
journal, January 2018
- Zhao, Nian; Yang, Lun; Xie, Bo
- Chemical Communications, Vol. 54, Issue 80
Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography
journal, February 2017
- Burgun, Alexandre; Coghlan, Campbell J.; Huang, David M.
- Angewandte Chemie, Vol. 129, Issue 29
Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers
journal, March 2018
- Yuan, Kuo; Song, Tianqun; Wang, Dawei
- Angewandte Chemie, Vol. 130, Issue 20
Copper‐doped sulfonic acid‐functionalized MIL‐101(Cr) metal–organic framework for efficient aerobic oxidation reactions
journal, January 2020
- Li, Xiujuan; Zhou, Zihao; Zhao, Yuzhen
- Applied Organometallic Chemistry, Vol. 34, Issue 4
Ethylene oligomerization in metal–organic frameworks bearing nickel( ii ) 2,2′-bipyridine complexes
journal, January 2017
- Gonzalez, Miguel I.; Oktawiec, Julia; Long, Jeffrey R.
- Faraday Discussions, Vol. 201
A new iron-based metal–organic framework with enhancing catalysis activity for benzene hydroxylation
journal, January 2019
- Tu, Thach N.; Nguyen, Hue T. T.; Nguyen, Huong T. D.
- RSC Advances, Vol. 9, Issue 29
The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks
journal, January 2020
- Zhou, Mi; El-Sayed, El-Sayed M.; Ju, Zhanfeng
- Inorganic Chemistry Frontiers, Vol. 7, Issue 6
Metal‐Organic Frameworks as Platform for Lewis‐Acid‐Catalyzed Organic Transformations
journal, July 2019
- Yadav, Anand; Kanoo, Prakash
- Chemistry – An Asian Journal, Vol. 14, Issue 20
In Operando Analysis of Diffusion in Porous Metal‐Organic Framework Catalysts
journal, December 2018
- Gao, Wen‐Yang; Cardenal, Ashley D.; Wang, Chen‐Hao
- Chemistry – A European Journal, Vol. 25, Issue 14
Sustainability in Catalytic Cyclohexane Oxidation: The Contribution of Porous Support Materials
journal, December 2019
- Andrade, Marta A.; Martins, Luísa M. D. R. S.
- Catalysts, Vol. 10, Issue 1
Recent Advances in Iron Catalyzed Oxidation Reactions of Organic Compounds
journal, August 2017
- Bauer, Eike B.
- Israel Journal of Chemistry, Vol. 57, Issue 12
Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal-Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers
journal, March 2018
- Yuan, Kuo; Song, Tianqun; Wang, Dawei
- Angewandte Chemie International Edition, Vol. 57, Issue 20
Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment
journal, March 2018
- Grigoropoulos, Alexios; McKay, Alasdair I.; Katsoulidis, Alexandros P.
- Angewandte Chemie International Edition, Vol. 57, Issue 17
A series of new mixed-ligand complexes based on 3,6-bis(imidazol-1-yl)pyridazine: syntheses, structures, and catalytic activities
journal, January 2017
- Zhou, Sheng-Bin; Wang, Xin-Fang; Du, Ceng-Ceng
- CrystEngComm, Vol. 19, Issue 23
Fine tuning of catalytic and sorption properties of metal–organic frameworks via in situ ligand exchange
journal, January 2017
- Wang, Peng; Chen, Kai; Liu, Qing
- Dalton Transactions, Vol. 46, Issue 34
A complex metal-organic framework catalyst for microwave-assisted radical polymerization
journal, October 2018
- Nguyen, Ha L.; Vu, Thanh T.; Nguyen, Dinh-Khoi
- Communications Chemistry, Vol. 1, Issue 1
Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework
journal, January 2020
- Zee, David Z.; Harris, T. David
- Chemical Science, Vol. 11, Issue 21
Hydrophobic Metal–Organic Frameworks
journal, June 2019
- Jayaramulu, Kolleboyina; Geyer, Florian; Schneemann, Andreas
- Advanced Materials
Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment
journal, March 2018
- Grigoropoulos, Alexios; McKay, Alasdair I.; Katsoulidis, Alexandros P.
- Angewandte Chemie, Vol. 130, Issue 17
Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography
journal, February 2017
- Burgun, Alexandre; Coghlan, Campbell J.; Huang, David M.
- Angewandte Chemie International Edition, Vol. 56, Issue 29
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.