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Title: Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, University at Buffalo, The State University of New York, Buffalo NY 14260 USA
  2. Department of Materials, Design, and Innovation, University at Buffalo, The State University of New York, Buffalo NY 14260 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1458781
Grant/Contract Number:  
[AC02-05CH11231]
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
[Journal Name: Chemistry - A European Journal Journal Volume: 24 Journal Issue: 43]; Journal ID: ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Oldacre, Amanda N., Crawley, Matthew R., Friedman, Alan E., and Cook, Timothy R. Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly. Germany: N. p., 2018. Web. doi:10.1002/chem.201802585.
Oldacre, Amanda N., Crawley, Matthew R., Friedman, Alan E., & Cook, Timothy R. Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly. Germany. doi:10.1002/chem.201802585.
Oldacre, Amanda N., Crawley, Matthew R., Friedman, Alan E., and Cook, Timothy R. Tue . "Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly". Germany. doi:10.1002/chem.201802585.
@article{osti_1458781,
title = {Tuning the Activity of Heterogeneous Cofacial Cobalt Porphyrins for Oxygen Reduction Electrocatalysis through Self-Assembly},
author = {Oldacre, Amanda N. and Crawley, Matthew R. and Friedman, Alan E. and Cook, Timothy R.},
abstractNote = {},
doi = {10.1002/chem.201802585},
journal = {Chemistry - A European Journal},
number = [43],
volume = [24],
place = {Germany},
year = {2018},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/chem.201802585

Citation Metrics:
Cited by: 2 works
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Works referenced in this record:

Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016


Cofaciale Bis(metallo)diporphyrine als potentielle molekulare Katalysatoren für Mehrelektronenreduktionen und -oxidationen kleiner Moleküle
journal, August 1994

  • Collman, James P.; Wagenknecht, Paul S.; Hutchison, James E.
  • Angewandte Chemie, Vol. 106, Issue 15-16
  • DOI: 10.1002/ange.19941061505

Highly Efficient NMR Enantiodiscrimination of Chiral Octanuclear Metalla-Boxes in Polar Solvent
journal, August 2009

  • Barry, Nicolas P. E.; Austeri, Martina; Lacour, Jérôme
  • Organometallics, Vol. 28, Issue 16
  • DOI: 10.1021/om900461s

Temperature Dependence of the Catalytic Two- versus Four-Electron Reduction of Dioxygen by a Hexanuclear Cobalt Complex
journal, October 2017

  • Monte-Pérez, Inés; Kundu, Subrata; Chandra, Anirban
  • Journal of the American Chemical Society, Vol. 139, Issue 42
  • DOI: 10.1021/jacs.7b07127

Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry
journal, June 2001


Anticancer activity of tetracationic arene ruthenium metalla-cycles
journal, January 2011

  • Barry, Nicolas P. E.; Edafe, Fabio; Therrien, Bruno
  • Dalton Transactions, Vol. 40, Issue 27
  • DOI: 10.1039/c1dt10489f

Role of Proton-Coupled Electron Transfer in O–O Bond Activation
journal, July 2007

  • Rosenthal, Joel; Nocera, Daniel G.
  • Accounts of Chemical Research, Vol. 40, Issue 7
  • DOI: 10.1021/ar7000638

Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts
journal, December 2017


Elementary Mechanisms in Electrocatalysis: Revisiting the ORR Tafel Slope
journal, January 2012

  • Holewinski, Adam; Linic, Suljo
  • Journal of The Electrochemical Society, Vol. 159, Issue 11
  • DOI: 10.1149/2.022211jes

Novel Multinuclear Catalysts for the Electroreduction of Dioxygen Directly to Water
journal, November 1997

  • Anson, Fred C.; Shi, Chunnian; Steiger, Beat
  • Accounts of Chemical Research, Vol. 30, Issue 11
  • DOI: 10.1021/ar960264j

Facile Synthesis of meso-Tetraaryl Cofacial Diporphyrins
journal, April 1995

  • Collman, James P.; Tyvoll, David A.; Chng, Leng Leng
  • The Journal of Organic Chemistry, Vol. 60, Issue 7
  • DOI: 10.1021/jo00112a008

Biomimetic Oxygen Reduction by Cofacial Porphyrins at a Liquid–Liquid Interface
journal, March 2012

  • Peljo, Pekka; Murtomäki, Lasse; Kallio, Tanja
  • Journal of the American Chemical Society, Vol. 134, Issue 13
  • DOI: 10.1021/ja3004914

Synthesis and photophysical studies of self-assembled multicomponent supramolecular coordination prisms bearing porphyrin faces
journal, June 2014

  • Shi, Yanhui; Sánchez-Molina, Irene; Cao, Changsheng
  • Proceedings of the National Academy of Sciences, Vol. 111, Issue 26
  • DOI: 10.1073/pnas.1408905111

Organometallic boxes built from 5,10,15,20-tetra(4-pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips
journal, October 2008

  • Barry, Nicolas P. E.; Govindaswamy, Padavattan; Furrer, Julien
  • Inorganic Chemistry Communications, Vol. 11, Issue 10
  • DOI: 10.1016/j.inoche.2008.08.007

Interactions of ruthenium coordination cubes with DNA
journal, January 2009

  • Barry, Nicolas P. E.; Abd Karim, Nurul H.; Vilar, Ramón
  • Dalton Transactions, Issue 48
  • DOI: 10.1039/b913642h

Oxygen Reduction to Water by a Cofacial Dimer of Iron(III)-Porphyrin and Iron(III)-Phthalocyanine Linked through a Highly Flexible Fourfold Rotaxane
journal, March 2017

  • Mihara, Nozomi; Yamada, Yasuyuki; Takaya, Hikaru
  • Chemistry - A European Journal, Vol. 23, Issue 31
  • DOI: 10.1002/chem.201700082

Molecular Catalysts for Multielectron Redox Reactions of Small Molecules: The“Cofacial Metallodiporphyrin” Approach
journal, September 1994

  • Collman, James P.; Wagenknecht, Paul S.; Hutchison, James E.
  • Angewandte Chemie International Edition in English, Vol. 33, Issue 1516
  • DOI: 10.1002/anie.199415371

Electrocatalytic four-electron reduction of oxygen to water by a highly flexible cofacial cobalt bisporphyrin
journal, January 2000

  • Chang, Christopher J.; Deng, Yongqi; Nocera, Daniel G.
  • Chemical Communications, Issue 15
  • DOI: 10.1039/b001620i

Synthesis, Characterization and Anticancer Activity of Porphyrin-Containing Organometallic Cubes
journal, January 2010

  • Barry, Nicolas P. E.; Zava, Olivier; Dyson, Paul J.
  • Australian Journal of Chemistry, Vol. 63, Issue 11
  • DOI: 10.1071/CH10221

Coordination-Driven Self-Assembly of Supramolecular Cages:  Heteroatom-Containing and Complementary Trigonal Prisms
journal, August 2003

  • Kryschenko, Yury K.; Seidel, S. Russell; Muddiman, David C.
  • Journal of the American Chemical Society, Vol. 125, Issue 32
  • DOI: 10.1021/ja030209n

Electrocatalytic activity and stability of substituted iron phthalocyanines towards oxygen reduction evaluated at different temperatures
journal, October 2008


α,β,γ,δ-Tetra-(4-pyridyl)-porphine and Some of its Metal Complexes
journal, August 1962


Mechanistic aspects of the catalytic reduction of dioxygen by cofacial metalloporphyrins
journal, May 1983

  • Durand, Richard R.; Bencosme, C. Susana; Collman, James P.
  • Journal of the American Chemical Society, Vol. 105, Issue 9
  • DOI: 10.1021/ja00347a032

Electroreduction of oxygen by pillared cobalt(II) cofacial diporphyrin catalysts
journal, May 1984

  • Chang, C. K.; Liu, H. Y.; Abdalmuhdi, I.
  • Journal of the American Chemical Society, Vol. 106, Issue 9
  • DOI: 10.1021/ja00321a055

Structural, Spectroscopic, and Reactivity Comparison of Xanthene- and Dibenzofuran-Bridged Cofacial Bisporphyrins
journal, June 2002

  • Chang, Christopher J.; Baker, Erin A.; Pistorio, Bradford J.
  • Inorganic Chemistry, Vol. 41, Issue 12
  • DOI: 10.1021/ic0111029

Coordination-Driven Assembly of Molecular Rectangles via an Organometallic “Clip”
journal, November 2000

  • Kuehl, Christopher J.; Mayne, Charles L.; Arif, Atta M.
  • Organic Letters, Vol. 2, Issue 23
  • DOI: 10.1021/ol006638x

Synthesis and Characterization of Cofacial Metallodiporphyrins Involving Cobalt and Lewis Acid Metals: New Dinuclear Multielectron Redox Catalysts of Dioxygen Reduction
journal, November 1995

  • Guilard, Roger; Brandes, Stephane; Tardieux, Catherine
  • Journal of the American Chemical Society, Vol. 117, Issue 47
  • DOI: 10.1021/ja00152a013

Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination
journal, March 2015

  • Cook, Timothy R.; Stang, Peter J.
  • Chemical Reviews, Vol. 115, Issue 15
  • DOI: 10.1021/cr5005666

A Self-Assembled Cofacial Cobalt Porphyrin Prism for Oxygen Reduction Catalysis
journal, January 2017

  • Oldacre, Amanda N.; Friedman, Alan E.; Cook, Timothy R.
  • Journal of the American Chemical Society, Vol. 139, Issue 4
  • DOI: 10.1021/jacs.6b12404